Aluminum oleate
-
Aluminum oleate
structure -
-
CAS No:
688-37-9
-
Formula:
C18H34O2.1/3Al
-
Chemical Name:
Aluminum oleate
-
Synonyms:
9-Octadecenoic acid (9Z)-,aluminum salt (3:1);Oleic acid,aluminum salt;9-Octadecenoic acid (Z)-,aluminum salt;9-Octadecenoic acid (9Z)-,aluminum salt;Aluminum oleate;Aluminum trioleate
-
CAS No:
Description
Yellowish-white, viscous mass. Insoluble in water; soluble in alcohol, benzene, ether, oil, and turpentine. Combustible.
Characteristics
78.90000
18.09420
1.010
120℃ [KIR78]
360ºC at 760 mmHg
270.1ºC
insoluble H2O; soluble alcohol, benzene, ethanol, oil, turpentine [MER06]
Extremely reactive with air, moisture and compounds containing active hydrogen and therefore must be kept under a blanket of inert gas. /Aluminum alkyls/|In general, materials ... toxic as stored or which can decompose into toxic components ... Should be stored in cool ... ventilated place, out of ... sun, away from ... fire hazard ... be periodically inspected and monitored. Incompatible materials should be isolated ...|All possibility of contact with water must be avoided. Solution containing not more than 20% of these compounds in non-reactive solvents, however, can be handled without risk of spontaneous ignition. /Aluminum alkyls/|Must be stored in an inert atmosphere; sensitive to oxidation and hydrolysis in air. /Trialkylaluminums/|Separate from air, water, halocarbons, alcohols. Store in a cool, dry, well-ventilated location. Outside or detached storage is preferred. Inside storage should be in a standard flammable liquid storage warehouse, room, or cabinet. /Aluminum alkyls/
White powder, existence doubted except as basic salt /commercial product/|Soluble in hot water /commercial product/|Insoluble in alcohol /commercial product/
Safety Information
Low melting solids or colorless, volatile liquids. /Alkylaluminum halides/
Aluminum compounds are treated under anhydrous conditions to prevent violent reactions, recover solvent, and form Al compounds suitable for landfill by reaction with anhydrous hydrolysis agent, eg calcium hydroxide. /Aluminum compounds/|SRP: The most favorable course of action is to use an alternative chemical product with less inherent propensity for occupational exposure or environmental contamination. Recycle any unused portion of the material for its approved use or return it to the manufacturer or supplier. Ultimate disposal of the chemical must consider: the material's impact on air quality; potential migration in soil or water; effects on animal, aquatic, and plant life; and conformance with environmental and public health regulations.
Extremely reactive with air, moisture, and compounds containing active hydrogen... /Alkyl aluminum compounds/|Reacts violently with a broad range of materials including air & water. /Aluminum alkyls/
Substances migrating to food from paper and paperboard products used in food packaging that are generally recognized as safe for their intended use, within section 409 of the Act. Aluminum oleate is included on this list.|Fatty acids derived from animal or vegetable fats and oils; and salts or such acids, single or mixed are indirect food additives for use only as a component of adhesives. /Fatty acid aluminum salts/
Wear appropriate personal protective clothing to prevent skin contact. /Aluminum (soluble salts and alkyls, as Al/|Wear appropriate eye protection to prevent eye contact. /Aluminum (soluble salts and alkyls, as Al)/|Protective clothing and a high standard of training in the necessary precautionary measures are essential for the handling of the materials. /Aluminum alkyls/
Certain polymerization catalysts, such as aluminum alkyls, react & burn violently on contact with water. /Aluminum alkyls/|Aluminum alkyls are organic aluminum compounds that are highly reactive and dangerous because of spontaneous burning in air. /Aluminum alkyls/|Prophoric material in flammable solvent. Vapors are heavier than air & may travel to a source of ignition & flash back. /Aluminum alkyls/
...Violently explosive when they come into contact with water. /Aluminum alkyls/
Stop flow of liquid before extinguishing fire. Use dry chemical or carbon dioxide. DO NOT use water as straight stream directly on spilled material. Water fog can be used to control fire. DO NOT use halogenated extinguishing agents on spilled material. Violent reaction may result. Use water spray to keep fire-exposed containers cool. Fight fire from protected location or maximum possible distance. /Aluminum Alkyls/
SRP: The scientific literature for the use of contact lenses in industry is conflicting. The benefit or detrimental effects of wearing contact lenses depend not only upon the substance, but also on factors including the form of the substance, characteristics and duration of the exposure, the uses of other eye protection equipment, and the hygiene of the lenses. However, there may be individual substances whose irritating or corrosive properties are such that the wearing of contact lenses would be harmful to the eye. In those specific cases, contact lenses should not be worn. In any event, the usual eye protection equipment should be worn even when contact lenses are in place.|Work clothing that becomes wet or significantly contaminated should be removed and replaced. /Aluminum (soluble salts and alkyls, as Al)/|Workers whose clothing may have become contaminated should change into uncontaminated clothing before leaving the work premises. /Aluminum (soluble salts and alkyls, as Al)/|The worker should immediately wash the skin when it becomes contaminated. /Aluminum (soluble salts and alkyls, as Al)/|SRP: Contaminated protective clothing should be segregated in such a manner so that there is no direct personal contact by personnel who handle, dispose, or clean the clothing. Quality assurance to ascertain the completeness of the cleaning procedures should be implemented before the decontaminated protective clothing is returned for reuse by the workers. Contaminated clothing should not be taken home at end of shift, but should remain at employee's place of work for cleaning.
