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Allyl chloride CAS:107-05-1

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CAS No.:

107-05-1

Grade:

Industrail Grade

Content:

99%

Port:

SHANGHAI

Brand:

Orient

Packaging:

25L, 200L, 1000L, customized

Price valid (until):

2025-12-26

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Qingdao Orient Chemical Co.,LTD

Company Type:

Trader

Location:

China

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Main Products:

pharmaceutical intermediates,peptides,electronic chemicals

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Product Description
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Inquiry History

Description

Allyl chloride Basic information

Product Name:	Allyl chloride
Synonyms:	2-propenylchloride;3-chloro-1-propen;3-Chloro-1-propylene;3-Chloroprene;3-chloro-prop-1-ene;3-chloro-propen;3-chloropropene (allyl chloride);3-chloropropene(allylchloride)
CAS:	107-05-1
MF:	C3H5Cl
MW:	76.52
EINECS:	203-457-6
Product Categories:	API Intermediate;omega-Functional Alkanols, Carboxylic Acids, Amines & Halides;omega-Unsaturated Halides;Benzimidazoles;Pharmaceutical Intermediates
Mol File:	107-05-1.mol

Allyl chloride Chemical Properties

Melting point	-136 °C
Boiling point	44-46 °C(lit.)
density	0.939 g/mL at 25 °C(lit.)
vapor density	2.6 (vs air)
vapor pressure	20.58 psi ( 55 °C)
refractive index	n20/D 1.414(lit.)
Fp	−20 °F
storage temp.	Store at +2°C to +8°C.
solubility	alcohol: miscible(lit.)
form	Powder/Solid
color	White
Specific Gravity	0.939
Odor	pungent odor
explosive limit	3.3-11.2%(V)
Water Solubility	3.6 G/L (20 ºC)
FreezingPoint	-134.5℃
Merck	14,289
BRN	635704
Henry's Law Constant	2.69 at 25 °C (static headspace-GC, Welke et al., 1998)
Dielectric constant	8.2（20℃）
Exposure limits	NIOSH REL: TWA 1 ppm (3 mg/m³), STEL 2 ppm (6 mg/m³), IDLH 250 ppm; OSHA PEL: TWA 1 ppm; ACGIH TLV: STEL 2 ppm.
Stability:	Stable, but reacts vigorously or violently with a wide variety of materials. Highly flammable. Incompatible with strong oxidizing agents, acids, amines, peroxides, chlorides of iron and aluminium, BF3, aromatic hydrocarbons, Lewis acids, metals, caustics, ammonia, ferric chloride, ethylene imine, ethylenediamine. Heat and light sensitive
LogP	2.1 at 25℃
CAS DataBase Reference	107-05-1(CAS DataBase Reference)
NIST Chemistry Reference	1-Propene, 3-chloro-(107-05-1)
IARC	3 (Vol. 36, Sup 7, 71, 125) In prep.
EPA Substance Registry System	Allyl chloride (107-05-1)

Safety Information

Hazard Codes	F,Xn,N,T
Risk Statements	45-46-11-20/21/22-36/37/38-48/20-50-68-40-39/23/24/25-23/24/25-48/23/24/25
Safety Statements	53-26-36/37-45-61-46-25-16-7
RIDADR	UN 1100 3/PG 1
OEB	B
OEL	TWA: 1 ppm (3 mg/m3), STEL: 2 ppm (6 mg/m3)
WGK Germany	2
RTECS	UC7350000
F	19
Autoignition Temperature	390 °C
Hazard Note	Flammable
TSCA	Yes
HS Code	2903 29 00
HazardClass	3
PackingGroup	I
Hazardous Substances Data	107-05-1(Hazardous Substances Data)
Toxicity	LD50 orally in rats: 0.7 g/kg (Smyth, Carpenter)
IDLA	250 ppm

