Tributylstannane
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Tributylstannane
structure -
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CAS No:
688-73-3
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Formula:
C12H28Sn
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Chemical Name:
Tributylstannane
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Synonyms:
Stannane,tributyl-;Tributyltin hydride;Tributylstannane;Tributylstannic hydride;Tri-n-butyltin hydride;Tributylstannyl hydride;Tri-n-butylstannane;Hydridotris(butyl)tin;SnH(butyl)3;30115-44-7
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CAS No:
Characteristics
0
4.88150
1.103 g/cm3 @ Temp: 20 °C
<0ºC
76-81 °C @ Press: 0.7-0.9 Torr
124.0±18.7 °C
n20/D 1.473(lit.)
REACTS
5 hPa (20 °C)
Safety Information
II
6.1
UN 1993 3/PG 3
3
R10;R15;R21;R25;R36/38;R48/23/25;R50/53
S35-S36/37/39-S45-S60-S61-S62-S36/37-S33-S26-S16
WH8675000
T:Toxic;N:Dangerousfortheenvironment;
P210, P233, P240, P241, P242, P243, P260, P264, P270, P273, P280, P301+P310, P302+P352, P303+P361+P353, P305+P351+P338, P312, P314, P321, P322, P330, P332+P313, P337+P313, P362, P363, P370+P378, P391, P403+P235, P405, P501
H226
Tributylstannane Use and Manufacturing
Tributyltin hydride (TBTH) is as a reagent for the reductive ionic 1,5-cyclization of 3-azamuconoates (3-azahexa-2,4-dienedioates).
Tributyltin hydride can also mediate cyclisation of unsaturated ethers and amines bearing an aldehyde or α,β-unsaturated ketone group.
Tributyltin hydride is also a reducing agent for the reduction of nitroalkenes.
A widely used radical reagent used in reductive cleavage,1 radical dehalogenation, and intramolecular radical cyclization.2
Computed Properties
Molecular Weight:291.06
Rotatable Bond Count:9
Exact Mass:292.121303
Monoisotopic Mass:292.121303
Heavy Atom Count:13
Complexity:72.1
Covalently-Bonded Unit Count:1
Compound Is Canonicalized:Yes
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