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Home > Encyclopedia > 1-Methyl-2,8,9-trioxa-5-aza-1-silabicyclo[3.3.3]undecane

1-Methyl-2,8,9-trioxa-5-aza-1-silabicyclo[3.3.3]undecane

1-Methyl-2,8,9-trioxa-5-aza-1-silabicyclo[3.3.3]undecane structure

1-Methyl-2,8,9-trioxa-5-aza-1-silabicyclo[3.3.3]undecane 

structure
  • CAS No:

    2288-13-3

  • Formula:

    C7H15NO3Si

  • Chemical Name:

    1-Methyl-2,8,9-trioxa-5-aza-1-silabicyclo[3.3.3]undecane

  • Synonyms:

    2,8,9-Trioxa-5-aza-1-silabicyclo[3.3.3]undecane,1-methyl-;1-Methyl-2,8,9-trioxa-5-aza-1-silabicyclo[3.3.3]undecane;Methylsilatrane;1-Methylsilatrane

  • Categories:

    Organic Chemistry  >  Coordination Complexes

Description

PHYSICAL DESCRIPTION: White crystals or granular solid with a slight odor. (NTP, 1992)


Methylsilatrane appears as white crystals or granular solid with a slight odor. (NTP, 1992)


Methylsilatrane appears as white crystals or granular solid with a slight odor. (NTP, 1992)

1-Methyl-2,8,9-trioxa-5-aza-1-silabicyclo[3.3.3]undecane Basic Attributes

189.286

189.28

218-928-1

98BUR3AW0M

DTXSID4025660

2934999090

Characteristics

30.9

0.00

Methylsilatrane appears as white crystals or granular solid with a slight odor. (NTP, 1992)

1.1±0.1 g/cm3

152 °C

174 °C @ Press: 31 Torr

greater than 305.6° F (NTP, 1992)

1.485

less than 1 mg/mL at 68.9° F (NTP, 1992)

greater than 1 (NTP, 1992) (Relative to Air)

Insoluble in water.

Amines, Phosphines, and Pyridines

METHYLSILATRANE is incompatible with strong oxidizing materials. (NTP, 1992)

Safety Information

R22

26-36

P261, P264, P271, P280, P302+P352, P304+P340, P305+P351+P338, P312, P321, P332+P313, P337+P313, P362, P403+P233, P405, P501

H315

This chemical is probably combustible. (NTP, 1992)

|Warning|H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]|P261, P264, P271, P280, P302+P352, P304+P340, P305+P351+P338, P312, P321, P332+P313, P337+P313, P362, P403+P233, P405, and P501|Aggregated GHS information provided by 13 companies from 1 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Fires involving this material can be controlled with a dry chemical, carbon dioxide or Halon extinguisher. (NTP, 1992)

SMALL SPILLS AND LEAKAGE: If you spill this chemical, you should dampen the solid spill material with water, then transfer the dampened material to a suitable container. Use absorbent paper dampened with water to pick up any remaining material. Seal your contaminated clothing and the absorbent paper in a vapor-tight plastic bag for eventual disposal. Wash all contaminated surfaces with a soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned. STORAGE PRECAUTIONS: You should store this material under ambient temperatures. (NTP, 1992)

RECOMMENDED RESPIRATOR: Where the neat test chemical is weighed and diluted, wear a NIOSH-approved half face respirator equipped with an organic vapor/acid gas cartridge (specific for organic vapors, HCl, acid gas and SO2) with a dust/mist filter. (NTP, 1992)

Drug Information

SYMPTOMS: This chemical may cause irritation of the eyes and skin. ACUTE/CHRONIC HAZARDS: When heated to decomposition this compound emits irritating fumes and toxic fumes of silicon oxide and carbon dioxide, and traces of incompletely burned carbon products. (NTP, 1992)

EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop. SKIN: IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water. If symptoms such as redness or irritation develop, IMMEDIATELY call a physician and be prepared to transport the victim to a hospital for treatment. INHALATION: IMMEDIATELY leave the contaminated area; take deep breaths of fresh air. If symptoms (such as wheezing, coughing, shortness of breath, or burning in the mouth, throat, or chest) develop, call a physician and be prepared to transport the victim to a hospital. Provide proper respiratory protection to rescuers entering an unknown atmosphere. Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used; if not available, use a level of protection greater than or equal to that advised under Protective Clothing. INGESTION: DO NOT INDUCE VOMITING. If the victim is conscious and not convulsing, give 1 or 2 glasses of water to dilute the chemical and IMMEDIATELY call a hospital or poison control center. Be prepared to transport the victim to a hospital if advised by a physician. If the victim is convulsing or unconscious, do not give anything by mouth, ensure that the victim's airway is open and lay the victim on his/her side with the head lower than the body. DO NOT INDUCE VOMITING. IMMEDIATELY transport the victim to a hospital. (NTP, 1992)

1-Methyl-2,8,9-trioxa-5-aza-1-silabicyclo[3.3.3]undecane Use and Manufacturing

2,8,9-Trioxa-5-aza-1-silabicyclo[3.3.3]undecane, 1-methyl-: ACTIVE

Computed Properties

Molecular Weight:189.28
Hydrogen Bond Acceptor Count:4
Exact Mass:189.08211987
Monoisotopic Mass:189.08211987
Topological Polar Surface Area:30.9
Heavy Atom Count:12
Complexity:140
Covalently-Bonded Unit Count:1
Compound Is Canonicalized:Yes

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