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Meethyl Acrylate(MA) 99.5% Industrial Grade Colorless volatile liquid

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CAS No.:

96-33-3

Grade:

Industrial Grade

Content:

99.5%

Port:

the port of Qingdao

Packaging:

200kg/drum

Price valid (until):

2023-04-30

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Shandong Lingnuo chemical Co., Ltd

Company Type:

Trader

Location:

China

Qualification:

Main Products:

Melamine,ethyl acetate,maleic anhydride,acetic acid,tetrahydrofuran,butyl acetate

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Product Description
Seller Information
Inquiry History

Description

Meethyl Acrylate(MA)

Methyl acrylate, an organic compound with the formula C4H6O2, is a colorless transparent liquid with a pungent odor. Slightly soluble in water, easily soluble in ethanol, ether, acetone, benzene.

It is mainly used as monomer of synthetic polymer, second monomer of polyacrylonitrile fiber, adhesive and so on.

It is easy to polymerize in the storage process, which can be accelerated by light, heat and peroxide. Pure monomers do not polymerize below 10℃. Usually 0.1% hydroquinone monomethyl ether is added as an inhibitor. Store in a cool, ventilated warehouse. Keep away from fire and heat. The temperature of the warehouse should not exceed 37℃. The package should be sealed and not in contact with air. It should be stored separately from oxidants, acids and bases, and should not be mixed. Do not store in large quantities or for long periods of time. Explosion-proof lighting and ventilation facilities are adopted. Do not use mechanical equipment and tools that are prone to spark. The storage area should be equipped with leak emergency treatment equipment and suitable holding materials. Packed in galvanized iron drums. Should be stored separately, to prevent direct sunlight, storage temperature <21℃, long-term storage and transportation should be added to resist polymer. Pay attention to fire prevention. Store and transport in accordance with flammable provisions.

Items	Specifications
CAS	96-33-3
chemical formula	C4H6O2
molecular weight	86.09
density	0.956 g/mL at 25 °C (lit.)
melting point	-75 °C (lit.)
boiling point	80 °C (lit.)
flash(ing) point	26.6°F
water solubility	60 g/L (20 ºC)
vapour pressure	67.5 mm Hg ( 20 °C)
vapor density	3 (vs air)
solubility	60g/l
refractive index	n20/D 1.402(lit.)
storage condition	2-8°C
stability	Stable. Incompatible with bases, acids, oxidizing agents, peroxides. May polymerize on exposure to light. Highly flammable. Commercial product may be inhibited by the presence of hydroquinone monometh
sensibility	Light Sensitive
appearance	Liquid
colour	Clear
Explosion limit	2.8%(V)
exposure limit	TLV-TWA 10 ppm (～35 mg/m3) (ACGIHand MSHA), TLV-TWA skin 10 ppm(～35 mg/m3) (OSHA); IDLH 1000 ppm(NIOSH).
physico-chemical property	Colorless volatile liquid. It has a pungent smell and a tear-jerking effect. Soluble in ethanol, ether, acetone and benzene, slightly soluble in water.
product use	Organic synthesis intermediate, is also the synthesis of polymer monomer. The rubber copolymerized by methyl acrylate has good resistance to high temperature and oil. The spinnability, thermoplasticity and dyeing properties of acrylonitrile can be improved by copolymerization with acrylonitrile. It can be copolymerized with methyl methacrylate vinyl acetate or styrene to produce coating and floor polish with good properties. It is also widely used in pharmaceutical manufacturing, leather processing, paper making, adhesive manufacturing and so on.
security	Methyl acrylate has moderate toxicity, has strong irritation and corrosion effect on eyes, skin and mucosa, and can be absorbed through the skin to cause poisoning, rat oral LD50 is 300mg/kg. Rabbit oral LD50 280mg/kg. Symptoms of chronic poisoning include headache, drowsiness, spasm of hands and feet, etc. The maximum allowable concentration in the workplace is 35mg/m3. Ventilation should be enhanced in the operating place. Operators should wear protective equipment such as rubber gloves, face masks and protective clothing. Poisoning should be immediately moved to a well-ventilated place to rest, take glucose and vitamin B, C, etc. Packed in galvanized iron drums. Should be stored separately, to prevent direct sunlight, storage temperature <21℃, long-term storage and transportation should be added to resist polymer. Pay attention to fire prevention. Store and transport in accordance with flammable provisions.

Basic Info

Product Name:

Methyl acrylate

Other Name:

2-Propenoic acid,methyl ester;Acrylic acid methyl ester;Methyl acrylate;2-Propenoic acid methyl ester;Methoxycarbonylethylene;Methyl propenoate;Methyl prop-2-enoate;Methyl acrylic ester;NSC 24146;K 400;Methacrylic acid tert-butyl ester;K 268P;Methyl acrylate-vinylidene copolymer;102256-29-1;1254182-69-8;2408240-60-6

CAS No.:

96-33-3

Molecular Formula:

C4H6O2

InChIKeys:

InChIKey=BAPJBEWLBFYGME-UHFFFAOYSA-N

Molecular Weight:

86.0892

Exact Mass:

86.09

EC Number:

202-500-6

HScode:

2916121000

Categories:

Inorganic Acid Esters

Characteristics

PSA:

26.3

XLogP3:

0.3454

Appearance:

colorless liquid

Density:

0.9535 g/cm³ @ Temp: 20 °C

Melting Point:

-76.5 °C

Boiling Point:

80.5 °C

Flash Point:

26.6 °F

Refractive Index:

n20/D 1.402(lit.)

