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2-Fluorotoluene

2-Fluorotoluene structure

2-Fluorotoluene 

structure
  • CAS No:

    95-52-3

  • Formula:

    C7H7F

  • Chemical Name:

    2-Fluorotoluene

  • Synonyms:

    Benzene,1-fluoro-2-methyl-;Toluene,o-fluoro-;1-Fluoro-2-methylbenzene;o-Fluorotoluene;2-Fluorotoluene;NSC 8859;Ortho-Fluorotoluene

  • Categories:

    Organic Chemistry  >  Organic Fluorine Compound

Description

clear colorless to slightly yellow liquid


2-fluorotoluene appears as a colorless liquid with an aromatic odor. May sink or float on water. (USCG, 1999)


2-fluorotoluene appears as a colorless liquid with an aromatic odor. May sink or float on water. (USCG, 1999)

2-Fluorotoluene Basic Attributes

110.13

110.13

1853362

202-428-5

L55XKB3K7H

8859

2388

DTXSID7021811

29036990

Characteristics

0

2.73

Clear colorless to slightly yellow Liquid

1.0041 g/cm3 @ Temp: 13.2 °C

-62 °C

115 °C

55 °F

1.477

H2O: immiscible

Flammables area

21 mm Hg ( 20 °C)

3.8 (vs air)

Oral-Wild Bird LD50: 100 mg/kg

Flammable; heat decomposes toxic fluoride gas

1.3%(V)

Highly flammable. Insoluble in water.

Aryl Halides

Highly Flammable

2-FLUOROTOLUENE is of generally low reactivity. Reacts with strong oxidizing agents and strong reducing agents. Also may be incompatible with many amines, nitrides, azo/diazo compounds, alkali metals, and epoxides (USCG, 1999).

Safety Information

II

3

UN 2388 3/PG 2

3

11-36/37/38

16-26-33-36-37/39

XT2579000

F,Xi

Treasury is ventilated, low temperature and dry; stored and transported separately from oxidant

Flammable/Irritant

P210-P261-P301 + P310-P305 + P351 + P338

H225-H301-H315-H319-H335

Special Hazards of Combustion Products: May contain toxic fluoride fumes. Behavior in Fire: Container may explode in heat of fire. Vapor may travel to a source of ignition and flashback. Vapor explosion hazard indoors, outdoors or in sewer. Toxic fluoride fumes may be produced. (USCG, 1999)|Flammable - 3rd degree

|Danger|H225 (100%): Highly Flammable liquid and vapor [Danger Flammable liquids]|P210, P233, P240, P241, P242, P243, P261, P264, P270, P271, P280, P301+P310, P302+P352, P303+P361+P353, P304+P312, P304+P340, P305+P351+P338, P312, P321, P330, P332+P313, P337+P313, P362, P370+P378, P403+P233, P403+P235, P405, and P501|Aggregated GHS information provided by 272 companies from 15 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Fire Extinguishing Agents: Dry chemical, CO 2 , or foam (USCG, 1999)

Excerpt from ERG Guide 130 [Flammable Liquids (Water-Immiscible / Noxious)]: As an immediate precautionary measure, isolate spill or leak area for at least 50 meters (150 feet) in all directions. LARGE SPILL: Consider initial downwind evacuation for at least 300 meters (1000 feet). FIRE: If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2016)

Excerpt from ERG Guide 130 [Flammable Liquids (Water-Immiscible / Noxious)]: ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). All equipment used when handling the product must be grounded. Do not touch or walk through spilled material. Stop leak if you can do it without risk. Prevent entry into waterways, sewers, basements or confined areas. A vapor-suppressing foam may be used to reduce vapors. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. Use clean, non-sparking tools to collect absorbed material. LARGE SPILL: Dike far ahead of liquid spill for later disposal. Water spray may reduce vapor, but may not prevent ignition in closed spaces. (ERG, 2016)

Wear self-contained positive pressure breathing apparatus and full protective clothing. (USCG, 1999)

Toxicity

practically nontoxic

Drug Information

Inhalation of vapor may cause respiratory irritation. Prolonged and repeated vapor exposures may produce systemic toxic effects. (USCG, 1999)

INHALATION: Move to fresh air. If breathing has stopped, give artificial respiration. If breathing is difficult, give oxygen. EYES OR SKIN: Flush with running water for at least 15 min.; hold eyelids open if necessary. Remove and isolate contaminated clothing and shoes at the site. INGESTION: DO NOT INDUCE VOMITING. If victim is unconscious or having convulsions, do nothing except keep victim warm. (USCG, 1999)

2-fluorotoluene

2-Fluorotoluene Use and Manufacturing

Uses

Used as medicine and pesticide intermediate

Benzene, 1-fluoro-2-methyl-: ACTIVE

Fire Hazards -> Flammable - 3rd degree

Computed Properties

Molecular Weight:110.13
XLogP3:2.9
Hydrogen Bond Acceptor Count:1
Exact Mass:110.053178385
Monoisotopic Mass:110.053178385
Heavy Atom Count:8
Complexity:70.8
Covalently-Bonded Unit Count:1
Compound Is Canonicalized:Yes

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