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Home > Encyclopedia > (2-Hydroxyethyl)ethylenediamine

(2-Hydroxyethyl)ethylenediamine

(2-Hydroxyethyl)ethylenediamine structure

(2-Hydroxyethyl)ethylenediamine 

structure
  • CAS No:

    111-41-1

  • Formula:

    C4H12N2O

  • Chemical Name:

    (2-Hydroxyethyl)ethylenediamine

  • Synonyms:

    Ethanol,2-[(2-aminoethyl)amino]-;2-[(2-Aminoethyl)amino]ethanol;N-Hydroxyethyl-1,2-ethanediamine;N-(β-Hydroxyethyl)ethylenediamine;N-(Hydroxyethyl)ethylenediamine;(β-Hydroxyethyl)ethylenediamine;N-(2-Aminoethyl)ethanolamine;N-(β-Aminoethyl)ethanolamine;N-(2-Hydroxyethyl)ethylenediamine;(2-Hydroxyethyl)ethylenediamine;N-(2-Hydroxyethyl)-1,2-ethanediamine;1-(2-Hydroxyethylamino)-2-aminoethane;2-(2-Hydroxyethylamino)ethylamine;N-(2′-Hydroxyethyl)ethylenediamine;2-(2′-Aminoethylamino)ethanol;N-(β-Hydroxyethyl)-1,2-ethanediamine;N-(2-Hydroxyethyl)-1,2-ethylenediamine;A-EA;NSC 461;Amino Alcohol EA;1-Aminooxyethylamine;Aminoethylethanolamine;N-(2-Hydroxyethyl)-1,2-diaminoethane;2-[(Aminoethyl)amino]ethanol;2-(2-Aminoethylamino)-1-ethanol;51251-98-0

  • Categories:

    Organic Chemistry  >  Amides

Description

CLEAR VISCOUS LIQUID Aminoethylethanolamine is combustible, colorless, liquid with an ammonia-like odor.A clear colorless liquid with an ammonia-like odor. Corrosive to tissue. Combustible, but may be difficult to ignite. Less dense than water. Vapors heavier than air. Toxic oxides of nitrogen produced during combustion. Used to make other chemicals.


Aminoethylethanolamine appears as a clear colorless liquid with an ammonia-like odor. Corrosive to tissue. Combustible, but may be difficult to ignite. Less dense than water. Vapors heavier than air. Toxic oxides of nitrogen produced during combustion. Used to make other chemicals.|Liquid|A clear colorless liquid with an ammonia-like odor.


Aminoethylethanolamine appears as a clear colorless liquid with an ammonia-like odor. Corrosive to tissue. Combustible, but may be difficult to ignite. Less dense than water. Vapors heavier than air. Toxic oxides of nitrogen produced during combustion. Used to make other chemicals.

(2-Hydroxyethyl)ethylenediamine Basic Attributes

104.15

104.15

506012

203-867-5

RC78W6NPXT

461

2735

DTXSID7025423

29221980

Characteristics

58.3

-1.7

Aminoethylethanolamine appears as a clear colorless liquid with an ammonia-like odor. Corrosive to tissue. Combustible, but may be difficult to ignite. Less dense than water. Vapors heavier than air. Toxic oxides of nitrogen produced during combustion. Used to make other chemicals.

1.0254 g/cm3 @ Temp: 25 °C

-38 °C

40-238 °C

>230 °F

n 20/D 1.485(lit.)

soluble

Store below +30°C.

<0.01 hPa (20 °C)

3.6 (vs air)

Oral-rat LD50: 3000 mg/kg; Oral-Mouse LD50:3550 mg/kg

Flammable; nitrocellulose exposed to large surface area catches fire; burning produces toxic nitrogen oxide fumes

3.3-10.1%(V)

MILD AMMONIACAL ODOR

Water soluble. Hygroscopic.

Alcohols and Polyols

AMINOETHYLETHANOLAMINE is an amine and alcohol. Amines are chemical bases. They neutralize acids to form salts plus water. These acid-base reactions are exothermic. The amount of heat that is evolved per mole of amine in a neutralization is largely independent of the strength of the amine as a base. Amines may be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen is generated by amines in combination with strong reducing agents, such as hydrides. This chemical is hygroscopic.

695 °F (USCG, 1999)

Safety Information

II

8

UN 2735 8/PG 2

1

34-43-61-62

26-36/37/39-45-53-28A

KJ6300000

C,T

Warehouse ventilated, low temperature and dry

Stable under normal temperatures and pressures.