Allyl chloride Usage And Synthesis

Chemical Properties	colourless, light yellow or amber liquid with an unpleasant smell
Chemical Properties	Allyl chloride is a colorless liquid, insoluble in water but soluble in common organic solvents. Allyl chloride is prepared by the reaction of propylene with chlorine. It is a common alkylating agent relevant to the manufacture of pharmaceuticals and pesticides. It is also a component in some thermo-setting resins. Allyl chloride has been produced commercially since 1945 and is used almost exclusively as a chemical intermediate, principally in the production of epichlorohydrin or as a raw material for epichlorohydrin. It is also used as a chemical intermediate in the preparation of glycerin, glycerol chlorohydrins, glycidyl ethers, allylamines, and allyl ethers of trimethylpropane, sodium allyl sulfonate, a series of allyl amines and quaternary ammonium salts, allyl ethers, and a variety of alcohols, phenols, and polyols. It is also used in pharmaceuticals as a raw material for the production of allyl isothiocyanate (synthetic mustard oil), allyl substituted barbiturates (sedatives), and cyclopropane (anesthetic); in the manufacture of specialty resins for water treatment and to produce babiturate and hypnotic agents such as aprobarbital, butalbital, methohexital sodium, secobarbital, talbutal, and thiamyl sodium.
Chemical Properties	Allyl chloride is a highly reactive and flammable, colorless, brown or purple liquid, with an unpleasant, pungent odor.
Physical properties	Colorless to light brown to reddish-brown liquid with a pungent, unpleasant, garlic-like odor. An experimentally determined odor threshold concentration of 470 ppb_v was reported by Leonardos et al. (1969).
History	Allyl chloride, the only chloropropene of industrial importance, was first produced in 1857 by A. CAHOURS and A. W. HOFMANN by reacting phosphorus chloride with allyl alcohol. The name allyl is derived from the latin allium, meaning garlic. Inhalation of even small amounts of allyl chloride produces, after a short time, the characteristic odor of garlic on the breath. At the end of the 1930s, IG Farbenindustrie and the Shell Development Co. developed the high-temperature chlorination of propene, permitting large-scale production of allyl chloride with good yields. A significant part of the development was done by the Shell Chemical Co. when erecting a commercial plant in 1945. Dow, Solvay, and Asahi-Kashima developed their own processes.
Reactivity Profile	1.Reactions of the Double Bond The reaction of allyl chloride with oxygen in the liquid phase at ca. 120 ℃ and in the presence of metal acetates or hydrogen peroxide yields glycerol monochlorohydrin. Halogens add readily to the double bond yielding the corresponding trihalogeno compounds. The reaction with hypochlorous acid, yielding 2,3- and 1,3-glycerol dichlorohydrins (which are then dehydrochlorinated with alkali to give epichlorohydrin), is of great industrial importance. Allyl chloride reacts with hydrogen halides to form 1,2-dihalogeno compounds. In the presence of peroxides, the reaction with hydrobromic acid yields 1-bromo-3chloropropane (Kharasch effect), but in highly concentrated hydrogen peroxide solution, 1,2-dibromo- 3-chloropropane is formed. Addition reactions of silanes, boranes, carboranes, and phosphorus trichloride, as well as cycloadditions of allyl cations with alkenes, are known. Allyl chloride polymerizes with sulfur dioxide to form polysulfones. 2.Reactions of the Chlorine Atom Recently, Allyl alcohol is produced increasingly by the isomerization of propene oxide. The chlorine atom is replaced easily by iodide, cyanide, isothiocyanate, sulfide, polysulfides (giving rubber-like condensation products), and alkyl thiols. The salts of carboxylic acids yield allyl esters (e.g., diallyl phthalate), which are easily polymerized to allyl resins or are copolymerized with other monomers. Sodium allyl sulfonate is obtained on reaction with sodium sulfite. The reaction of allyl chloride with ammonia yields a mixture of mono-, di-, and triallylamines, and the reaction with primary and secondary amines makes the corresponding alkylallylamines. Phase-transfer-catalyzed carbonylation (e.g., with Ni(CO)4 or (Me4N)2 [Ni6(CO)12]) in the presence of sodium hydroxide leads to the sodium salt of vinylacetic acid. In the presence of alkalis, allyl chloride reacts with polyols to form the corresponding allyl ethers.
Uses	Allyl chloride is used in the synthesis of glycerol, allyl alcohol and epichlorohydrin.
Uses	Manufacture of epichlorohydrin, epoxy resin, glycerin pesticides, and sodium allyl sulfonate
Uses	Allyl chloride (3-chloropropene; 1-chloro-2-propene) is a chemical intermediate used in the synthesis of allyl compounds found in varnish, resins, polymers, pesticides, and pharmaceuticals (O’Neil, 2001).
Production Methods	Allyl chloride can be synthesized by reaction of allyl alcohol with HCl or by treatment of allyl formate with HCl in the presence of a catalyst (ZnCl2).
Definition	ChEBI: Allyl chloride is an organochlorine compound.
General Description	A clear colorless liquid with an unpleasant pungent odor. Flash point -20°F. Boiling point 113°F. Less dense than water (7.8 lb / gal) and insoluble in water. Hence floats on water. Vapor irritates skin, eyes and mucous membranes. Vapors are heavier than air. Long exposure to low concentrations or short exposure to high concentrations may have adverse health effects from inhalation or skin absorption.
Air & Water Reactions	Highly flammable. Insoluble in water.

