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CAS No:
207739-72-8
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Formula:
C81H68N4O8
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Chemical Name:
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CAS No:
Description
2,2',7,7'-Tetrakis[N,N-di(4-methoxyphenyl)amino]-9,9'-spirobifluorene is Light Grey Solid
Best Quality,Lower Price Use and Manufacturing
Nitrogen gas in 50 mL 2-necked flask, the 4, 4'-dimethoxydiphenylamine (2.00 g, 8.72 mmol), 2, 2', 7, 7'-tetrabromo-9, 9'-spirobi[9H-fluorene] (1.23 g, 1.94 mmol), sodium tertbutoxide (1.12 g, 11.6 mmol), tris (dibenzylideneacetone) dipalladium (0) (0.071 g, 0.078 mmol) and tri-tert-butylphosphine (0.025 g, 0.12 mmol) to put this in dry toluene 15mL was added to 110 °C and stirred for 12 hours. The reaction mixture was cooled to room temperature and extracted with ethyl acetate and dried with washed with brine MgSO4 The solvent was removed by separation and purification by column chromatography (ethyl acetate / hexane = 1/2) of the solid of the title compound as a beige It was obtained (45percent, 1.07 g)Nitrogen gas in 50 mL 2-necked flask, the 4, 4'-dimethoxydiphenylamine (2.00 g, 8.72 mmol), 2, 2', 7, 7'-tetrabromo-9, 9'-spirobi[9H-fluorene] (1.23 g, 1.94 mmol), sodium tertbutoxide (1.12 g, 11.6 mmol), tris (dibenzylideneacetone) dipalladium (0) (0.071 g, 0.078 mmol) and tri-tert-butylphosphine (0.025 g, 0.12 mmol) to put this in dry toluene 15mL was added to 110 °C and stirred for 12 hours. The reaction mixture was cooled to room temperature and extracted with ethyl acetate and dried with washed with brine MgSO4 The solvent was removed by separation and purification by column chromatography (ethyl acetate / hexane = 1/2) of the solid of the title compound as a beige It was obtained (45percent, 1.07 g)
Spirobifluorene derivatives are suitable for use as charge-transfer materials, especial for photovoltaic cells, and as electroluminescent materials.
Computed Properties
Molecular Weight:1225.4
XLogP3:19.1
Hydrogen Bond Acceptor Count:12
Rotatable Bond Count:20
Exact Mass:1224.50371514
Monoisotopic Mass:1224.50371514
Topological Polar Surface Area:86.8
Heavy Atom Count:93
Complexity:1830
Covalently-Bonded Unit Count:1
Compound Is Canonicalized:Yes
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