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Best Quality,Lower Price

Best Quality,Lower Price structure

Best Quality,Lower Price 

structure

Description

2,2',7,7'-Tetrakis[N,N-di(4-methoxyphenyl)amino]-9,9'-spirobifluorene is Light Grey Solid

Best Quality,Lower Price Basic Attributes

1225.42862

1224.504

DTXSID90583231

29222990

Characteristics

86.8

19.1

1.35±0.1 g/cm3(Predicted)

234-238°C

1.744

Refrigerator

Safety Information

3

24/25

Best Quality,Lower Price Use and Manufacturing

Methods of Manufacturing

Nitrogen gas in 50 mL 2-necked flask, the 4, 4'-dimethoxydiphenylamine (2.00 g, 8.72 mmol), 2, 2', 7, 7'-tetrabromo-9, 9'-spirobi[9H-fluorene] (1.23 g, 1.94 mmol), sodium tertbutoxide (1.12 g, 11.6 mmol), tris (dibenzylideneacetone) dipalladium (0) (0.071 g, 0.078 mmol) and tri-tert-butylphosphine (0.025 g, 0.12 mmol) to put this in dry toluene 15mL was added to 110 °C and stirred for 12 hours. The reaction mixture was cooled to room temperature and extracted with ethyl acetate and dried with washed with brine MgSO4 The solvent was removed by separation and purification by column chromatography (ethyl acetate / hexane = 1/2) of the solid of the title compound as a beige It was obtained (45percent, 1.07 g)Nitrogen gas in 50 mL 2-necked flask, the 4, 4'-dimethoxydiphenylamine (2.00 g, 8.72 mmol), 2, 2', 7, 7'-tetrabromo-9, 9'-spirobi[9H-fluorene] (1.23 g, 1.94 mmol), sodium tertbutoxide (1.12 g, 11.6 mmol), tris (dibenzylideneacetone) dipalladium (0) (0.071 g, 0.078 mmol) and tri-tert-butylphosphine (0.025 g, 0.12 mmol) to put this in dry toluene 15mL was added to 110 °C and stirred for 12 hours. The reaction mixture was cooled to room temperature and extracted with ethyl acetate and dried with washed with brine MgSO4 The solvent was removed by separation and purification by column chromatography (ethyl acetate / hexane = 1/2) of the solid of the title compound as a beige It was obtained (45percent, 1.07 g)

Uses

Spirobifluorene derivatives are suitable for use as charge-transfer materials, especial for photovoltaic cells, and as electroluminescent materials.

Computed Properties

Molecular Weight:1225.4
XLogP3:19.1
Hydrogen Bond Acceptor Count:12
Rotatable Bond Count:20
Exact Mass:1224.50371514
Monoisotopic Mass:1224.50371514
Topological Polar Surface Area:86.8
Heavy Atom Count:93
Complexity:1830
Covalently-Bonded Unit Count:1
Compound Is Canonicalized:Yes

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