Potassium pyrophosphate
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Potassium pyrophosphate
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CAS No:
7320-34-5
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Formula:
H4O7P2.4K
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Chemical Name:
Potassium pyrophosphate
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Synonyms:
Diphosphoric acid,potassium salt (1:4);Pyrophosphoric acid,tetrapotassium salt;Diphosphoric acid,tetrapotassium salt;Phosphosol;Potassium pyrophosphate;Tetrapotassium pyrophosphate;Tetrakalium pyrophosphate;Tetrapotassium diphosphate;Potassium phosphate (K4P2O7);Potassium diphosphate (K4P2O7);E 450v;Potassium metaphosphate oxide (K4(PO3)2O);1174512-44-7;1269628-81-0;2223678-13-3
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CAS No:
Description
Potassium pyrophosphate is a white, crystalline powder that exhibits a high degree of solubility in water. This substance is essentially a salt, comprised of potassium ions and pyrophosphate ions. Due to its versatile properties, potassium pyrophosphate is extensively utilized in the food industry as a buffering agent, an emulsifier, and a chelating agent. It is particularly popular in the processing of meat and dairy products, where it helps to maintain the desired pH levels, improve texture, and prevent the precipitation of metal ions that could otherwise cause discoloration or spoilage.
Potassium pyrophosphate Basic Attributes
330.336522
329.767
230-785-7
B9W4019H5G
0983
3288
DTXSID3036446
28353990
Characteristics
136
0.94120
White Powder
2.33
1090 °C
>1500
H2O: soluble
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Store protected from moisture.
LD50 skin in rabbit: > 4640mg/kg
Between 10,0 and 10,8 (1 % solution)
Soluble in water.
Salts, Basic
Salts, basic, such as POTASSIUM TETRAPYRO PHOSPHATE, are generally soluble in water. The resulting solutions contain moderate concentrations of hydroxide ions and have pH's greater than 7.0. They react as bases to neutralize acids. These neutralizations generate heat, but less or far less than is generated by neutralization of the bases in reactivity group 10 (Bases) and the neutralization of amines. They usually do not react as either oxidizing agents or reducing agents but such behavior is not impossible.
Safety Information
3288
2
36/37/38-36
26-36-22
JL6735000
Xi
Separated from strong acids. Dry.
Stable at room temperature in closed containers under normal storage and handling conditions.
P264, P280, P305+P351+P338, P33, P313
H319
Excerpt from ERG Guide 151 [Substances - Toxic (Non-combustible)]: Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Containers may explode when heated. Runoff may pollute waterways. (ERG, 2016)|Not combustible. Gives off irritating or toxic fumes (or gases) in a fire.
|Warning|H319 (98.71%): Causes serious eye irritation [Warning Serious eye damage/eye irritation]|P264, P280, P305+P351+P338, and P337+P313|Aggregated GHS information provided by 2618 companies from 14 notifications to the ECHA C&L Inventory.
Excerpt from ERG Guide 151 [Substances - Toxic (Non-combustible)]: SMALL FIRE: Dry chemical, CO2 or water spray. LARGE FIRE: Water spray, fog or regular foam. Move containers from fire area if you can do it without risk. Dike fire-control water for later disposal; do not scatter the material. Use water spray or fog; do not use straight streams. FIRE INVOLVING TANKS OR CAR/TRAILER LOADS: Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. Do not get water inside containers. Cool containers with flooding quantities of water until well after fire is out. Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. ALWAYS stay away from tanks engulfed in fire. For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible, withdraw from area and let fire burn. (ERG, 2016)|In case of fire in the surroundings, use appropriate extinguishing media.
Excerpt from ERG Guide 151 [Substances - Toxic (Non-combustible)]: As an immediate precautionary measure, isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids. SPILL: Increase, in the downwind direction, as necessary, the isolation distance shown above. FIRE: If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2016)
Excerpt from ERG Guide 151 [Substances - Toxic (Non-combustible)]: Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Stop leak if you can do it without risk. Prevent entry into waterways, sewers, basements or confined areas. Cover with plastic sheet to prevent spreading. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. DO NOT GET WATER INSIDE CONTAINERS. (ERG, 2016)
Excerpt from ERG Guide 151 [Substances - Toxic (Non-combustible)]: Wear positive pressure self-contained breathing apparatus (SCBA). Wear chemical protective clothing that is specifically recommended by the manufacturer. It may provide little or no thermal protection. Structural firefighters' protective clothing provides limited protection in fire situations ONLY; it is not effective in spill situations where direct contact with the substance is possible. (ERG, 2016)
Personal protection: chemical protection suit including self-contained breathing apparatus. Sweep spilled substance into covered containers. If appropriate, moisten first to prevent dusting. Wash away remainder with plenty of water.
