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Home > Encyclopedia > (S)-O-TOLYL-CBS-OXAZABOROLIDINE, 0.5M I&

(S)-O-TOLYL-CBS-OXAZABOROLIDINE, 0.5M I&

(S)-O-TOLYL-CBS-OXAZABOROLIDINE, 0.5M I& structure

(S)-O-TOLYL-CBS-OXAZABOROLIDINE, 0.5M I& 

structure
  • CAS No:

    463941-07-3

  • Formula:

    C24H24BNO

  • Chemical Name:

    (S)-O-TOLYL-CBS-OXAZABOROLIDINE, 0.5M I&

  • Synonyms:

    (S)-O-TOLYL-CBS-OXAZABOROLIDINE, 0.5M I&;(s)-(-)-3,3-diphenyl-1-o-tolyl-tetrahydropyrrolo(1,2-c)(1,3,2)oxazaborole solution;(s)-(-)-o-tolyl-cbs-oxazaborolidine solution;(S)-()-o-Tolyl-CBS-oxazaborolidine solution,(S)-()-3,3-Diphenyl-1-o-tolyl-tetrahydropyrrolo(1,2-c)(1,3,2)oxazaborole solution;(S)-(-)-o-Tolyl-CBS-oxazaborolidine solution 0.5 M in toluene;(S)-o-tol-Corey-Bakshi-Shibata catalyst

  • Categories:

    Chemical Reagents  >  Organic Reagents

(S)-O-TOLYL-CBS-OXAZABOROLIDINE, 0.5M I& Basic Attributes

353.272

353.19500

DTXSID90458596

Characteristics

12.47000

4.06650

0.9009 g/mL at 25ºC

473.3ºC at 760 mmHg

7 °C

n20/D 1.514

Safety Information

UN12943/PG2

3

11-38-48/20-63-65-67

36/37-62-16

F,Xn

(S)-O-TOLYL-CBS-OXAZABOROLIDINE, 0.5M I& Use and Manufacturing

Chiral oxaborane and trifluoromethanesulfonimide can generate chiral Lewis acid during protonation reaction, which has proved to be very suitable for enantioselective Diels-Alder reaction. 1,2

Computed Properties

Molecular Weight:353.3
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:3
Exact Mass:353.1950946
Monoisotopic Mass:353.1950946
Topological Polar Surface Area:12.5
Heavy Atom Count:27
Complexity:481
Defined Atom Stereocenter Count:1
Covalently-Bonded Unit Count:1
Compound Is Canonicalized:Yes

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