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Bis(1,5-cyclooctadiene)nickel

Bis(1,5-cyclooctadiene)nickel structure

CAS No:
1295-35-8
Formula:
C16H24Ni
Chemical Name:
Bis(1,5-cyclooctadiene)nickel
Synonyms:
Nickel,bis[(1,2,5,6-η)-1,5-cyclooctadiene]-;Nickel,bis(1,5-cyclooctadiene)-;1,5-Cyclooctadiene,nickel complex;Bis[(1,2,5,6-η)-1,5-cyclooctadiene]nickel;Bis(1,5-cyclooctadiene)nickel;Bis(cyclooctadiene)nickel;Bis(1,5-cyclooctadiene)nickel(0);Nickel dicyclooctadiene;Bis-1,5-cyclooctadienylnickel;Dicyclooctadiene nickel;Di(1,5-cyclooctadiene)nickel;Bis(cyclooctadiene)nickel(0);Bis(η4-1,5-cyclooctadiene)nickel;Bis(cyclooctadienyl)nickel;Nickel bis(cyclooctadiene);Nickel(COD)2;12289-90-6;32761-24-3;53585-17-4;57776-90-6
Categories:
Organic Chemistry > Organometallic Compounds

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Description

Golden shiny crystalline powderYellow crystals or yellowish green solid.

Bis(1,5-cyclooctadiene)nickel Basic Attributes

Molecular Weight：

275.06

Exact Mass：

266.060547

EC Number：

215-072-0

HScode：

29319090

Characteristics

PSA：

XLogP3：

5.34560

Appearance：

Gold Shiny Crystalline Powder

Melting Point：

140-142 °C (decomp)

Boiling Point：

Decomposes (NTP, 1992)

Flash Point：

31.7ºC

Water Solubility：

soluble in benzene, toluene, terahydrofuran, ether, dimethyl formamide, hexamethylphosphoramide, N-methylpyrrolidinone. Insoluble in water.Decomposes (NTP, 1992)

Storage Conditions：

0-6°C

Vapor Pressure：

4.25mmHg at 25°C

Safety Information

Packing level：

Hazard category：

4.2

Transport codes：

UN 1325 4.1/PG 2

wgk germany：

hazard class code：

11-40-45-十一月

safety instructions：

36/37-45-16-53

RTECS Number：

QR6135000

Marks：

F,Xn,T

Precautionary statement(s)：

P210-P261-P281-P342 + P311

Hazard Statements：

H228-H334-H351

Bis(1,5-cyclooctadiene)nickel Use and Manufacturing

Catalyst for cycloaddition of 1,3-diene compounds. It is used to catalyze the addition of allyl phenyl sulfide to alkyne to form 1,4-diene compounds. The reaction with the terminal alkyne proceeds with high yield and high selectivity. Various functional groups can be connected.

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Guide of Bis(1,5-cyclooctadiene)nickel

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Basic Attributes
Characteristics
Safety Information
Use and Manufacturing
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