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Methyl cellulose

Methyl cellulose structure

Methyl cellulose 

structure
  • CAS No:

    9004-67-5

  • Formula:

    C20H38O11

  • Chemical Name:

    Methyl cellulose

  • Synonyms:

    adulsin;Methyl cellulose, viscosity 8000 cPs;'TYLOSE'(R) MH 300;'TYLOSE'(R) MH 1000;walsrodermc20000s;FEMA 2696;MethyI cellulose;METHYL CELLULOSE (CMC)

  • Categories:

    Organic Chemistry  >  Alcohols, Phenols, Phenol Alcohols

Description

It is a kind of methyl ether of cellulose. It is white or pale yellow or light gray small particles (95% through a 40 mesh sieve), filaments like or powder. It is odorless, tasteless and has hygroscopicity with an apparent density of 0.3~0.7g/mL.When all the R in the structure is methyl, the substitution degree is equal to 3, and the methoxy content is 45.57%. For methylcellulose used as the food additive, the methoxy content should be around 26%~33% which corresponds to a degree of substitution of 1.7 to 2.2. When the substitution degree is lower than 1.3, it can be dissolved in alkaline. While methylcellulose with substitution degree higher than 2.6 is soluble in an organic solvent. When the degree of substitution is less than 1.3, it can be dissolved in alkali; for those with substitution degree higher than 2.6, it is soluble in organic solution. At the range between 1.3 and 2.6, it is soluble in cold water, pyridine, aniline, trimethyl formamide, benzyl alcohol and acetic acid.Aqueous solution is stable at neutral and room temperature; but it can generate gelation effect and be precipitated at high temperature. Gelation temperature is dependent on the absolute viscosity and concentration of the solution; solution of large viscosity and high concentration has a relative low gelling temperature. In the presence of inorganic salts, viscosity can be increased. Due to that it belongs to a non-ionic solution, the polyvalent metal is not able to precipitate it; Gelation will only occur when the concentration of the electrolyte and other dissolved substances exceeds a certain limit.Aqueous solution has surfactant activity and dried to form a thin film; upon heating and cooling, it will orderly go through the reversible transition from the sol to gel.


white powder or (often) 2% solution in water, properties


Methylcellulose occurs as a white, fibrous powder or granules. It is practically odorless and tasteless. It should be labeled to indicate its viscosity type (viscosity of a 1 in 50 solution).


Methyl cellulose is a water soluble, gel-like substance with no odor and no taste.


Odorless white or creamy white fibrous powder. Tasteless.

Methyl cellulose Basic Attributes

454.50912

232-674-9

TSCA listed

White, yellow-white or grayish-white

39129000

Characteristics

1.01 g/cm3(Temp: 70 °C)

290-305 °C

1.4970

SOLUBLE IN COLD WATER

ADI does not make special provision (FAO/WHO, 2001).GRAS (FDA, §182.1480, 2000).

odorless

5.0 -8.0

Methyl cellulose is hygroscopic. Swells in water to a viscous, colloidal solid. Slightly water soluble.

Methyl cellulose is incompatible with strong oxidizing agents. Methyl cellulose is also incompatible with aminacrine HCl, chlorocresol, mercuric chloride, phenol resorcinol, tannic acid and silver nitrate.

Room Temperature

Safety Information

3

24/25

FJ5959000

Methylcellulose powder is stable, although slightly hygroscopic. The bulk material should be stored in an airtight container in a cool, dry place.Solutions of methylcellulose are stable to alkalis and dilute acids at pH 3–11, at room temperature. At pH less than 3, acid-catalyzed hydrolysis of the glucose–glucose linkages occurs and the viscosity of methylcellulose solutions is reduced.On heating, solution viscosity is reduced until gel formation occurs at approximately 50°C;Methylcellulose solutions are liable to microbial spoilage and antimicrobial preservatives should therefore be used. Solutions may also be sterilized by autoclaving, although this process can decrease the viscosity of a solution.The change in viscosity after autoclaving is related to solution pH. Solutions at pH less than 4 had viscosities reduced by more than 20% subsequent to autoclaving.

