Titanium chloride (TiCl3)
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Titanium chloride (TiCl3)
structure -
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CAS No:
7705-07-9
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Formula:
Cl3Ti
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Chemical Name:
Titanium chloride (TiCl3)
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Synonyms:
Titanium chloride (TiCl3);Titanium trichloride;Titanous chloride;Titanium(III) chloride;Titanium chloride;TAC 121;Trichlorotitanium;TAC 132;TGY 24;TAS 101;TAC 140;TAC 144;Lynx 900;TEN 12;TOS 17;MSK-TiCl3;TAS 101 (inorganic compound)
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CAS No:
Description
It appears as deep purple crystal and can be easily subject to deliquescence. Its chemical formula is TiCl3. It has a molecular weight of 154.26. It has a relative density is 2.64, a melting point of 440 °C (decomposition) and the boiling point of 660 °C (106 × 133.322 Pa). It is easily soluble in water and slightly soluble in ethanol with both the solutions exhibiting purple color. Upon heating, the solution will be turned into a blue with further returning back to purple after cooling down. I
Liquid
Characteristics
0 Ų
2.06850
Purple powder
1.192 g/mL at 25 °C
150-208 °C
100 °C
1.4856 (25ºC)
H2O: soluble
Keep container closed when not in use. Store in a cool, dry, well-ventilated area away from incompatible substances. Corrosives area. Do not expose to air. Store under an inert atmosphere.
Combustible in case of oxidant and H pore-forming agent; emit toxic hydrogen cyanide gas in case of cyanide; decompose toxic chloride fumes when heated
Safety Information
II
8
UN 3264 8/PG 2
3
34-37-35-17-14
6-26-30-36/37/39-43-45
XR1924000
C,F
The warehouse is ventilated and dried at low temperature; stored separately from oxidants, cyanides, H pore-forming agents and alkalis
Corrosive
Stable, but reacts violently with water and is spontaneously flammable in air.
P222-P231-P280-P305 + P351 + P338-P310-P422
H250-H314
Flammable - 3rd degree, Reactive - 3rd degree
|Danger|H250 (96.08%): Catches fire spontaneously if exposed to air [Danger Pyrophoric liquids; Pyrophoric solids]|P210, P222, P260, P261, P264, P271, P272, P280, P284, P301+P330+P331, P302+P334, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P310, P312, P320, P321, P333+P313, P363, P370+P378, P403+P233, P405, P422, and P501|Aggregated GHS information provided by 204 companies from 8 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.|H250: Catches fire spontaneously if exposed to air [Danger Pyrophoric liquids; Pyrophoric solids]|P210, P222, P223, P231+P232, P260, P264, P280, P301+P330+P331, P302+P334, P303+P361+P353, P304+P340, P305+P351+P338, P310, P321, P335+P334, P363, P370+P378, P402+P404, P405, P422, and P501|P210, P222, P260, P264, P270, P280, P301+P310, P301+P330+P331, P302+P334, P303+P361+P353, P304+P340, P305+P351+P338, P310, P321, P330, P363, P370+P378, P405, P422, and P501
Titanium chloride (TiCl3) Use and Manufacturing
The aluminum reduction method uses excess titanium tetrachloride and aluminum powder to react at 136°C, and aluminum trichloride is used as an initiator to generate titanium trichloride and aluminum trichloride. The excess titanium tetrachloride is distilled off by heating, and it can be recycled for recycling. At the same time, the aluminum trichloride is sublimated to obtain the finished titanium trichloride. Its 3TiCl4+Al→3TiCl3+A1C13
A powerful reducing agent.Reduces nitrate to ammonia; when boiled with aqueous SO2, sulfur is separated; hence is used as an aqueous solution for estimation of nitro groups, ferric ions, per-salts, etc.Removes stains, etc. (stripper) in laundering.
Intermediates
All other basic inorganic chemical manufacturing|Titanium chloride (TiCl3): ACTIVE
Fire Hazards -> Flammable - 3rd degree, Reactive - 3rd degree
Computed Properties
Molecular Weight:154.22
Exact Mass:152.854499
Monoisotopic Mass:152.854499
Heavy Atom Count:4
Complexity:8
Covalently-Bonded Unit Count:1
Compound Is Canonicalized:Yes
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