Vanadium(V) oxychloride
1 Inquiries
7727-18-6
shanghai
as request
2024-02-21
13-Dimethyladamantane,1-Bromo-35-dimethyladamantane,perhydroacenaphthylene,4-[1,1-bis(4-hydroxyphenyl)ethyl]phenol,CYCLOBUTANE-1,2-DICARBOXYLIC ACID DIMETHYL ESTER, TRANS
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Product Description
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Seller Information
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Inquiry History
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DescriptionBasic Info
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Product Name:
Vanadium oxytrichloride
Other Name:Vanadium,trichlorooxo-,(T-4)-;Vanadium,trichlorooxo-;(T-4)-Trichlorooxovanadium;Vanadium oxychloride;Vanadium oxytrichloride;Vanadyl trichloride;Vanadium chloride oxide (VOCl3);Vanadyl chloride (VOCl3);Vanadyl chloride;Trichlorooxovanadium;Vanadium(V) oxytrichloride;Vanadium oxide trichloride;Vanadium trichloride oxide;Vanadium chloride oxide (VCl3O);Vanadium monoxide trichloride;Vanadium trichloride monooxide;Vanadium trichloride monoxide;Trichlorovanadium oxide;Trichlorooxovanadium(V);204864-21-1
CAS No.:7727-18-6
Molecular Formula:Cl3OV
InChIKeys:InChIKey=JBIQAPKSNFTACH-UHFFFAOYSA-K
Molecular Weight:173.30000
Exact Mass:171.84500
EC Number:231-780-2
UN Number:2443
DSSTox ID:DTXSID7064784
Color/Form:Lemon-yellow liquid|Yellow liquid, emitting red fumes on exposure to air|Fuming red-yellow liquid
Categories:
Characteristics-
PSA:
17.07000
XLogP3:1.94970
Appearance:Vanadium oxytrichloride appears as a lemon yellow liquid. Boiling point 257-260°F (125-127°C). Corrosive to metals and tissue. Used as a catalyst.
Density:1.829 g/cm3
Melting Point:-77 °C
Boiling Point:126-127 °C
Flash Point:126-127°C
Refractive Index:1.6300
Water Solubility:decomposes in H2O to vanadic acid and HCl; soluble methanol, ether, acetone, acids [KIR83] [MER06]
Storage Conditions:Containers of vanadium shall be kept tightly closed at all times when not in use. Containers shall be stored in a safe manner to minimize accidental breakage, spillage, or contact with moisture. Combustible materials, such as finely ground vanadium carbide, vanadium aluminum alloys, vanadium metal, or ferrovanadium should be kept away from heat, sparks, or flames. /Vanadium compounds/
Vapor Pressure:13.8 mm Hg ( 20 °C)
Vapor Density:5.98 (Air = 1)
Toxicity:LD50 orally in rats: 0.14 g/kg (Smyth)
Odor:Sharp unpleasant odor
Experimental Properties:Decomposes in presence of moisture into vanadic acid and HCl. When a small quantity of water is added, it becomes thick and almost blood-red because of formation of vanadic acid.|Nonionizing solvent; dissolves most nonmetals; dissolves and/or reacts with many organic compounds; hydrolyzes in moisture|Readily hydrolyzes and forms coordination compounds with simple donor molecules, e.g., ethers, but is reduced by reaction with sulfur-containing ligands and molecules; dissolves sulfur|Enthalpy of formation at 298.15 K: -734.7 kJ/mol (liquid); -695.6 kJ/mol (gas); molar heat capacity at 298.15 K: 89.9 J/mol K|Fumes in air. Reacts with moist air to form vanadic acid and hydrochloric acid fumes. Reacts exothermically with water to generate acidic fumes and acidic solutions. Violently hygroscopic.
Air and Water Reactions:Fumes in air. Reacts with moist air to form vanadic acid and hydrochloric acid fumes [Von Schwartz 1918. p.321]. Reacts exothermically with water to generate acidic fumes and acidic solutions. Violently hygroscopic.
Reactive Group:Acyl Halides, Sulfonyl Halides, and Chloroformates
Reactivity Alerts:Water-Reactive
Reactivity Profile:VANADIUM OXYTRICHLORIDE is incompatible with bases, including amines, with strong oxidizing agents, and with alcohols. May react vigorously or explosively if mixed with diisopropyl ether or other ethers in the presence of trace amounts of metal salts [J. Haz. Mat., 1981, 4, 291]. Combination with sodium metal led to a violent explosion [Bretherick 5th ed., 1995].
Corrosivity:In presence of moisture will corrode most metals
Heat of Vaporization:Enthalpy of vaporization = 36.78 kJ/mol at 127 °C
Critical Temperature & Pressure:Critical temperature: 636 deg K (measured); critical pressure: 3740 kPa (estimated)
Hazard IdentificationClassification of the substance or mixture
Skin corrosion, Sub-category 1C
Hazardous to the aquatic environment, long-term (Chronic) - Category Chronic 3
GHS label elements, including precautionary statements
Pictogram(s) 
Signal word Danger
Hazard statement(s) H314 Causes severe skin burns and eye damage
H412 Harmful to aquatic life with long lasting effects
Precautionary statement(s) Prevention P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P264 Wash ... thoroughly after handling.
P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/...
P273 Avoid release to the environment.
Response P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P363 Wash contaminated clothing before reuse.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P316 Get emergency medical help immediately.
P321 Specific treatment (see ... on this label).
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Storage P405 Store locked up.
Disposal P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.
Other hazards which do not result in classification
no data available
Handling and StoragePrecautions for safe handling
Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.
Conditions for safe storage, including any incompatibilities
Store the container tightly closed in a dry, cool and well-ventilated place. Store apart from foodstuff containers or incompatible materials.
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Seller Information
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Business Type:
Trader
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Main Products:
13-Dimethyladamantane,1-Bromo-35-dimethyladamantane,perhydroacenaphthylene,4-[1,1-bis(4-hydroxyphenyl)ethyl]phenol,CYCLOBUTANE-1,2-DICARBOXYLIC ACID DIMETHYL ESTER, TRANS
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Location:
Room 1623,Building A, ZhongqiaoCenter,Goverment District,Hefei city,Anhui Province,China
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Payment Terms:
TT against copy of documents,D/P,L/C,D/A,TT against B/L draft before shipment,100% TT in advance
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Average lead Time:
7
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Total Annual Revenue:
$1 million-$2.5 million
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Total Employees:
5-10
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Year of Establishment:
2019
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Inquiry History1 Inquiries
Country Product Purchase Quantity Date Posted 
India
Vanadium oxytrichloride
100 G Jul 31, 2024 Post an enquiry for this product