/GUIDE 135: SUBSTANCES - SPONTANEOUSLY COMBUSTIBLE/ Fire or Explosion: Flammable/combustible material. May ignite on contact with moist air or moisture. May burn rapidly with flare-burning effect. Some react vigorously or explosively on contact with water. Some may decompose explosively when heated or involved in a fire. May re-ignite after fire is extinguished. Runoff may create fire or explosion hazard. Containers may explode when heated. /Aluminum alkyls/|/GUIDE 135: SUBSTANCES - SPONTANEOUSLY COMBUSTIBLE/ Health: Fire will produce irritating, corrosive and/or toxic gases. Inhalation of decomposition products may cause severe injury or death. Contact with substance may cause severe burns to skin and eyes. Runoff from fire control may cause pollution. /Aluminum alkyls/|/GUIDE 135: SUBSTANCES - SPONTANEOUSLY COMBUSTIBLE/ Public Safety: CALL Emergency Response Telephone Number ... . As an immediate precautionary measure, isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids. Stay upwind. Keep unauthorized personnel away. Keep out of low areas. /Aluminum alkyls/|/GUIDE 135: SUBSTANCES - SPONTANEOUSLY COMBUSTIBLE/ Protective Clothing: Wear positive pressure self-contained breathing apparatus (SCBA). Wear chemical protective clothing that is specifically recommended by the manufacturer. It may provide little or no thermal protection. Structural firefighters' protective clothing will only provide limited protection. /Aluminum alkyls/|For more DOT Emergency Guidelines (Complete) data for ALUMINUM OLEATE (8 total), please visit the HSDB record page.
The International Maritime Dangerous Goods Code lays down basic principles for transporting hazardous chemicals. Detailed recommendations for individual substances and a number of recommendations for good practice are included in the classes dealing with such substances. A general index of technical names has also been compiled. This index should always be consulted when attempting to locate the appropriate procedures to be used when shipping any substance or article.|The International Air Transport Association (IATA) Dangerous Goods Regulations are published by the IATA Dangerous Goods Board pursuant to IATA Resolutions 618 and 619 and constitute a manual of industry carrier regulations to be followed by all IATA Member airlines when transporting hazardous materials.|No person may /transport,/ offer or accept a hazardous material for transportation in commerce unless that person is registered in conformance ... and the hazardous material is properly classed, described, packaged, marked, labeled, and in condition for shipment as required or authorized by ... /the hazardous materials regulations (49 CFR 171-177)./
Irritation of the eyes has been noted in patients who have been exposed /to aluminum alkyls/. /Aluminum alkyls/|May cause minor irritation to lungs or eyes. /Aluminum (dust or powder)/
Recommended Exposure Limit: 10-Hr Time-Weighted Avg: 10 mg/cu m (total). /Aluminum/|Recommended Exposure Limit: 10 Hr Time-Weighted Avg: 5 mg/cu m (resp). /Aluminum/|Recommended Exposure Limit: 10 Hr Time-Weighted Avg: 2 mg/cu m. /Aluminum (soluble salts and alkyls, as Al)/|Recommended Exposure Limit: 10 Hr Time-Weighted Avg: 5 mg/cu m. /Aluminum (pyro powders and welding fumes, as Al)/
Aluminum oleate Use and Manufacturing
By heating aluminum hydroxide, water, and oleic acid. The resultant mixture is filtered and dried.
In oil or turpentine solution as lacquer for metals, as size, waterproofing agent, drier, for paints, high-pressure and high-temp greases for thickening lubricating oils.
White powder, existence doubted except as basic salt /commercial product/
Computed Properties
Molecular Weight:871.3
Hydrogen Bond Acceptor Count:6
Rotatable Bond Count:42
Exact Mass:870.7257043
Monoisotopic Mass:870.7257043
Topological Polar Surface Area:120
Heavy Atom Count:61
Complexity:228
Undefined Bond Stereocenter Count:3
Covalently-Bonded Unit Count:4
Compound Is Canonicalized:Yes
Learn More Other Chemicals
-
Quino[2,3-b]acridine-2,9-disulfonic acid, 5,7,12,14-tetrahydro-7,14-dioxo-, aluminum salt (3:2)
19795-24-5
-
Aluminum zinc oxide (Al2ZnO4)
12068-53-0
-
1,2-Benzenedicarboxylic acid, 1-tridecyl ester, aluminum salt (3:1)
67952-97-0
-
Phenol, 2,3,4,5,6-pentabromo-, aluminum salt (3:1) Formula
68084-29-7
-
Hexadecanoic acid, aluminum salt, basic Formula
101012-91-3
-
Aluminum barium oxide (Al10BaO16) Formula
97435-20-6
-
Telluric acid (H2TeO4), aluminum salt (3:2) Structure
25268-69-3
-
Silicic acid, aluminum silver salt Structure
63939-08-2
-
What is Aluminum tungsten oxide (Al2W3O12)
15123-82-7
-
What is Aluminum phosphate (Al2(HPO4)3)
13530-54-6