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A: Yes, we can provide free sample, you only need pay the shipping cost.

Q2: What is the lead time?

A: For stock goods, it usually take about 5-7 days by air, 15-30 days by sea,For customized products, the delivery time needs to be confirmed based on the actual situation.

Q3: How can I buy? What is the payment method?

A: You can contract us through Email or you can browse our website:orientchem.cc, we have bank transfer,

Q4:What if there are quality issues？

A：We attach great importance to after-sales service of our products. If there are any quality issues, please contact us within 30 days of receiving the goods and we will handle returns and exchanges for you.

Certificates

Basic Info

Product Name:

Allyl chloride

Other Name:

1-Propene,3-chloro-;Propene,3-chloro-;3-Chloro-1-propene;Allyl chloride;1-Chloro-2-propene;3-Chloropropylene;3-Chloropropene;2-Propenyl chloride;NSC 20939;HCO 1260ZF

CAS No.:

107-05-1

Molecular Formula:

C3H5Cl

InChIKeys:

InChIKey=OSDWBNJEKMUWAV-UHFFFAOYSA-N

Molecular Weight:

76.523

Exact Mass:

76.52

BRN:

635704

EC Number:

203-457-6

HScode:

2903291000

Categories:

Bulk Drug Intermediates

Characteristics

PSA:

XLogP3:

2.1

Appearance:

Allyl chloride appears as a clear colorless liquid with an unpleasant pungent odor. Flash point -20°F. Boiling point 113°F. Less dense than water (7.8 lb / gal) and insoluble in water. Hence floats on water. Vapor irritates skin, eyes and mucous membranes. Vapors are heavier than air. Long exposure to low concentrations or short exposure to high concentrations may have adverse health effects from inhalation or skin absorption.

Density:

0.938 g/cm³ @ Temp: 20 °C

Melting Point:

-135 °C

Boiling Point:

44-45 °C

Flash Point:

-25°F

Refractive Index:

1.401

Water Solubility:

H2O: 3.6 G/L (20 ºC)

Storage Conditions:

Keep containers sealed. Remove any sources of ignition.

Vapor Pressure:

Vapour pressure, kPa at 20°C: 39.3

Vapor Density:

2.64

Toxicity:

Oral-Rat LD50: 1100 mg/kg; Oral-Mouse LD50: 425 mg/kg

Flammability characteristics:

Class IB Flammable Liquid: Fl.P. below 73°F and BP at or above 100°F.

Explosive limit:

vol% in air: 2.91.2

Odor:

Pungent, unpleasant odor.

