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Home > Encyclopedia > Methanaminium, N-methyl-N-methylene-, iodide

Methanaminium, N-methyl-N-methylene-, iodide

Methanaminium, N-methyl-N-methylene-, iodide structure

Methanaminium, N-methyl-N-methylene-, iodide 

structure
  • CAS No:

    33797-51-2

  • Formula:

    C3H8N.I

  • Chemical Name:

    Methanaminium, N-methyl-N-methylene-, iodide

  • Synonyms:

    Methanaminium,N-methyl-N-methylene-,iodide;Ammonium,dimethylmethylene-,iodide;Dimethyl(methylene)ammonium iodide;Methylenedimethylammonium iodide;Eschenmoser's salt;Eschenmoser's reagent;N,N-Dimethylmethyleneiminium iodide;N,N-Dimethylaminomethyleneammonium iodide;Dimethylmethylideneiminium iodide;N-Methyl-N-methylenemethanaminium iodide

  • Categories:

    Chemical Reagents  >  Organic Reagents

Description

CREAM TO YELLOW CRYSTALLINE POWDER

Methanaminium, N-methyl-N-methylene-, iodide Basic Attributes

185.01

184.970139

3594966

251-680-2

5C42I004S1

DTXSID10369115

2923900090

Characteristics

3

-3.03690

Cream to yellow Crystalline Powder

1.7217 (estimate)

238 °C

soluble in dimethylformamide. Partially soluble in acetonitrile, tetrahydrofuran and dichloromethane.

2-8°C

Safety Information

NONH for all modes of transport

3

36/37/38

26-36

Xi

P261-P305 + P351 + P338

H315-H319-H335

|Warning|H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]|P261, P264, P271, P280, P302+P352, P304+P340, P305+P351+P338, P312, P321, P332+P313, P337+P313, P362, P403+P233, P405, and P501|Aggregated GHS information provided by 45 companies from 4 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Methanaminium, N-methyl-N-methylene-, iodide Use and Manufacturing

Methods of Manufacturing

The mixture of trimethylamine, diiodomethane, dioxane and absolute ethanol was placed in the dark and reacted at room temperature for 100h. The resulting crystals were collected by filtration, washed with ethanol and ether in sequence, and dried in vacuum at 70°C to obtain iodomethyl tris Methyl ammonium iodide. It was heated together with sulfolane to 160°C for 12 minutes, and the precipitated crystals were collected by filtration, washed with carbon tetrachloride, and dried in vacuum at 50°C to obtain a finished product.

Uses

In organic synthesis.

Computed Properties

Molecular Weight:185.01
Hydrogen Bond Acceptor Count:1
Exact Mass:184.97015
Monoisotopic Mass:184.97015
Topological Polar Surface Area:3
Heavy Atom Count:5
Complexity:26.3
Covalently-Bonded Unit Count:2
Compound Is Canonicalized:Yes

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