2,3,3,3-Tetrafluoropropene Safety Data Sheets

Characteristics

Products for Sale

Suppliers

SAFETY DATA SHEETS

According to the UN GHS revision 8

Version: 1.0

Creation Date: July 15, 2019

Revision Date: July 15, 2019

SECTION 1: Identification

1.1 GHS Product identifier

Product name	2,3,3,3-Tetrafluoroprop-1-ene

1.2 Other means of identification

Product number	-
Other names	1234yf;2,3,3,3-tetrafluoro-propene;HFC 1134yf

1.3 Recommended use of the chemical and restrictions on use

Identified uses	Industrial and scientific research uses.
Uses advised against	no data available

1.4 Supplier's details

Company	Echemi.com
Address	Echemi.com
Telephone	Echemi.com

1.5 Emergency phone number

Emergency phone number	Echemi.com
Service hours	Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

SECTION 2: Hazard identification

2.1 Classification of the substance or mixture

Flammable gases, Category 1A, Flammable gas

2.2 GHS label elements, including precautionary statements

Precautionary statement(s)
Pictogram(s)
Signal word	Danger
Hazard statement(s)	H220 Extremely flammable gas H280 Contains gas under pressure; may explode if heated
Prevention	P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
Response	P377 Leaking gas fire: Do not extinguish, unless leak can be stopped safely. P381 In case of leakage, eliminate all ignition sources.
Storage	P403 Store in a well-ventilated place.
Disposal	none

2.3 Other hazards which do not result in classification

no data available

SECTION 3: Composition/information on ingredients

3.1 Substances

Chemical name	Common names and synonyms	CAS number	EC number	Concentration
2,3,3,3-Tetrafluoroprop-1-ene	2,3,3,3-Tetrafluoroprop-1-ene	754-12-1	616-220-0	100%

SECTION 4: First-aid measures

4.1 Description of necessary first-aid measures

If inhaled

Fresh air, rest.

Following skin contact

ON FROSTBITE: rinse with plenty of water, do NOT remove clothes. Refer for medical attention .

Following eye contact

ON FROSTBITE: rinse with plenty of water. Refer immediately for medical attention.

Following ingestion

Rinse mouth with water. Do not induce vomiting. Never give anything by mouth to an unconscious person. Call a doctor or Poison Control Center immediately.

4.2 Most important symptoms/effects, acute and delayed

no data available

4.3 Indication of immediate medical attention and special treatment needed, if necessary

no data available

SECTION 5: Fire-fighting measures

5.1 Suitable extinguishing media

Use dry chemical, carbon dioxide or alcohol-resistant foam.

5.2 Specific hazards arising from the chemical

Extremely flammable. Cylinder may explode in heat of fire. Gas/air mixtures are explosive.

5.3 Special protective actions for fire-fighters

Shut off supply; if not possible and no risk to surroundings, let the fire burn itself out. In other cases extinguish with carbon dioxide, dry powder. Combat fire from a sheltered position. In case of fire: keep cylinder cool by spraying with water.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

Evacuate danger area! Consult an expert! Turn off gas at source if possible. Ventilation. Remove gas with fine water spray. NEVER direct water jet on liquid. Personal protection: complete protective clothing including self-contained breathing apparatus.

6.2 Environmental precautions

Prevent further spillage or leakage if it is safe to do so. Do not let the chemical enter drains. Discharge into the environment must be avoided.

6.3 Methods and materials for containment and cleaning up

Collect and arrange disposal. Keep the chemical in suitable and closed containers for disposal. Remove all sources of ignition. Use spark-proof tools and explosion-proof equipment. Adhered or collected material should be promptly disposed of, in accordance with appropriate laws and regulations.

SECTION 7: Handling and storage

7.1 Precautions for safe handling

NO open flames, NO sparks and NO smoking. Closed system, ventilation, explosion-proof electrical equipment and lighting. Prevent build-up of electrostatic charges (e.g., by grounding) if in liquid state. Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.

7.2 Conditions for safe storage, including any incompatibilities

Fireproof. Cool. Keep in a well-ventilated room.

SECTION 8: Exposure controls/personal protection

8.1 Control parameters

Occupational Exposure limit values

MAK: 950 mg/m3, 200 ppm; peak limitation category: II(2); pregnancy risk group: C

Biological limit values

no data available

8.2 Appropriate engineering controls

Ensure adequate ventilation. Handle in accordance with good industrial hygiene and safety practice. Set up emergency exits and the risk-elimination area.

8.3 Individual protection measures, such as personal protective equipment (PPE)

Eye/face protection

Wear face shield or safety goggles.

Skin protection

Cold-insulating gloves.

Respiratory protection

Use ventilation.

