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Tributylstannane

Tributylstannane structure

Tributylstannane 

structure
  • CAS No:

    688-73-3

  • Formula:

    C12H28Sn

  • Chemical Name:

    Tributylstannane

  • Synonyms:

    Stannane,tributyl-;Tributyltin hydride;Tributylstannane;Tributylstannic hydride;Tri-n-butyltin hydride;Tributylstannyl hydride;Tri-n-butylstannane;Hydridotris(butyl)tin;SnH(butyl)3;30115-44-7

  • Categories:

    Organic Chemistry  >  Organosulfur Compounds

Description

clear colourless liquid


Tributylstannane is an organotin compound.

Tributylstannane Basic Attributes

291.061

291.06

211-704-4

2931900090

Characteristics

0

4.88150

1.103 g/cm3 @ Temp: 20 °C

<0ºC

76-81 °C @ Press: 0.7-0.9 Torr

124.0±18.7 °C

n20/D 1.473(lit.)

REACTS

5 hPa (20 °C)

Safety Information

II

6.1

UN 1993 3/PG 3

3

R10;R15;R21;R25;R36/38;R48/23/25;R50/53

S35-S36/37/39-S45-S60-S61-S62-S36/37-S33-S26-S16

WH8675000

T:Toxic;N:Dangerousfortheenvironment;

P210, P233, P240, P241, P242, P243, P260, P264, P270, P273, P280, P301+P310, P302+P352, P303+P361+P353, P305+P351+P338, P312, P314, P321, P322, P330, P332+P313, P337+P313, P362, P363, P370+P378, P391, P403+P235, P405, P501

H226

Drug Information

TBTC chloride

Tributylstannane Use and Manufacturing

Tributyltin hydride (TBTH) is as a reagent for the reductive ionic 1,5-cyclization of 3-azamuconoates (3-azahexa-2,4-dienedioates).

Tributyltin hydride can also mediate cyclisation of unsaturated ethers and amines bearing an aldehyde or α,β-unsaturated ketone group.

Tributyltin hydride is also a reducing agent for the reduction of nitroalkenes.
A widely used radical reagent used in reductive cleavage,1 radical dehalogenation, and intramolecular radical cyclization.2

Computed Properties

Molecular Weight:291.06
Rotatable Bond Count:9
Exact Mass:292.121303
Monoisotopic Mass:292.121303
Heavy Atom Count:13
Complexity:72.1
Covalently-Bonded Unit Count:1
Compound Is Canonicalized:Yes

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