9,10-Dihydro-9,10-dioxo-1,5-anthracenedisulfonic acid
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9,10-Dihydro-9,10-dioxo-1,5-anthracenedisulfonic acid
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CAS No:
117-14-6
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Formula:
C14H8O8S2
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Chemical Name:
9,10-Dihydro-9,10-dioxo-1,5-anthracenedisulfonic acid
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Synonyms:
1,5-Anthracenedisulfonic acid,9,10-dihydro-9,10-dioxo-;1,5-Anthraquinonedisulfonic acid;9,10-Dihydro-9,10-dioxo-1,5-anthracenedisulfonic acid;1,5-Disulfoanthraquinone;Anthraquinonone-1,5-disulfonic acid;9,10-Anthraquinone-1,5-disulfonate;NSC 201;9,10-Anthraquinone-1,5-disulfonic acid
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CAS No:
9,10-Dihydro-9,10-dioxo-1,5-anthracenedisulfonic acid Basic Attributes
368.34
368.34
204-177-7
5461Q8F687
201
DTXSID1059448
2914399090
Characteristics
159.64000
3.11700
1.8 g/cm3
310~311℃
1.705
1.81 M
Oral-rat LD50: 2357 mg/kg; Oral-Mouse LD50: 2357 mg/kg
Flammable; burning produces toxic sulfur oxide fumes
9,10-Dihydro-9,10-dioxo-1,5-anthracenedisulfonic acid Use and Manufacturing
Using anthraquinone as a raw material, it is sulfonated step by step in the presence of mercury sulfate to simultaneously generate 1, 5-disulfonic acid and 1, 8-disulfonic acid. The resulting sulfonate is diluted with sulfuric acid, and its solubility in sulfuric acid is different. Separation. Operation example Add 270kg of anthraquinone and 630kg of 34% fuming sulfuric acid (containing 2.7kg of metallic mercury) into the sulfonation pot, heat it to 120-125°C and keep it for 4h. After heat preservation, the temperature is lowered to 100°C, and 180kg of 96% sulfuric acid is added. After adding, press the material into the glass-lined pot. Add 360kg of 78% sulfuric acid at 75°C, add it in 1h, cool down to 55°C within 4h, keep for 1h, so that anthraquinone-1, 5-disulfonic acid is completely precipitated. After filtering, the filter cake is washed twice with 240L of 78% sulfuric acid. The filter cake is a finished product of anthraquinone-1, 5-disulfonic acid. The filtrate and washing liquid are combined to produce anthraquinone 1, 8-disulfonic acid. Raw material consumption quota: anthraquinone (98%) 1498kg/t, sulfuric acid (65%) 1206kg/t, oleum (SO320%) 2407kg/t.
Dye intermediate. Used to produce anthraquinone disperse dyes and acid dyes, such as Disperse Blue 2BLN and acid anthraquinone sky blue.
1,5-Anthracenedisulfonic acid, 9,10-dihydro-9,10-dioxo-: ACTIVE
Computed Properties
Molecular Weight:368.3
XLogP3:0.4
Hydrogen Bond Donor Count:2
Hydrogen Bond Acceptor Count:8
Rotatable Bond Count:2
Exact Mass:367.96605956
Monoisotopic Mass:367.96605956
Topological Polar Surface Area:160
Heavy Atom Count:24
Complexity:692
Covalently-Bonded Unit Count:1
Compound Is Canonicalized:Yes
Recommended Suppliers of 9,10-Dihydro-9,10-dioxo-1,5-anthracenedisulfonic acid
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