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Home > Encyclopedia > N,N′-Di(2-naphthyl)-p-phenylenediamine

N,N′-Di(2-naphthyl)-p-phenylenediamine

N,N′-Di(2-naphthyl)-p-phenylenediamine structure

N,N′-Di(2-naphthyl)-p-phenylenediamine 

structure
  • CAS No:

    93-46-9

  • Formula:

    C26H20N2

  • Chemical Name:

    N,N′-Di(2-naphthyl)-p-phenylenediamine

  • Synonyms:

    1,4-Benzenediamine,N1,N4-di-2-naphthalenyl-;p-Phenylenediamine,N,N′-di-2-naphthyl-;1,4-Benzenediamine,N,N′-di-2-naphthalenyl-;N1,N4-Di-2-naphthalenyl-1,4-benzenediamine;Aceto DIPP;sym-Di-β-naphthyl-p-phenylenediamine;DNPD;Tisperse MB 2X;N,N′-Di-β-naphthyl-p-phenylenediamine;Diafen NN;Nonox CI;N,N′-di-β-Naphthyl-p-phenylenediamine;AgeRite White;N,N′-Bis(β-naphthyl)-p-phenylenediamine;N,N′-Di-2-naphthyl-1,4-benzenediamine;N,N′-Di(2-naphthyl)-p-phenylenediamine;s-Di-β-Naphthyl-p-phenylenediamine;N,N′-di-2-Naphthyl-p-phenyldiamine;AgeRite W;Antigene F;Antioxidant DNP;Antioxidant 123;ASM-DNT;Santowhite CI;1,4-Bis(2-naphthylamino)benzene;N,N′-Di-2-naphthyl-1,4-phenylenediamine;N,N′-p-Phenylenebis[2-naphthylamine];N,N′-Bis(2-naphthyl)-p-phenylenediamine;DNP;Nocrac White;Antage F;N,N′-Bis(2-naphthyl)-1,4-phenylenediamine;Anchor DNPD;NSC 3410;Nonflex F;Ouchi Shinko White F;60005-69-8;112721-02-5;866724-57-4

  • Categories:

    Catalyst and Auxiliary  >  UV Absorbers

Description

PHYSICAL DESCRIPTION: Gray powder. (NTP, 1992)


N,n'-di-2-naphthyl-p-phenylenediamine is a gray powder. (NTP, 1992)


N,n'-di-2-naphthyl-p-phenylenediamine is a gray powder. (NTP, 1992)

N,N′-Di(2-naphthyl)-p-phenylenediamine Basic Attributes

360.45

360.45

202-249-2

EWK9V6MZH6

3410

DTXSID3020918

2921590090

Characteristics

24.1

5.78

N,n'-di-2-naphthyl-p-phenylenediamine is a gray powder. (NTP, 1992)

1.25 (NTP, 1992)

225-229°C

232-134°C (dec.)

399.0±17.7 °C

1.772

H2O: <0.1 g/100 mL at 19 ºC

Keep in a cool, dry, dark location in a tightly sealed container or cylinder. Keep away from incompatible materials, ignition sources and untrained individuals. Secure and label area. Protect containers/cylinders from physical damage.

9.87E-15mmHg at 25°C

LD50 oral in rat: 4500mg/kg

Insoluble in water.

Amines, Phosphines, and Pyridines

N,N'-DI-2-NAPHTHYL-P-PHENYLENEDIAMINE neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides.

Safety Information

20/21/22-36/37/38

22-36/37/39

ST2100000

P261, P264, P272, P280, P302+P352, P305+P351+P338, P321, P332+P313, P333+P313, P337+P313, P362, P363, P501

H315

Flash point data for this chemical are not available; however, it is probably combustible. (NTP, 1992)

|Warning|H315 (95.69%): Causes skin irritation [Warning Skin corrosion/irritation]|P261, P264, P272, P280, P302+P352, P305+P351+P338, P321, P332+P313, P333+P313, P337+P313, P362, P363, and P501|Aggregated GHS information provided by 539 companies from 7 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Fires involving this material can be controlled with a dry chemical, carbon dioxide or Halon extinguisher. (NTP, 1992)

