2-[(4-Aminophenyl)methyl]benzenamine
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2-[(4-Aminophenyl)methyl]benzenamine
structure -
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CAS No:
1208-52-2
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Formula:
C13H14N2
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Chemical Name:
2-[(4-Aminophenyl)methyl]benzenamine
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Synonyms:
Benzenamine,2-[(4-aminophenyl)methyl]-;Aniline,2,4′-methylenedi-;2-[(4-Aminophenyl)methyl]benzenamine;2,4′-Diaminodiphenylmethane;2′,4-Bis(aminophenyl)methane;2,4′-Methylenebis(aniline);2,4′-Methylenedianiline;o,p′-Diaminodiphenylmethane;2,4′-Diphenylmethanediamine;2,4′-Methylenediphenylamine;2-(4-Aminobenzyl)aniline;2-[(4-Aminophenyl)methyl]aniline
- Categories:
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CAS No:
2-[(4-Aminophenyl)methyl]benzenamine Basic Attributes
198.269
198.26
214-900-8
VH1ZAZ44QJ
DTXSID9051616
2921590090
Characteristics
52
2.2
Leaflets. (NTP, 1992)
0.9827 (rough estimate)
88 °C
22 °C @ Press: 9 Torr
226.6±21.8 °C
1.4400 (estimate)
2.76E-06mmHg at 25°C
No rapid reaction with air. No rapid reaction with water.
Amines, Aromatic
2,4'-DIAMINODIPHENYLMETHANE is readily oxidzable. Neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides.
Safety Information
Ⅱ
2811
6.1
Stable. Combustible. Incompatible with oxidizing agents.
P201, P202, P260, P261, P264, P270, P272, P273, P280, P281, P301+P310, P302+P352, P307+P311, P308+P313, P314, P321, P330, P333+P313, P363, P391, P405, P501
H301
Flash point data for this compound are not available. It is probably combustible. (NTP, 1992)
|Danger|H301 (96.15%): Toxic if swallowed [Danger Acute toxicity, oral]|P201, P202, P260, P261, P264, P270, P272, P273, P280, P281, P301+P310, P302+P352, P307+P311, P308+P313, P314, P321, P330, P333+P313, P363, P391, P405, and P501|Aggregated GHS information provided by 40 companies from 3 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
Fires involving this material can be controlled with a dry chemical, carbon dioxide or Halon extinguisher. (NTP, 1992)
SMALL SPILLS AND LEAKAGE: If you spill this chemical, you should dampen the solid spill material with water, then transfer the dampened material to a suitable container. Use absorbent paper dampened with water to pick up any remaining material. Seal your contaminated clothing and the absorbent paper in a vapor-tight plastic bag for eventual disposal. Wash all contaminated surfaces with a soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned. STORAGE PRECAUTIONS: You should keep this material in a tightly closed container under an inert atmosphere, and store it at refrigerated temperatures. (NTP, 1992)
RECOMMENDED RESPIRATOR: Where the neat test chemical is weighed and diluted, wear a NIOSH-approved half face respirator equipped with an organic vapor/acid gas cartridge (specific for organic vapors, HCl, acid gas and SO2) with a dust/mist filter. (NTP, 1992)
Drug Information
ACUTE/CHRONIC HAZARDS: This material emits toxic fumes when heated to decomposition. It may be toxic upon inhalation or skin contact. (NTP, 1992)
EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop. SKIN: IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water. If symptoms such as redness or irritation develop, IMMEDIATELY call a physician and be prepared to transport the victim to a hospital for treatment. INHALATION: IMMEDIATELY leave the contaminated area; take deep breaths of fresh air. If symptoms (such as wheezing, coughing, shortness of breath, or burning in the mouth, throat, or chest) develop, call a physician and be prepared to transport the victim to a hospital. Provide proper respiratory protection to rescuers entering an unknown atmosphere. Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used; if not available, use a level of protection greater than or equal to that advised under Protective Clothing. INGESTION: DO NOT INDUCE VOMITING. If the victim is conscious and not convulsing, give 1 or 2 glasses of water to dilute the chemical and IMMEDIATELY call a hospital or poison control center. Be prepared to transport the victim to a hospital if advised by a physician. If the victim is convulsing or unconscious, do not give anything by mouth, ensure that the victim's airway is open and lay the victim on his/her side with the head lower than the body. DO NOT INDUCE VOMITING. IMMEDIATELY transport the victim to a hospital. (NTP, 1992)
2-[(4-Aminophenyl)methyl]benzenamine Use and Manufacturing
EXAMPLES OF AMINE ANTIOXIDANTS ... 4-Iodecanoylamino-phenol 4-Octadecanoylamino-phenol Di-(4-methoxy-phenyl)-amine 2, 6-Di-tert.-butyl-4-dimethylamino-methyl-phenol 2, 4'-Diamino-diphenylmethane 4, 4'-Diamino-diphenylmethane N, N, N', N'-Tetramethyl-4, 4'-diamino-diphenylmethane 1, 2-Di-(phenylamino)-ethane ...Examples of amine antioxidants ... 4-isodecanoylamino-phenol 4-octadecanoylamino-phenol di-(4-methoxy-phenyl)-amine 2, 6-di-tert.-butyl-4-dimethylamino-methyl-phenol 2, 4'-diamino-diphenylmethane 4, 4'-diamino-diphenylmethane N, N, N', N'-tetramethyl-4, 4'-diamino-diphenylmethane 1, 2-di-(phenylamino)-ethane ...EXAMPLES OF AMINE ANTIOXIDANTS ... 4-Iodecanoylamino-phenol 4-Octadecanoylamino-phenol Di-(4-methoxy-phenyl)-amine 2, 6-Di-tert.-butyl-4-dimethylamino-methyl-phenol 2, 4'-diamino-diphenylmethane 4, 4'-Diamino-diphenylmethane N, N, N, N'-Tetramethyl-4, 4'-diamino-diphenylmethane 1, 2-Di-(phenylamino)-ethane ...
Intermediates
(1979) NOT PRODUCED COMMERCIALLY IN U.S.|(1981) NOT PRODUCED COMMERCIALLY IN U.S.
All other basic organic chemical manufacturing|Benzenamine, 2-[(4-aminophenyl)methyl]-: ACTIVE
Computed Properties
Molecular Weight:198.26
XLogP3:2.2
Hydrogen Bond Donor Count:2
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:2
Exact Mass:198.115698455
Monoisotopic Mass:198.115698455
Topological Polar Surface Area:52
Heavy Atom Count:15
Complexity:185
Covalently-Bonded Unit Count:1
Compound Is Canonicalized:Yes
Recommended Suppliers of 2-[(4-Aminophenyl)methyl]benzenamine
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CN
2 YRS
Business licensed Certified factoryManufactory Supplier of 4-(Pentafluorothio)aniline,Pentafluoro,Pentafluorothio,Pentafluorosulfur,[4-(bromomethyl)phenyl]-pentafluoro-lambda6-sulfane,[4-(pentafluoro-sulfanyl)phenyl]acetic acidInquiryCAS No.: 1208-52-2Grade: Industrial GradeContent: 95%
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2-[(4-Aminophenyl)methyl]benzenamine
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