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DavePhos-Pd-G3

DavePhos-Pd-G3 structure

DavePhos-Pd-G3 

structure
  • CAS No:

    1445085-87-9

  • Formula:

    C39H49N2O3PPdS

  • Chemical Name:

    DavePhos-Pd-G3

  • Synonyms:

    Methanesulfonato[2-(dicyclohexylphosphino)-2'-(N,N-diMethylaMino)-1,1'-biphenyl](2'-aMino-1,1'-biphenyl-2-yl)palladiuM(II) CH2Cl2 adduct, Min. 98% [DavePhos Palladacycle];DavePhos-Pd-G3 AldrichCPR;Methanesulfonato[2-(dicyclohexylphosphino)-2'-(N,N-dimethylamino)-1,1'-biphenyl](2'-amino-1,1'-biphenyl-2-yl)palladium(II) CH2Cl2 adduct;METHANESULFONATO[2-(DICYCLOHEXYLPHOSPHINO)-2'-(N,N-DIMETHYLAMINO)-1,1'-BIPHENYL](2'-AMINO-1,1'-BIPHENYL-2-YL)PALLADIUM(II)CH2CL2ADDUCT,MIN.98%[DAVEPHOSPALLADACYCLEGEN.3];[2-(dicyclohexylphosphino)-2-(N,N-dimethylamino)-1,1-biphenyl]-2-(2-amino-1,1-biphenyl)]palladium(II) methanesulfonate;Methanesulfonato[2-(dicyclohexylphosphino)-2'-(N,N-dimethylamino)-1,1'-biphenyl](2'-amino-1,1'-biphenyl-2-yl)palladium(II) CH2Cl2 adduct,[DavePhos Palladacycle Gen. 3];Methanesulfonato[2-(dicyclohexylphosphino)-2'-(N,N-diMethylaMino)-1,1'-biphenyl](2'-aMino-1,1'-biphenyl-2-yl)palladiuM(II) CH2Cl2 adduct [DavePhos Palladacycle];Methanesulfonato[2-(dicyclohexylphosphino)-2'-(N,N-dimethylamino)1,1'-biphenyl](2'-amino-1,1'-biphenyl-2-yl)palladium(II)

  • Categories:

    Catalyst and Auxiliary  >  Polymer

Description

DavePhos-Pd-G3 is a modified G3 precatalyst (G3′). It has been synthesized by Buchwald and coworkers from second generation (G2) precatalyst by methylation of the amino group present on biphenyl backbone. It is a useful catalyst for various cross-coupling reactions. They are versatile catalysts. They have long life in solutions and are readily soluble in various organic solvents. G3- precatalysts have been employed in various C-N bond forming reactions.

DavePhos-Pd-G3 Basic Attributes

763.29

white

Characteristics

183-200°C (decomp)

2-8°C, protect from light, stored under nitrogen

Safety Information

WGK 3

DavePhos-Pd-G3 Use and Manufacturing

Pd precatalyst for cross-coupling

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