P201, P202, P260, P261, P264, P272, P280, P281, P301+P330+P331, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P308+P313, P310, P321, P333+P313, P363, P405, P501

H314

This chemical is combustible. (NTP, 1992)

|Danger|H314: Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]|P201, P202, P260, P261, P264, P272, P280, P281, P301+P330+P331, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P308+P313, P310, P321, P333+P313, P363, P405, and P501|H290 (13.87%): May be corrosive to metals [Warning Corrosive to Metals]|P201, P202, P234, P260, P261, P264, P271, P272, P280, P281, P301+P330+P331, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P308+P313, P310, P312, P321, P333+P313, P363, P390, P403+P233, P404, P405, and P501|Aggregated GHS information provided by 3215 companies from 36 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.|P201, P202, P260, P261, P264, P272, P280, P281, P285, P301+P330+P331, P302+P352, P303+P361+P353, P304+P340, P304+P341, P305+P351+P338, P308+P313, P310, P314, P321, P333+P313, P342+P311, P363, P405, and P501

Excerpt from ERG Guide 153 [Substances - Toxic and/or Corrosive (Combustible)]: SMALL FIRE: Dry chemical, CO2 or water spray. LARGE FIRE: Dry chemical, CO2, alcohol-resistant foam or water spray. Move containers from fire area if you can do it without risk. Dike fire-control water for later disposal; do not scatter the material. FIRE INVOLVING TANKS OR CAR/TRAILER LOADS: Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. Do not get water inside containers. Cool containers with flooding quantities of water until well after fire is out. Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. ALWAYS stay away from tanks engulfed in fire. (ERG, 2016)

Excerpt from ERG Guide 153 [Substances - Toxic and/or Corrosive (Combustible)]: As an immediate precautionary measure, isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids. SPILL: Increase, in the downwind direction, as necessary, the isolation distance shown above. FIRE: If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2016)

Excerpt from ERG Guide 153 [Substances - Toxic and/or Corrosive (Combustible)]: ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Stop leak if you can do it without risk. Prevent entry into waterways, sewers, basements or confined areas. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. DO NOT GET WATER INSIDE CONTAINERS. (ERG, 2016)

Goggles or face shield, protective clothing (USCG, 1999)

| 3 - Materials that, under emergency conditions, can cause serious or permanent injury.| 1 - Materials that must be preheated before ignition can occur. Materials require considerable preheating, under all ambient temperature conditions, before ignition and combustion can occur.| 0 - Materials that in themselves are normally stable, even under fire conditions.

Toxicity

moderately toxic

2.88

Drug Information

Skin contact will cause mild irritation; eye contact will cause more severe irritation. (USCG, 1999)|Corrosives

EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop. SKIN: IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water. If symptoms such as redness or irritation develop, IMMEDIATELY call a physician and be prepared to transport the victim to a hospital for treatment. INHALATION: IMMEDIATELY leave the contaminated area; take deep breaths of fresh air. If symptoms (such as wheezing, coughing, shortness of breath, or burning in the mouth, throat, or chest) develop, call a physician and be prepared to transport the victim to a hospital. Provide proper respiratory protection to rescuers entering an unknown atmosphere. Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used; if not available, use a level of protection greater than or equal to that advised under Protective Clothing. INGESTION: DO NOT INDUCE VOMITING. If the victim is conscious and not convulsing, give 1 or 2 glasses of water to dilute the chemical and IMMEDIATELY call a hospital or poison control center. Be prepared to transport the victim to a hospital if advised by a physician. If the victim is convulsing or unconscious, do not give anything by mouth, ensure that the victim's airway is open and lay the victim on his/her side with the head lower than the body. DO NOT INDUCE VOMITING. IMMEDIATELY transport the victim to a hospital. (NTP, 1992)

aminoethylethanolamine

(2-Hydroxyethyl)ethylenediamine Use and Manufacturing

Methods of Manufacturing

Derived from ethylenediamine and ethylene oxide.

Uses

Textile finishing compounds (antifuming agents, dyestuffs, cationic surfactants), resins, rubber products, insecticides, and certain medicinals.


Corrosion inhibitors and anti-scaling agents


Paper products

Production

10,000,000 - 50,000,000 lb

Adhesive manufacturing|Ethanol, 2-[(2-aminoethyl)amino]-: ACTIVE

Health Hazards -> Corrosives

Computed Properties

Molecular Weight:104.15
XLogP3:-1.7
Hydrogen Bond Donor Count:3
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:4
Exact Mass:104.094963011
Monoisotopic Mass:104.094963011
Topological Polar Surface Area:58.3
Heavy Atom Count:7
Complexity:32.9
Covalently-Bonded Unit Count:1
Compound Is Canonicalized:Yes

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