See More Allyl chloride Properties 

Hazard Identification

Classification of the substance or mixture

Flammable liquids, Category 2

Acute toxicity - Category 4, Oral

Acute toxicity - Category 4, Dermal

Skin irritation, Category 2

Eye irritation, Category 2

Acute toxicity - Category 4, Inhalation

Specific target organ toxicity â single exposure, Category 3

Germ cell mutagenicity, Category 2

Carcinogenicity, Category 2

Specific target organ toxicity â repeated exposure, Category 2

Hazardous to the aquatic environment, short-term (Acute) - Category Acute 1

GHS label elements, including precautionary statements

Precautionary statement(s)
Pictogram(s)
Signal word	Danger
Hazard statement(s)	H225 Highly flammable liquid and vapour H302 Harmful if swallowed H312 Harmful in contact with skin H315 Causes skin irritation H319 Causes serious eye irritation H332 Harmful if inhaled H335 May cause respiratory irritation H341 Suspected of causing genetic defects H351 Suspected of causing cancer H373 May cause damage to organs through prolonged or repeated exposure H400 Very toxic to aquatic life
Prevention	P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P233 Keep container tightly closed. P240 Ground and bond container and receiving equipment. P241 Use explosion-proof [electrical/ventilating/lighting/...] equipment. P242 Use non-sparking tools. P243 Take action to prevent static discharges. P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/... P264 Wash ... thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P271 Use only outdoors or in a well-ventilated area. P203 Obtain, read and follow all safety instructions before use. P260 Do not breathe dust/fume/gas/mist/vapours/spray. P273 Avoid release to the environment.
Response	P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse affected areas with water [or shower]. P370+P378 In case of fire: Use ... to extinguish. P301+P317 IF SWALLOWED: Get medical help. P330 Rinse mouth. P302+P352 IF ON SKIN: Wash with plenty of water/... P317 Get medical help. P321 Specific treatment (see ... on this label). P362+P364 Take off contaminated clothing and wash it before reuse. P332+P317 If skin irritation occurs: Get medical help. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P319 Get medical help if you feel unwell. P318 IF exposed or concerned, get medical advice. P391 Collect spillage.
Storage	P403+P235 Store in a well-ventilated place. Keep cool. P403+P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up.
Disposal	P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.

Other hazards which do not result in classification

no data available

Handling and Storage

Precautions for safe handling

NO open flames, NO sparks and NO smoking. Closed system, ventilation, explosion-proof electrical equipment and lighting. Do NOT use compressed air for filling, discharging, or handling. Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.

Conditions for safe storage, including any incompatibilities

Fireproof. Separated from food and feedstuffs and incompatible materials. See Chemical Dangers. Dry.Ambient storage temperature, venting should be pressure-vacuum type.

See More Allyl chloride Safety Data Sheet 

Seller Information

Business Type:
Trader

Main Products:
pharmaceutical intermediates,peptides,electronic chemicals

Location:
Room 102, 1st Floor, East Office Building, No. 45 Pengwan Road, Qianwan Bonded Port Area, Qingdao Zone, China (Shandong) Pilot Free Trade Zone

Payment Terms:
100% TT in advance

Average lead Time:
10

Total Annual Revenue:
$10 million-$25 million

Total Employees:
51-100

Year of Establishment:
2024

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We are mainly specilized in supply of pharmaceutical intermediates, electronic chemicals，food additives, and other fine chemical products.
Integrity is the foundation, quality is life. We would like to work together with you to build a greener and brighter future.

Website: orientchem.cc
Email: scarlett@orientchem.cc
WhatsApp: +86 17753254221

Inquiry History

8 Inquiries

Country	Product	Purchase Quantity	Date Posted
Russia	Allyl Chloride	40 MT	Mar 27, 2026
India	allyl chloride	40 MT	Jul 13, 2026
India	Allyl Chloride	1 20' Fcl	Jun 24, 2026
Chile	Allyl chloride	1 MT	Aug 28, 2024
India	Allyl Chloride	115 MT	Feb 15, 2024
India	ALLYL CHLORIDE	1 20' Fcl	Feb 26, 2026
India	ALLYL CHLORIDE COMMERCIAL	700.00 KG	Nov 3, 2025
Russia	Allyl chloride	180 TON	Jan 29, 2024

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Allyl chloride CAS:107-05-1

Product Description

Seller Information

Inquiry History

Classification of the substance or mixture

GHS label elements, including precautionary statements

Other hazards which do not result in classification

Precautions for safe handling

Conditions for safe storage, including any incompatibilities

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