Titanium tetrabutoxide

340.32

388.157257

227-006-8

FJS8Q2MX9I

2920

DTXSID6041262

COLORLESS TO LIGHT-YELLOW LIQUID|Pale yellow, viscous liquid

29051900

36.92000

5.06960

Pale yellow Liquid

0.998 g/cm³ @ Temp: 20 °C

-55 °C

312 °C

55 °F

n20/D 1.491(lit.)

RAPIDLY HYDROLIZED;Miscible with aliphatic, aromatic, chlorinated and oxygenated solvents.

Flammables area

5.6 hPa (20 °C)

11.7 (Air= 1)

Oral-rat LD50: 3122 mg/kg; Intravenous-Mouse LD50: 180 mg/kg

In case of heat, open flame is flammable; thermal decomposition is spicy and stimulates smoke

2.0-12.0%(V)

WEAK, ALCOHOL-LIKE ODOR

REACTS WITH WATER TO FORM BUTANOL AND TITANIUM DIOXIDE|Forms a glass below -55 °C; decomp in water

Soluble in water. Reacts with water to form butanol and titanium dioxide, the reaction is not generally thought to be hazardous.

Bases, Strong

Organometallics are strongly reactive with many other groups. Incompatible with acids and bases. Organometallics are good reducing agents and therefore incompatible with oxidizing agents. Often reactive with water to generate toxic or flammable gases. Generally highly toxic. Often react on contact with tissues to give toxic products.

(EST) -8100 CAL/G

2%-12%

79 CAL/G

III

8

UN 1993 3/PG 3

1

10-36/37/38-67-41-37/38-45

16-26-39-24/25-53

XR1585000

Xi,T

Treasury is ventilated, low temperature and dry; stored separately from oxidant

Stable, but moisture sensitive. Flammable. Incompatible with water, moisture, strong oxidizing agents, strong acids.

P280-P305 + P351 + P338 + P310-P403 + P235

H226-H315-H318-H335-H336

SRP: At the time of review, criteria for land treatment or burial (sanitary landfill) disposal practices are subject to significant revision. Prior to implementing land disposal of waste residue (including waste sludge), consult with environmental regulatory agencies for guidance on acceptable disposal practices.

Incompatible with oxidizing materials.

Combustible. Containers may explode in fire. May give off dense white smoke. Containers may explode. (USCG, 1999)

|Danger|H226 (89.82%): Flammable liquid and vapor [Warning Flammable liquids]|P210, P233, P240, P241, P242, P243, P261, P264, P271, P280, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P310, P312, P321, P332+P313, P337+P313, P362, P370+P378, P403+P233, P403+P235, P405, and P501|Aggregated GHS information provided by 1507 companies from 39 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.|H226 (52.98%): Flammable liquid and vapor [Warning Flammable liquids]|P210, P233, P240, P241, P242, P243, P261, P264, P270, P271, P280, P301+P312, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P310, P312, P321, P330, P332+P313, P337+P313, P362, P370+P378, P403+P233, P403+P235, P405, and P501|Aggregated GHS information provided by 169 companies from 10 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.|Warning|H227: Combustible liquid [Warning Flammable liquids]|P210, P280, P370+P378, P403+P235, and P501

Excerpt from ERG Guide 132 [Flammable Liquids - Corrosive]: As an immediate precautionary measure, isolate spill or leak area for at least 50 meters (150 feet) in all directions. SPILL: Increase, in the downwind direction, as necessary, the isolation distance shown above. FIRE: If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2016)

Excerpt from ERG Guide 132 [Flammable Liquids - Corrosive]: Fully encapsulating, vapor-protective clothing should be worn for spills and leaks with no fire. ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). All equipment used when handling the product must be grounded. Do not touch or walk through spilled material. Stop leak if you can do it without risk. Prevent entry into waterways, sewers, basements or confined areas. A vapor-suppressing foam may be used to reduce vapors. Absorb with earth, sand or other non-combustible material and transfer to containers (except for Hydrazine). Use clean, non-sparking tools to collect absorbed material. LARGE SPILL: Dike far ahead of liquid spill for later disposal. Water spray may reduce vapor, but may not prevent ignition in closed spaces. (ERG, 2016)

Excerpt from ERG Guide 132 [Flammable Liquids - Corrosive]: Wear positive pressure self-contained breathing apparatus (SCBA). Wear chemical protective clothing that is specifically recommended by the manufacturer. It may provide little or no thermal protection. Structural firefighters' protective clothing provides limited protection in fire situations ONLY; it is not effective in spill situations where direct contact with the substance is possible. (ERG, 2016)|SELF-CONTAINED BREATHING APPARATUS OR ORGANIC CANISTER MASK; GOGGLES OR FACE SHIELD; RUBBER GLOVES.

FLAMMABLE WHEN EXPOSED TO HEAT OR FLAME.

CONTAINERS MAY EXPLODE IN FIRE.

EXTINGUISH WITH DRY CHEM OR CARBON DIOXIDE. DO NOT USE WATER ON FIRE. COOL EXPOSED CONTAINERS WITH WATER.

MAY GIVE OFF DENSE WHITE SMOKE.

moderately toxic

LD50 Rat oral 3122 mg/kg|LD50 Mouse iv 180 mg/kg

LIQUID: Irritating to skin and eyes. If swallowed will cause nausea and vomiting. (USCG, 1999)

INHALATION: move from contaminated atmosphere; if symptoms of respiratory discomfort persist, see a physician. EYES: immediately flush with large quantities of running water for a minimum of 15 minutes; obtain medical attention if irritation persists. SKIN: immediately flush affected areas with water; obtain medical attention if irritation persists. INGESTION: give large amounts of water or warm salty water to induce vomiting; if this measure is unsuccessful, vomiting may be induced by tickling the back of the patient's throat with a finger; vomiting should be encouraged until vomitus is clear; obtain medical attention if abdominal discomfort persists. (USCG, 1999)

INHALATION CAUSES NONSPECIFIC IRRITATION OF THE UPPER RESP TRACT. CONTACT WITH LIQUID MAY CAUSE CORNEAL DAMAGE IN EYES AND LOCAL IRRITATION OF SKIN. INGESTION CAUSES NONSPECIFIC IRRITATION OF GI TRACT, NAUSEA, VOMITING, CRAMPS, AND DIARRHEA; IN SEVERE CASES, CENTRAL NERVOUS SYSTEM DEPRESSION MAY RESULT.

1-butanol, titanium(4+) salt

Grades of Purity: Technical

All other basic inorganic chemical manufacturing|1-Butanol, titanium(4+) salt (4:1): ACTIVE|1-Butanol, titanium(4+) salt (4:1), homopolymer: ACTIVE|XU - indicates a substance exempt from reporting under the Chemical Data Reporting Rule, (40 CFR 711).|IN DENTAL OR MEDICAL BONDING COMPOSITIONS|IN ANHYDROUS HAIR SET COMPOSITION