Benzenamine, 4-methyl-, hydrochloride (1:1)
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Benzenamine, 4-methyl-, hydrochloride (1:1)
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CAS No:
540-23-8
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Formula:
C7H9N.ClH
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Chemical Name:
Benzenamine, 4-methyl-, hydrochloride (1:1)
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Synonyms:
Benzenamine,4-methyl-,hydrochloride (1:1);p-Toluidine,hydrochloride;Benzenamine,4-methyl-,hydrochloride;4-Methylaniline hydrochloride;p-Toluidinium chloride;4-Aminotoluene hydrochloride;p-Methylanilinium chloride;4-Methylanilinium chloride;p-Methylaniline hydrochloride;4-Methylphenylammonium chloride;4-Methylbenzenamine hydrochloride
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CAS No:
Description
white to light beige crystalline powder, crystals
P-toluidine hydrochloride appears as off-white to grayish-white crystals. (NTP, 1992)
P-toluidine hydrochloride appears as off-white to grayish-white crystals. (NTP, 1992)
Benzenamine, 4-methyl-, hydrochloride (1:1) Basic Attributes
143.61
143.05000
208-740-8
PT5II901IF
DTXSID2021365
2921430090
Characteristics
26.02000
2.96040
P-toluidine hydrochloride appears as off-white to grayish-white crystals. (NTP, 1992)
1.193 g/cm3
243 °C
200.4ºC
greater than or equal to 100 mg/mL at 68° F (NTP, 1992)
Store below +30°C.
Oral-rat LD50: 1285 mg/kg; Oral-Mouse LD50: 1100 mg/kg
Open flame is flammable; liberates toxic aniline gas in case of heat
Water soluble. May be sensitive to moisture.
Salts, Acidic
P-TOLUIDINE HYDROCHLORIDE reacts with oxidizing and alkali materials. (NTP, 1992).
Safety Information
II
6.1(a)
UN 2811 6.1/PG 1
3
23/24/25-36-40-43-50
28-36/37-45-61
XU7525000
T,N
The warehouse is ventilated, low temperature and dry; stored and transported separately from food materials
P261-P273-P280-P301 + P310-P305 + P351 + P338-P311
H301-H311-H317-H319-H331-H351-H400
Flash point data for this chemical are not available, but it is probably combustible. (NTP, 1992)
|Danger|H301 (97.44%): Toxic if swallowed [Danger Acute toxicity, oral]|P201, P202, P261, P264, P270, P271, P272, P273, P280, P281, P301+P310, P302+P352, P304+P340, P305+P351+P338, P308+P313, P311, P312, P321, P322, P330, P333+P313, P337+P313, P361, P363, P391, P403+P233, P405, and P501|Aggregated GHS information provided by 39 companies from 2 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.|H301: Toxic if swallowed [Danger Acute toxicity, oral]
Fires involving this compound should be controlled with a dry chemical, carbon dioxide or Halon extinguisher. (NTP, 1992)
SMALL SPILLS AND LEAKAGE: If you spill this chemical, you should dampen the solid spill material with water, then transfer the dampened material to a suitable container. Use absorbent paper dampened with water to pick up any remaining material. Seal your contaminated clothing and the absorbent paper in a vapor-tight plastic bag for eventual disposal. Wash all contaminated surfaces with a soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned. STORAGE PRECAUTIONS: You should store this chemical under refrigerated temperatures, protect from moisture and keep it away from oxidizing materials. (NTP, 1992)
RECOMMENDED RESPIRATOR: Where the neat test chemical is weighed and diluted, wear a NIOSH-approved half face respirator equipped with an organic vapor/acid gas cartridge (specific for organic vapors, HCl, acid gas and SO2) with a dust/mist filter. (NTP, 1992)
Drug Information
SYMPTOMS: Symptoms of exposure to this compound are cyanosis, air hunger, nausea, vomiting, low blood pressure and convulsions. Chronic exposure results in weight loss, weakness and anemia. ACUTE/CHRONIC HAZARDS: When heated to decomposition this compound emits very toxic fumes. (NTP, 1992)
EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop. SKIN: IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water. If symptoms such as redness or irritation develop, IMMEDIATELY call a physician and be prepared to transport the victim to a hospital for treatment. INHALATION: IMMEDIATELY leave the contaminated area; take deep breaths of fresh air. If symptoms (such as wheezing, coughing, shortness of breath, or burning in the mouth, throat, or chest) develop, call a physician and be prepared to transport the victim to a hospital. Provide proper respiratory protection to rescuers entering an unknown atmosphere. Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used; if not available, use a level of protection greater than or equal to that advised under Protective Clothing. INGESTION: DO NOT INDUCE VOMITING. If the victim is conscious and not convulsing, give 1 or 2 glasses of water to dilute the chemical and IMMEDIATELY call a hospital or poison control center. Be prepared to transport the victim to a hospital if advised by a physician. If the victim is convulsing or unconscious, do not give anything by mouth, ensure that the victim's airway is open and lay the victim on his/her side with the head lower than the body. DO NOT INDUCE VOMITING. IMMEDIATELY transport the victim to a hospital. (NTP, 1992)
Benzenamine, 4-methyl-, hydrochloride (1:1) Use and Manufacturing
Used for the analysis of the content of ammonium dodecylbenzenesulfonate and as an additive for ammonium bicarbonate fertilizer
Benzenamine, 4-methyl-, hydrochloride (1:1): INACTIVE
Computed Properties
Molecular Weight:143.61
Hydrogen Bond Donor Count:2
Hydrogen Bond Acceptor Count:1
Exact Mass:143.0501770
Monoisotopic Mass:143.0501770
Topological Polar Surface Area:26
Heavy Atom Count:9
Complexity:62.8
Covalently-Bonded Unit Count:2
Compound Is Canonicalized:Yes
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