chlorocresol; mercuric chloride; phenol; resorcinol; tannic acid; silver nitrate; cetylpyridinium chloride; p-hydroxybenzoic acid; paminobenzoic acid; methylparaben; propylparaben; and butylparaben.Salts of mineral acids (particularly polybasic acids), phenols, and tannins will coagulate solutions of methylcellulose, although this can be prevented by the addition of ethanol (95%) or glycol diacetate. Complexation of methylcellulose occurs with highly surface-active compounds such as tetracaine and dibutoline sulfate.High concentrations of electrolytes increase the viscosity of methylcellulose mucilages owing to the ‘salting out’ of methylcellulose. With very high concentrations of electrolytes, the methylcellulose may be completely precipitated in the form of a discrete or continuous gel. Methylcellulose is incompatible with strong oxidizing agents.

Flash point data for Methyl cellulose are not available; however, Methyl cellulose is probably combustible.

Methyl cellulose Use and Manufacturing

Uses

It can be used as thickeners; stabilizer; emulsifier; excipients; dispersant; binders; substitutes of film-forming agent hydrosol. It can also be used in mayonnaise, shortenings and some other foods. Because of that the materials can’t digested in the body, it can maintain several times amount of water, resulting in satiety; it can be used in crackers, waffles and other food for taking effect. For application, first 1/5 of the required amount of water for moistening the powder, together with cold water (necessary, to add ice) for mixing well. EEC: approved for using at frozen foam products, potato chips, soft drinks, special dietary foods, baked goods filling, the top material for foaming, sauces, and sauces.It can also be used in mayonnaise, shortenings and some other foods.Because of that the materials can’t digested in the body, it can maintain several times amount of water, resulting in satiety; it can be used in crackers, waffles and other food for taking effect.For application, first 1/5 of the required amount of water for moistening the powder, together with cold water (necessary, to add ice) for mixing well. EEC: approved for using at frozen foam products, potato chips, soft drinks, special dietary foods, baked goods filling, the top material for foaming, sauces, and sauces.The product is widely used in the architecture industry such as the mixture agent for cement, plaster, and clay seams. It can also be used as adhesive film-forming agent in cosmetics, medicine, and food industry; also can be used as sizing agents for spinning, and printing and dyeing, synthetic resin dispersing agent, paint film formers and thickeners. Methyl cellulose is a very stable material which is resistant to acid, alkalis, microorganisms, and heating. It can be excrete out from the human body without any change. It is used for synthetic resin dispersing agent, film-forming agent of painting, thickener, binder materials, textile sizing agent, and the film-forming agent in the pharmaceutical and food industries.


Methylcellulose is a gum composed of cellulose in which the meth- oxyl groups replace the hydroxyl groups. it is soluble in cold water but insoluble in hot water. solutions increase in viscosity upon heating, gel at 50–55°c, and liquefy upon cooling. it is used in baked goods for moisture retention, and in fruit pie fillings for the reduction of water absorption into the pie crust during baking. it is also used in breaded shrimp where it functions to form an oil barrier film.


Thickener for aqueous and non-aqueous systems, clear films with grease resistance, binders, lubricants, steric stabilizer and water retention aid.


As a substitute for water-soluble gums; to render paper greaseproof, in adhesives, as thickening agent in cosmetics, as protective colloid in emulsions, as binder and stabilizer in foods. As fat replacer in the formulation of dietetic foods. Pharmaceutic aid (suspending agent).


Methyl cellulose is used as a thickener and an emulsifier in various food and cosmetic products; as a gel in advanced cookery and as a lubricant. It is also involved in the treatment of constipation. It acts as a buffer additive in capillary electrophoresis to control electoosmotic flow for improved separations. In paper and textile industries, it is used as a sizing, thereby protecting the fibers from water or oil.

Production

Methylcellulose is prepared from wood pulp (cellulose) by treatment with alkali followed by methylation of the alkali cellulose with methyl chloride. The product is then purified and ground to powder form.

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