allethrin584-79-2

Allethrin

Cyclopropanecarboxylic acid,2,2-dimethyl-3-(2-methyl-1-propen-1-yl)-,2-methyl-4-oxo-3-(2-propen-1-yl)-2-cyclopenten-1-yl ester;Cyclopropanecarboxylic acid,2,2-dimethyl-3-(2-methylpropenyl)-,ester with 2-allyl-4-hydroxy-3-methyl-2-cyclopenten-1-one;Cyclopropanecarboxylic acid,2,2-dimethyl-3-(2-methyl-1-propenyl)-,2-methyl-4-oxo-3-(2-propenyl)-2-cyclopenten-1-yl ester;Chrysanthemummonocarboxylic acid,3-allyl-2-methyl-4-oxo-2-cyclopenten-1-yl ester;2-Cyclopenten-1-one,2-allyl-4-hydroxy-3-methyl-,2,2-dimethyl-3-(2-methylpropenyl)cyclopropanecarboxylate;2-Allyl-4-hydroxy-3-methyl-2-cyclopenten-1-one ester of 2,2-dimethyl-3-(2-methylpropenyl)cyclopropane carboxylic acid;3-Allyl-4-keto-2-methylcyclopentenyl chrysanthemummonocarboxylate;3-Allyl-4-methyl-2-oxo-3-cyclopenten-1-yl ester of 2,2-dimethyl-3-(2-methylpropenyl)cyclopropanecarboxylic acid;2,2-Dimethyl-3-(2-methyl-1-propenyl)cyclopropanecarboxylic acid,ester with 2-allyl-4-hydroxy-3-methyl-2-cyclopenten-1-one;Allethrin;Pynamin;ENT 17510;(±)-Allerethonyl (±)-cis,trans-chrysanthemate;Allyl cinerin I;dl-2-Allyl-4-hydroxy-3-methyl-2-cyclopenten-1-one ester with dl-chrysanthemummonocarboxylic acid;(±)-3-Allyl-4-keto-2-methylcyclopent-2-enyl (±)-cis,trans-chrysanthemummonocarboxylate;Pyresyn;Allethrine;trans-Allethrin;Exthrin;Wasp Stopper CF;Matox;RU 27436;EBT;OMS 3045;137-98-4;6385-67-7;6385-68-8;8018-12-0;18793-35-6;18877-88-8;20301-61-5;22431-63-6;22556-34-9;23453-08-9;24313-23-3;25406-22-8;25406-25-1;25406-24-0;71119-51-2;71211-88-6;84030-86-4

584-79-2

C19H26O3

InChIKey=ZCVAOQKBXKSDMS-UHFFFAOYSA-N

302.41

302.41

209-542-4

0X03II877M

0212|0213|0227|0228

11782

2902|3352

DTXSID8035180

29183000

Insecticides

43.4

4.7

Clear amber Viscous Liquid

1.01 g/cm³ @ Temp: 20 °C

4 °C

140 °C @ Press: 0.1 Torr

66 °C

1.515

2 mg l -1

0-6°C

Vapour pressure, Pa at 25°C:

