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Home > Encyclopedia > Guanidine, N,N-diethyl-, hydrochloride (1:1)

Guanidine, N,N-diethyl-, hydrochloride (1:1)

Guanidine, N,N-diethyl-, hydrochloride (1:1) structure

Guanidine, N,N-diethyl-, hydrochloride (1:1) 

structure
  • CAS No:

    1114-39-2

  • Formula:

    C5H13N3.ClH

  • Chemical Name:

    Guanidine, N,N-diethyl-, hydrochloride (1:1)

  • Synonyms:

    Guanidine,N,N-diethyl-,hydrochloride (1:1);Guanidine,1,1-diethyl-,monohydrochloride;Guanidine,N,N-diethyl-,monohydrochloride;1,1-Diethylguanidine hydrochloride

  • Categories:

    Agrochemicals  >  Pesticide Intermediates

Guanidine, N,N-diethyl-, hydrochloride (1:1) Basic Attributes

151.63776

151.087631

214-213-3

DTXSID00149645

2925290090

Characteristics

53.11000

1.82370

148-149 °C

154.6ºC at 760mmHg

47.3ºC

3.16mmHg at 25°C

Safety Information

P261, P264, P270, P271, P280, P301+P312, P302+P352, P304+P340, P305+P351+P338, P310, P312, P321, P330, P332+P313, P362, P403+P233, P405, P501

H302

|Danger|H302 (100%): Harmful if swallowed [Warning Acute toxicity, oral]|P261, P264, P270, P271, P280, P301+P312, P302+P352, P304+P340, P305+P351+P338, P310, P312, P321, P330, P332+P313, P362, P403+P233, P405, and P501|Aggregated GHS information provided by 38 companies from 1 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Guanidine, N,N-diethyl-, hydrochloride (1:1) Use and Manufacturing

Methods of Manufacturing

The preparation method is to put the diethylamine solution in the reactor, add hydrochloric acid to adjust the pH of the solution to 9.2, and then add 50% cyanamide aqueous solution dropwise under stirring, the reaction temperature is 100 ℃, about 4 hours after the addition is complete, then reflux 1h, let it stand overnight at room temperature, then add 40% sodium hydroxide and pass in carbon dioxide to obtain 1, 1-diethylguanidine hydrochloride under cooling, and crystallize, filter and dry to obtain the finished product. S-methyl isothiourea can also be used to react with diethylamine to obtain 1, 1-diethyl sulphate (2:1) (CAS[77297-00-8]).

Uses

1,1-Diethylguanidine hydrochloride is an intermediate of the pesticide pyrimidinphos.

Computed Properties

Molecular Weight:151.64
Hydrogen Bond Donor Count:3
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:3
Exact Mass:151.0876252
Monoisotopic Mass:151.0876252
Topological Polar Surface Area:53.1
Heavy Atom Count:9
Complexity:75.7
Covalently-Bonded Unit Count:2
Compound Is Canonicalized:Yes

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