Water Solubility:

Slightly soluble in water;soluble in ethanol, ether, acetone and benzene.

Storage Conditions:

Low temperature and dry storage, separate storage with oxidants and acids

Vapor Pressure:

Vapour pressure, kPa at 20°C: 9.1

Vapor Density:

3 (vs air)

Toxicity:

LD50 orally in rats: 0.3 g/kg (Smyth, Carpenter)

Flammability characteristics:

Class IB Flammable Liquid: Fl.P. below 73°F and BP at or above 100°F.

Explosive limit:

vol% in air: 2.85

Odor:

Acrid odor

See More Methyl acrylate Properties 

Hazard Identification

Classification of the substance or mixture

Flammable liquids, Category 2

Acute toxicity - Category 4, Oral

Acute toxicity - Category 4, Dermal

Skin irritation, Category 2

Eye irritation, Category 2

Skin sensitization, Category 1

Acute toxicity - Category 4, Inhalation

Specific target organ toxicity â single exposure, Category 3

GHS label elements, including precautionary statements

Precautionary statement(s)
Pictogram(s)
Signal word	Danger
Hazard statement(s)	H225 Highly flammable liquid and vapour H302 Harmful if swallowed H312 Harmful in contact with skin H315 Causes skin irritation H319 Causes serious eye irritation H317 May cause an allergic skin reaction H332 Harmful if inhaled H335 May cause respiratory irritation
Prevention	P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P233 Keep container tightly closed. P240 Ground and bond container and receiving equipment. P241 Use explosion-proof [electrical/ventilating/lighting/...] equipment. P242 Use non-sparking tools. P243 Take action to prevent static discharges. P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/... P264 Wash ... thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P272 Contaminated work clothing should not be allowed out of the workplace. P271 Use only outdoors or in a well-ventilated area.
Response	P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse affected areas with water [or shower]. P370+P378 In case of fire: Use ... to extinguish. P301+P317 IF SWALLOWED: Get medical help. P330 Rinse mouth. P302+P352 IF ON SKIN: Wash with plenty of water/... P317 Get medical help. P321 Specific treatment (see ... on this label). P362+P364 Take off contaminated clothing and wash it before reuse. P332+P317 If skin irritation occurs: Get medical help. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333+P317 If skin irritation or rash occurs: Get medical help. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P319 Get medical help if you feel unwell.
Storage	P403+P235 Store in a well-ventilated place. Keep cool. P403+P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up.
Disposal	P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.

Other hazards which do not result in classification

no data available

Handling and Storage

Precautions for safe handling

NO open flames, NO sparks and NO smoking. Closed system, ventilation, explosion-proof electrical equipment and lighting. Do NOT use compressed air for filling, discharging, or handling. Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.

Conditions for safe storage, including any incompatibilities

Fireproof. See Chemical Dangers. Cooled. Keep in the dark. Well closed. Store only if stabilized.Before entering confined space where this chemical may be present, check to make sure that an explosive concentration does not exist. Methyl acrylate must be stored to avoid contact with oxidizers (such as perchlorates, peroxides, permanganates, chlorates, and nitrates) since violent reactions occur. Store in tightly closed containers in a cool, well ventilated area away from heat and moisture. At temperatures above 20 deg C a violent reation could take place. Methyl acrylate should always be used with an inhibitor. Check that the correct concentration of inhibitor is used; if it is not, a violent reaction could occur. Sources of ignition, such as smoking and open flames, are prohibited where methyl acrylate is handled, used, or stored. Metal containers involving the transfer of 5 gallons or more of methyl acrylate should be grounded and bonded. Drums must be equipped with self-closing valves, pressure vacuum bungs, and flame arresters. Use only non-sparking tools and equipment, especially when opening and closing containers of methyl acrylate. Wherever methyl acrylate is used, handled, manufactured, or stored, use explosion-proof electrical equipment and fittings.

See More Methyl acrylate Safety Data Sheet 

Seller Information

Business Type:
Trader

Main Products:
Melamine,ethyl acetate,maleic anhydride,acetic acid,tetrahydrofuran,butyl acetate

Location:
Room 21-1, 14th floor, Zone (A), Guangrao City Commercial Complex, Quanfu Yuan, Guangrao County, Dongying City, Shandong Province

Payment Terms:
TT against copy of documents,L/C

Average lead Time:
20

Total Annual Revenue:
$50 million-$100 million

Total Employees:
51-100

Year of Establishment:
2018

Shandong Lingnuo chemical Co.,Ltd is located in Dongying City, Shandong Province, export more than ten years It is mainly exported to Africa, Asia,Middle East,South America , mainly delaing with product tetrahydrofuran, Melamine, Methylene chloride, aniline oil, Dimethyl Formamide,Acetic acid, Isopropyl Alcohol, Maleic anhydride,Methyl Acetate,DMSO, Ethanol and so on.

Inquiry History

7 Inquiries

Country	Product	Purchase Quantity	Date Posted
United States	Methyl Acrylate	1 KG	Jan 24, 2026
Poland	Methyl Acrylate	25.00 KG	Apr 3, 2026
Qatar	Methyl acrylate	1.00 40' Fcl	Jul 31, 2025
Qatar	Methyl Acrylate (MA)	1.00 40' Fcl	Jul 2, 2025
South Korea	Methyl acrylate	70 MT	Feb 2, 2026
India	Methyl Acrylate	1 20' Fcl	Nov 8, 2024
Thailand	METHYL ACRYLATE	25 KG	Oct 11, 2024

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