Oral-rat LD50: 425 mg/kg; Oral-Mouse LD50: 330 mg/kg

Flammable; burning produces irritating fumes

Henry's Law constant = 1.04X10-7 atm-cu m/mol at 21 °C (est) /Allethrin I/

Allethrins are sometimes classified as type I pyrethroids, since they lack an alpha-cyano substituent.|Clear, amber-colored, viscous liquid. Miscible with most organic solvents at 20-25 °C /Allethrin I/|Clear, pale yellow liquid. MW: 302.4. Soluble in alcohol, petroleum ether, kerosene, carbon tetrachloride, ethylene dichloride, nitromethane. Index of refraction: 1.5040 at 20 °C/D; 1.5023 at 30 °C/D. BP: 140 °C at 0.1 mm Hg. Vaporizes without decomposition when heated at 150 °C. /Allethrin I/|BP: 281.5 °C at 760 mm Hg. Density: 1.01 at 20 °C. Solubility in water: 4.6 mg/L at 25 °C. Solubility in hexane 0.655 g/mL, methanol 72.0 mL/mL (both 20 °C). VP: 1.2X10-6 mm Hg at 21 °C /Allethrin I/|log Kow = 4.78 /Allethrin I/|Conversion factors Air (25 °C): 1 mg/cu m = 0.081 ppm|Pale yellow liquid /Technical grade Allethrin I/|/TECHNICAL & COMMERCIAL ALLETHRIN/ ... CHEMICAL PROPERTIES ARE AKIN TO THOSE OF PYRETHRINS ... BUT HAVING MORE STABLE SIDE CHAIN IT IS ... MORE PERSISTENT. ...|VP: 2 mPa at 25 °C; water solubility: 4.6 mg/L /Bioallethrin/|Mol. wt. 302.4 MF: C19H26O3. Orange-yellow viscous liquid. The material in D-Trans is an amber viscous liquid. MP: Not applicable; no crystallization observed at -40 °C. BP: Bioallethrin 165-170 °C/0.15 mmHg. VP: 43.9 mPa (25 °C) log Kow = 4.68 (25 °C); Henry's Law constant: 2.89 Pa cu m/mol (calc). Specific gravity/density: 1.012 at 20 °C. Solubility: in water, 4.6 mg/L (25 °C). Completely miscible with chloroform, ethyl acetate, toluene and dichloromethane (20 °C). Specific rotation:-18.5 to -22.5deg at 20 °C (50 g/L toluene). Stability: Degraded by UV light. In aqueous solution, DT50 1410.7 days (pH 5), 547.3 days (pH 7), 4.3 days (pH 9). /Bioallethrin/|Amber colored viscous liquid, slight aromatic odor. Specific gravity of D-trans concn 90% is typically 0.997 at 20 °C. Stable under normal conditions of storage and use. Avoid highly alkaline or acidic situations. Miscible with acetone, benzene, ethanol, hexane, methylene chloride, and refined kerosene. /Bioallethrin/|Composition Esbiol (OMS 3046) contains approximately 95% m/m total isomers, of which approximately 90% is esdepallethrine. Esbiothrin (OMS 3045) contains approximately 93% m/m total isomers, of which approximately72% is esdepallethrine, the remainder being essentially the (R)-cyclopentenyl isomer, with <3% cis- isomers. MW: 302.4; MF: C19H26O3. Form: Orange-yellow viscous liquid. MP: Not applicable; no crystallisation observed at -40 °C. BP: 165-170 °C/0.15 mmHg (OMS 3046); 163-170 °C/0.15 mmHg (OMS 3045). VP: 44 mPa (25 °C). Specific gravity/density: 1.010 at 20 °C. Solubility: Completely miscible with 100% ethanol, acetone, dichloromethane, di-isopropyl ether, toluene, n-hexane, chloroform, ethyl acetate, methanol, n-octanol, and petroleum solvent (20 °C ). Stability: Degraded by UV light. Specific rotation: OMS 3046: -47.5 deg to -55 deg at 20 °C/D (50 g/L toluene); OMS 3045: approximately -37 deg at 20 °C/D (50 g/L toluene) /Esbiol/|Yellow-colored viscous liquid with slight aromatic odor. Specific gravity of esbiol concn 90% is typically 0.98 at 20 °C. Stable under normal conditions of storage use use. Avoid highly acidic of alkaline situations. Miscible with acetone, benzene, ethanol, hexane, refined kerosene, isoparaffinic solvents, and other organic solvents. Insoluble in water. /S-Bioallethrin/|Composition: d-Allethrin is approximately 95% (1R)- isomers and approximately 75% trans isomers; see also bioallethrin. MW: 302.4. MF: C19H26O3. Form Tech. is a pale yellow liquid. BP: 281.5 °C/760 mmHg. VP: 0.16 mPa (21 °C). log Kow = 4.96 (room temperature). Specific gravity/density 1.01 (20 °C). Solubility: Practically insoluble in water. In hexane 0.655 g/mL, methanol 72.0 mL/mL (both 20 °C). Stability: Decomposed by UV light. Hydrolysed in alkaline media. /Pynamin forte/[Tomlin CDS, ed. Allethrin|Hydroxyl radical reaction rate constant = 2.25X10-10 cu cm/molec-sec at 25 °C (est) /Allethrin I/

Insoluble in water.

Esters, Sulfate Esters, Phosphate Esters, Thiophosphate Esters, and Borate Esters

ALLETHRIN is an ester and ketone. Esters react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides. Ketones are reactive with many acids and bases liberating heat and flammable gases (e.g., H2). The amount of heat may be sufficient to start a fire in the unreacted portion of the ketone. Ketones react with reducing agents such as hydrides, alkali metals, and nitrides to produce flammable gas (H2) and heat. Ketones are incompatible with isocyanates, aldehydes, cyanides, peroxides, and anhydrides. They react violently with aldehydes, HNO3, HNO3 + H2O2, and HClO4.