SMALL SPILLS AND LEAKAGE: If a spill of this chemical occurs, FIRST REMOVE ALL SOURCES OF IGNITION, then you should dampen the solid spill material with acetone and transfer the dampened material to a suitable container. Use absorbent paper dampened with acetone to pick up any remaining material. Seal your contaminated clothing and the absorbent paper in a vapor-tight plastic bag for eventual disposal. Solvent wash all contaminated surfaces with acetone followed by washing with a soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned. STORAGE PRECAUTIONS: You should keep this material in a tightly closed container under an inert atmosphere, and store it at refrigerated temperatures. (NTP, 1992)

RECOMMENDED RESPIRATOR: Where the neat test chemical is weighed and diluted, wear a NIOSH-approved half face respirator equipped with an organic vapor/acid gas cartridge (specific for organic vapors, HCl, acid gas and SO2) with a dust/mist filter. (NTP, 1992)

Drug Information

SYMPTOMS: Symptoms of exposure to this compound may include skin irritation. ACUTE/CHRONIC HAZARDS: When heated to decomposition this compound emits toxic fumes of nitrogen oxides. (NTP, 1992)

EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop. SKIN: IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water. If symptoms such as redness or irritation develop, IMMEDIATELY call a physician and be prepared to transport the victim to a hospital for treatment. INHALATION: IMMEDIATELY leave the contaminated area; take deep breaths of fresh air. If symptoms (such as wheezing, coughing, shortness of breath, or burning in the mouth, throat, or chest) develop, call a physician and be prepared to transport the victim to a hospital. Provide proper respiratory protection to rescuers entering an unknown atmosphere. Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used; if not available, use a level of protection greater than or equal to that advised under Protective Clothing. INGESTION: DO NOT INDUCE VOMITING. If the victim is conscious and not convulsing, give 1 or 2 glasses of water to dilute the chemical and IMMEDIATELY call a hospital or poison control center. Be prepared to transport the victim to a hospital if advised by a physician. If the victim is convulsing or unconscious, do not give anything by mouth, ensure that the victim's airway is open and lay the victim on his/her side with the head lower than the body. DO NOT INDUCE VOMITING. IMMEDIATELY transport the victim to a hospital. (NTP, 1992)

diafen NN

N,N′-Di(2-naphthyl)-p-phenylenediamine Use and Manufacturing

Methods of Manufacturing

Derived from the condensation of p-phenylenediamine and β-naphthol. Add p-phenylenediamine and β-naphthol into the autoclave, and conduct condensation reaction at 260-265°C. After the reaction is over, the reaction product is added to alcohol to reflux, cooled, filtered, washed with ethanol, dried, and crushed to obtain the finished product. Raw material consumption (kg/t) p-phenylenediamine 330 β-naphthol 1100

Uses

The anti-aging agent DNP is one of the important low-toxic antioxidants for rubber and plastic processing. It has heat resistance, anti-aging, anti-copper, manganese and other harmful metal performance characteristics. The anti-aging agent DNP is widely used for copper, manganese and other harmful metal suppression and heat resistance Aging antioxidants have obvious activation effects on thiazole accelerators. It is suitable for industrial rubber products such as cables and elastic rubber and brown or dark-colored latex products. It is a general anti-aging agent for natural rubber and synthetic rubber. It is mainly used as an antioxidant for rubber, latex and plastics. The anti-aging agent DNP is both a chain break inhibitor and a metal complexing agent. It has excellent heat aging resistance, natural aging resistance, and resistance to harmful metals such as copper and manganese. It has anti-ultraviolet light function in styrene butadiene rubber. There is no restorative effect on the latex, and there is no lack of viscosity increase

1,4-Benzenediamine, N1,N4-di-2-naphthalenyl-: ACTIVE

Computed Properties

Molecular Weight:360.4
XLogP3:7.5
Hydrogen Bond Donor Count:2
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:4
Exact Mass:360.162648646
Monoisotopic Mass:360.162648646
Topological Polar Surface Area:24.1
Heavy Atom Count:28
Complexity:439
Covalently-Bonded Unit Count:1
Compound Is Canonicalized:Yes

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