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(1,5-CYCLOOCTADIENE)(PYRIDINE)(TRICYCLOHEXYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE

(1,5-CYCLOOCTADIENE)(PYRIDINE)(TRICYCLOHEXYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE structure

CAS No:
64536-78-3
Formula:
C31H47F6IrNP2
Chemical Name:
(1,5-CYCLOOCTADIENE)(PYRIDINE)(TRICYCLOHEXYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE
Synonyms:
tricyclohexylphosphinecyclooctadienepyridineiridium PF6;Crabtrees catalyst, (1,5-Cyclooctadiene)(pyridine)(tricyclohexylphosphine)-Ir(I) PF6, Iridium(I) hexafluorophosphate (1,5-Cyclooctadiene)-(pyridine)-(tricyclohexylphosphine) complex;(TRICYCLOHEXYLPHOSPHINE)(1,5-CYCLOOCTA- DIENE)(PYRIDINE)IRIDIUM(I) PF6;(Tricyclohexylphosphine)(1,5-cyclooctadiene)(pyridine)iridium(I) hexafluorophosphate,99%;(1,5-Cyclooctadiene)pyridine(tricyclohexylphosphine)iridium hexafluorophosphate;(Tricyclohexylphosphine)(1,5-cyclooctadiene)(pyridine)iridium(I)hexafluorophosphate,99%CRABTREE'SCATALYST;1,5-Cyclooctadiene-(pyridyl)-(tricyclohexylphosphine)-iridium hexafluoropho;(cycloocta-1,5-diene)pyridyl(tricyclohexyl-phosphine)iridium(I)hexafluorophosphate Crabtree's catalyst
Categories:
Catalyst and Auxiliary > Precious Metal Catalysts

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Description

orange crystals. Air stable for days, but long term storage under N2 and in the dark recommended.

(1,5-CYCLOOCTADIENE)(PYRIDINE)(TRICYCLOHEXYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE Basic Attributes

Molecular Weight：

801.88

TSCA：

Color/Form：

Orange

HScode：

29310099

Characteristics

Density：

1.67 g/cm3

Melting Point：

175 °C (dec.)(lit.)

Water Solubility：

Slightly soluble in acetone, dichloromethane, ethanol and diethyl ether. Insoluble in water.

Critical Temperature & Pressure：

Inert atmosphere,Room Temperature

Safety Information

wgk germany：

hazard class code：

Xi,Xn

safety instructions：

26-36

Hazard Statements：

36/37/38

(1,5-CYCLOOCTADIENE)(PYRIDINE)(TRICYCLOHEXYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE Use and Manufacturing

1,5-Cyclooctadiene(pyridine)(tricyclohexylphosphine)iridium(I) hexafluorophosphate is used as a catalyst for hydrogenation of mono-, di-, tri-, and tetra-substituted substrates and the isomerization and hydroboration of alkenes. It is also used in isotope exchange reactions, especially the direct exchange of a hydrogen atom with its isotopes deuterium and tritium. Carbonyl groups are also known to direct the hydrogenation by the Crabtree catalyst is highly regioselective.

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Guide of (1,5-CYCLOOCTADIENE)(PYRIDINE)(TRICYCLOHEXYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE

Description
Basic Attributes
Characteristics
Safety Information
Use and Manufacturing
Recommended Suppliers
Latest News
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