3,3-Bis(chloromethyl)oxetane

155.02

155.02

201-136-5

N12TP81ATK

650608

DTXSID9058816

Finely divided powder for coatings|Natural, black, or olive green molding powder.

2932999099

9.23000

0.85

The monomer unit of a thermoplastic resin trademarked Penton.

1.4 g/cm³

18.7 °C

80 °C @ Press: 10 Torr

114 °C

1.462

Oral-rat LD50: 600 mg/kg; Oral-Mouse LD50: 420 mg/kg

Flammable; burning produces toxic chloride fumes

A linear polymer extremely resistant to chemicals and to thermal degradation at molding and extrusion temperature ... dimensionally stable, very low water absorption.

No rapid reaction with air. No rapid reaction with water.

Ethers

3,3-BIS(CHLOROMETHYL)OXETANE is a chlorinated ether.

III

6.1(b)

2810

3

22-26-36/37/38

23-26-36/37/39-45

RQ6826000

T+,Xn

Treasury is ventilated, low temperature and dry; stored separately from food materials

P264, P270, P301+P312, P330, P501

H302

|Warning|H302 (97.44%): Harmful if swallowed [Warning Acute toxicity, oral]|P264, P270, P301+P312, P330, and P501|Aggregated GHS information provided by 39 companies from 2 notifications to the ECHA C&L Inventory.

For emergency situations, wear a positive pressure, pressure-demand, full facepiece self-contained breathing apparatus (SCBA) or pressure- demand supplied air respirator with escape SCBA and a fully-encapsulating, chemical resistant suit. (EPA, 1998)

Self extinguishing

Purification of waste water from the synthesis of 3,3-di-(chloromethyl) oxycyclobutane.|Biological clarification of sewage from production of 3,3-bis(chloromethyl) oxycyclobutane.

Releases of CERCLA hazardous substances are subject to the release reporting requirement of CERCLA section 103, codified at 40 CFR part 302, in addition to the requirements of 40 CFR part 355. Oxetane, 3,3-bis(chloromethyl)- is an extremely hazardous substance (EHS) subject to reporting requirements when stored in amounts in excess of its threshold planning quantity (TPQ) of 500 lbs.

highly toxic

Signs and Symptoms of Oxetane, 3,3-Bis(chloromethyl)- Exposure: Signs and symptoms of acute exposure to oxetane, 3,3-bis(chloromethyl)- may include headache, dizziness, weakness and nausea. Also, irritation of the eyes, skin, respiratory tract may be observed. Esophagus or gastrointestinal tract irritation is possible if ingested. Longer term exposure may lead to allergic hypersensitivity dermatitis or asthma with bronchospasm and wheezing. Emergency Life-Support Procedures: Acute exposure to oxetane, 3,3-bis(chloromethyl)- may require decontamination and life support for the victims. Emergency personnel should wear protective clothing appropriate to the type and degree of contamination. Air-purifying or supplied-air respiratory equipment should also be worn, as necessary. Rescue vehicles should carry supplies such as plastic sheeting and disposable plastic bags to assist in preventing spread of contamination. Inhalation Exposure: 1. Move victims to fresh air. Emergency personnel should avoid self-exposure to oxetane, 3,3-bis(chloromethyl)-. 2. Evaluate vital signs including pulse and respiratory rate, and note any trauma. If no pulse is detected, provide CPR. If not breathing, provide artificial respiration. If breathing is labored, administer 100% humidified oxygen or other respiratory support. 3. Obtain authorization and/or further instructions from the local hospital for performance of other invasive procedures. 4. Transport to a health care facility. Dermal/Eye Exposure: 1. Remove victims from exposure. Emergency personnel should avoid self-exposure to oxetane, 3,3-bis(chloromethyl)-. 2. Evaluate vital signs including pulse and respiratory rate, and note any trauma. If no pulse is detected, provide CPR. If not breathing, provide artificial respiration. If breathing is labored, administer 100% humidified oxygen or other respiratory support. 3. Obtain authorization and/or further instructions from the local hospital for performance of other invasive procedures. 4. Remove and isolate contaminated clothing as soon as possible. 5. If eye exposure has occurred, eyes must be flushed with lukewarm water for at least 15 minutes. 6. Wash exposed skin areas thoroughly with soap and water. 7. Transport to a health care facility. Ingestion Exposure: 1. Evaluate vital signs including pulse and respiratory rate, and note any trauma. If no pulse is detected, provide CPR. If not breathing, provide artificial respiration. If breathing is labored, administer 100% humidified oxygen or other respiratory support. 2. Obtain authorization and/or further instructions from the local hospital for performance of other invasive procedures. 3. Vomiting may be induced with syrup of Ipecac. If elapsed time since ingestion of oxetane, 3,3-bis(chloromethyl)- is unknown or suspected to be greater than 30 minutes, do not induce vomiting and proceed to Step 4. Ipecac should not be administered to children under 6 months of age.Warning: Ingestion of oxetane, 3,3-bis(chloromethyl)- may result in sudden onset of seizures or loss of consciousness. Syrup of Ipecac should be administered only if victims are alert, have an active gag-reflex, and show no signs of impending seizure or coma. Observe patients with ingestion for possible development of esophageal or gastrointestinal burns or irritation. If ANY uncertainty exists, proceed to Step 4.The following dosages of Ipecac are recommended: children up to 1 year old, 10 mL (1/3 oz); children 1 to 12 years old, 15 mL (1/2 oz); adults, 30 mL (1 oz). Ambulate (walk) the victims and give large quantities of water. If vomiting has not occurred after 15 minutes, Ipecac may be readministered. Continue to ambulate and give water to the victims. If vomiting has not occurred within 15 minutes after second administration of Ipecac, administer activated charcoal. 4. Activated charcoal may be administered if victims are conscious and alert. Use 15 to 30 g (1/2 to 1 oz) for children, 50 to 100 g (1-3/4 to 3-1/2 oz) for adults, with 125 to 250 mL (1/2 to 1 cup) of water. 5. Transport to a health care facility. (EPA, 1998)

Oxetane, 3,3-bis(chloromethyl)-, homopolymer: INACTIVE|XU - indicates a substance exempt from reporting under the Chemical Data Reporting Rule, (40 CFR 711).|Oxetane, 3,3-bis(chloromethyl)-: ACTIVE|Penton: Trademark for a thermoplastic resin derived from 3,3-bis(chloromethyl)oxetane ...|Poly(3,3-bis-(chloromethyl)oxetane) (PBCMO) was available commercially as Penton but it is no longer marketed. /Poly(3,3-bis-(chloromethyl)oxetane)/