Separated from strong acids. Dry.
Evaporation at 20 °C is negligible; a harmful concentration of airborne particles can, however, be reached quickly , especially if powdered.
The substance is corrosive to the eyes, skin and respiratory tract. Corrosive on ingestion. Inhalation of the aerosol may cause lung oedema.
PREVENT DISPERSION OF DUST! AVOID ALL CONTACT!
Use local exhaust or breathing protection.
Protective gloves. Protective clothing.
Wear face shield or eye protection in combination with breathing protection.
Drug Information
Excerpt from ERG Guide 151 [Substances - Toxic (Non-combustible)]: Highly toxic, may be fatal if inhaled, swallowed or absorbed through skin. Avoid any skin contact. Effects of contact or inhalation may be delayed. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution. (ERG, 2016)
Excerpt from ERG Guide 151 [Substances - Toxic (Non-combustible)]: Ensure that medical personnel are aware of the material(s) involved and take precautions to protect themselves. Move victim to fresh air. Call 911 or emergency medical service. Give artificial respiration if victim is not breathing. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Administer oxygen if breathing is difficult. Remove and isolate contaminated clothing and shoes. In case of contact with substance, immediately flush skin or eyes with running water for at least 20 minutes. For minor skin contact, avoid spreading material on unaffected skin. Keep victim calm and warm. Effects of exposure (inhalation, ingestion or skin contact) to substance may be delayed. (ERG, 2016)
Fresh air, rest. Half-upright position. Refer for medical attention.
Remove contaminated clothes. Rinse skin with plenty of water or shower. Refer for medical attention .
First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.
tetrapotassium pyrophosphate
The substance can be absorbed into the body by inhalation of dust.
Burning sensation. Cough. Laboured breathing. Shortness of breath. Sore throat. Symptoms may be delayed.
Redness. Skin burns. Pain. Blisters.
Redness. Pain. Severe deep burns.
Potassium pyrophosphate Use and Manufacturing
The neutralization calcination method uses the ratio of 1 mol phosphoric acid to 2 mol potassium hydroxide. First, add 30% phosphoric acid to the neutralizer, and slowly add potassium hydroxide solution under stirring to neutralize the reaction, and control the pH at 8.4 Preferably, the reacted solution is heated, and activated carbon is added for decolorization. The insoluble matter is removed by filtration, and then concentrated by evaporation. Then, it is cooled and crystallized and centrifuged to obtain dipotassium hydrogen phosphate, which is heated to 120~130℃ to remove the crystal water. To form anhydrous dipotassium hydrogen phosphate, calcining and polymerize it at a high temperature of 500-600°C for about 2 to 3 hours, and then cool it to obtain a finished product of potassium pyrophosphate. When H3P04+2KOH→K2FIPO4+2H2O2K2HPO4[△]→K4P2O7+H2O makes the finished product potassium pyrophosphate react with 0.1mol/L silver nitrate solution, it is qualified that there is no silver yellow orthophosphate.
It is used as an emulsifier, texture improver, chelating agent in the food industry, and as a raw material for alkaline water for noodle products. It is often used in combination with other condensed phosphates. It is usually used to prevent the production of struvite in canned aquatic products and prevent the discoloration of canned fruits; improve the expansion of ice cream, the yield of ham and sausage, and the water holding capacity of ground fish; improve the taste of noodles and improve th
10,000,000 - 50,000,000 lb
All other chemical product and preparation manufacturing|Diphosphoric acid, potassium salt (1:4): ACTIVE
EPA Safer Chemical Functional Use Classes -> Oxidants and Oxidant Stabilizers|Safer Chemical Classes -> Yellow triangle - The chemical has met Safer Choice Criteria for its functional ingredient-class, but has some hazard profile issues|Food additives|Cosmetics -> Buffering; Chelating
Food Additives -> EMULSIFIER; TEXTURIZER; THICKENER;
Computed Properties
Molecular Weight:330.34
Hydrogen Bond Acceptor Count:7
Exact Mass:329.7667523
Monoisotopic Mass:329.7667523
Topological Polar Surface Area:136
Heavy Atom Count:13
Complexity:124
Covalently-Bonded Unit Count:5
Compound Is Canonicalized:Yes
Drug Function and Efficacy
Tartar control agent
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