Thermal hazards

no data available

SECTION 9: Physical and chemical properties and safety characteristics

Physical state	COLOURLESS LIQUEFIED GAS.
Colour	no data available
Odour	no data available
Melting point/freezing point	-152ÂºC
Boiling point or initial boiling point and boiling range	-28ÂºC
Flammability	no data available
Lower and upper explosion limit/flammability limit	no data available
Flash point	no data available
Auto-ignition temperature	405Â°C
Decomposition temperature	no data available
pH	no data available
Kinematic viscosity	no data available
Solubility	0.2 g/l(very poor)(24Â°C)
Partition coefficient n-octanol/water	2.15
Vapour pressure	600 kPa(21.1Â°C)
Density and/or relative density	1.203 g/cm3
Relative vapour density	no data available
Particle characteristics	no data available

SECTION 10: Stability and reactivity

10.1 Reactivity

no data available

10.2 Chemical stability

no data available

10.3 Possibility of hazardous reactions

The gas is heavier than air and may travel along the ground; distant ignition possible.Decomposes on contact with hot surfaces or flames. This produces toxic fumes including hydrogen fluoride.

10.4 Conditions to avoid

no data available

10.5 Incompatible materials

no data available

10.6 Hazardous decomposition products

no data available

SECTION 11: Toxicological information

Acute toxicity

Oral: no data available
Inhalation: no data available
Dermal: no data available

Skin corrosion/irritation

no data available

Serious eye damage/irritation

no data available

Respiratory or skin sensitization

no data available

Germ cell mutagenicity

no data available

Carcinogenicity

no data available

Reproductive toxicity

no data available

STOT-single exposure

Asphyxiation. Rapid evaporation of the liquid may cause frostbite. See Notes.

STOT-repeated exposure

no data available

Aspiration hazard

On loss of containment this substance can cause suffocation by lowering the oxygen content of the air in confined areas.

SECTION 12: Ecological information

12.1 Toxicity

Toxicity to fish: no data available
Toxicity to daphnia and other aquatic invertebrates: no data available
Toxicity to algae: no data available
Toxicity to microorganisms: no data available

12.2 Persistence and degradability

no data available

12.3 Bioaccumulative potential

no data available

12.4 Mobility in soil

no data available

12.5 Other adverse effects

no data available

SECTION 13: Disposal considerations

13.1 Disposal methods

Product

The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.

Contaminated packaging

Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials.

SECTION 14: Transport information

14.1 UN Number

ADR/RID: UN3161 (For reference only, please check.)

IMDG: UN3161 (For reference only, please check.)

IATA: UN3161 (For reference only, please check.)

14.2 UN Proper Shipping Name

ADR/RID: LIQUEFIED GAS, FLAMMABLE, N.O.S. (For reference only, please check.)

IMDG: LIQUEFIED GAS, FLAMMABLE, N.O.S. (For reference only, please check.)

IATA: LIQUEFIED GAS, FLAMMABLE, N.O.S. (For reference only, please check.)

14.3 Transport hazard class(es)

ADR/RID: 2.1 (For reference only, please check.)

IMDG: 2.1 (For reference only, please check.)

IATA: 2.1 (For reference only, please check.)

14.4 Packing group, if applicable

ADR/RID: (For reference only, please check.)

IMDG: (For reference only, please check.)

IATA: (For reference only, please check.)

14.5 Environmental hazards

ADR/RID: No

IMDG: No

IATA: No

14.6 Special precautions for user

no data available

14.7 Transport in bulk according to IMO instruments

no data available

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations specific for the product in question

Chemical name	Common names and synonyms	CAS number	EC number
2,3,3,3-Tetrafluoroprop-1-ene	2,3,3,3-Tetrafluoroprop-1-ene	754-12-1	616-220-0
European Inventory of Existing Commercial Chemical Substances (EINECS)			Not Listed.
EC Inventory			Not Listed.
United States Toxic Substances Control Act (TSCA) Inventory			Listed.
China Catalog of Hazardous chemicals 2015			Not Listed.
New Zealand Inventory of Chemicals (NZIoC)			Listed.
Philippines Inventory of Chemicals and Chemical Substances (PICCS)			Not Listed.
Vietnam National Chemical Inventory			Listed.
Chinese Chemical Inventory of Existing Chemical Substances (China IECSC)			Not Listed.
Korea Existing Chemicals List (KECL)			Listed.

SECTION 16: Other information

Information on revision

Creation Date	July 15, 2019
Revision Date	July 15, 2019

Abbreviations and acronyms

CAS: Chemical Abstracts Service
ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
RID: Regulation concerning the International Carriage of Dangerous Goods by Rail
IMDG: International Maritime Dangerous Goods
IATA: International Air Transportation Association
TWA: Time Weighted Average
STEL: Short term exposure limit
LC50: Lethal Concentration 50%
LD50: Lethal Dose 50%
EC50: Effective Concentration 50%

References

IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home
HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm
IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/
eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en
CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple
ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp
ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg
Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp
ECHA - European Chemicals Agency, website: https://echa.europa.eu/

Other Information

High concentrations in the air cause a deficiency of oxygen with the risk of unconsciousness or death.Check oxygen content before entering the area.Turn leaking cylinder with the leak up to prevent escape of gas in liquid state.

Disclaimer: The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. We as supplier shall not be held liable for any damage resulting from handling or from contact with the above product.

2,3,3,3-Tetrafluoropropene is included in Organic Fluorine Compound category.