1,3,4,6-Tetrakis(methoxymethyl)glycoluril
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1,3,4,6-Tetrakis(methoxymethyl)glycoluril
structure -
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CAS No:
17464-88-9
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Formula:
C12H22N4O6
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Chemical Name:
1,3,4,6-Tetrakis(methoxymethyl)glycoluril
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Synonyms:
1,3,4,6-TETRAKIS(METHOXYMETHYL)GLYCOLURIL;1,3,4,6- four(MethoxyMethyl)glycoluril;1,3,4,6-tetrakis(methoxymethyl)glycoluril:tetrahydro-1,3,4,6-tetrakis(methoxymethyl)-imidazo(4,5-d)IMIDAZOLE-2,5(1h,3h)-dione;Tetrakis(methyoxymethyl)glycoluril;Tetrahydro-1,3,4,6-tetrakis(methoxymethyl)-imidazo[4,5-D]imidazole-2,5(1H,3H)-dione;Imidazo4,5-dimidazole-2,5(1H,3H)-dione, tetrahydro-1,3,4,6-tetrakis(methoxymethyl)-;1,3,4,6-Tetrakis(methoxymethyl)-1,3,3a,4,6,6a-hexahydroimidazo[4,5-d]imidazole-2,5-dione;1,3,4,6-Tetrakis(methoxymethyl)-3,3a,6,6a-tetrahydroimidazo[4,5-d]imidazole-2,5(1H,4H)-dione
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CAS No:
1,3,4,6-Tetrakis(methoxymethyl)glycoluril Basic Attributes
318.33
318.33
241-480-3
TSCA listed
DTXSID4066202
White to Almost white
2933.99.9701
Characteristics
84
-1.1
DryPowder
1.243±0.06 g/cm3(Predicted)
90-110°C
454.7±45.0 °C(Predicted)
228.8ºC
1.5
Soluble in water
1.87E-08mmHg at 25°C
-1.09±0.20(Predicted)
Sealed in dry,Room Temperature
Safety Information
P261, P264, P270, P271, P280, P301+P312, P302+P352, P304+P312, P304+P340, P305+P351+P338, P312, P322, P330, P337+P313, P363, P501
H302
|Warning|H302 (61.54%): Harmful if swallowed [Warning Acute toxicity, oral]|P261, P264, P270, P271, P280, P301+P312, P302+P352, P304+P312, P304+P340, P305+P351+P338, P312, P322, P330, P337+P313, P363, and P501|Aggregated GHS information provided by 184 companies from 4 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
1,3,4,6-Tetrakis(methoxymethyl)glycoluril Use and Manufacturing
Synthesis of cucurbit[n]urils in methanesulphonic acid usingTetramethoxymethylglycoluril (TMMG)Unsubstituted glycoluril (19.94 g) and methane sulphonic acid (neat, 82 ml_) were placed in a reaction flask and heated to 80 °C. TMMG (44.66 g) was added in drop-wise and the reaction mixture was then heated to 100 °C (internal temp) for 18 hours. The reaction mixture was cooled and added to methanol (410 ml) to produce a beige powder which was analysed by1H NMR. Approximate Yields b1H NMR (percent of recovered product) cucurbit[5]uri 5percent, cucurbit[6]uri 58percent, cucurbit[7]uril 28percent, cucurbit[8]uril 9percent, cucurbit[9]uril 0percent, cucurbit[10]uril 0percent, cucurbit[11]uril 0percentThe Amberlyst 15 resin was dried in an oven to 60% of the original weight.3 g of 60 g (0.188 mol) of
Paint additives and coating additives not described by other categories
Crosslinker for powder coatings, negative hotoresist
1,3,4,6-Tetrakis(methoxymethyl)glycoluril is used as a crosslinker for powder coatings, photoresists with antireflective coatings, and hydrogels.
Plastic material and resin manufacturing|Imidazo[4,5-d]imidazole-2,5(1H,3H)-dione, tetrahydro-1,3,4,6-tetrakis(methoxymethyl)-: ACTIVE
Computed Properties
Molecular Weight:318.33
XLogP3:-1.1
Hydrogen Bond Acceptor Count:6
Rotatable Bond Count:8
Exact Mass:318.15393443
Monoisotopic Mass:318.15393443
Topological Polar Surface Area:84
Heavy Atom Count:22
Complexity:352
Covalently-Bonded Unit Count:1
Compound Is Canonicalized:Yes
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1,3,4,6-Tetrakis(methoxymethyl)glycoluril
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