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Acrylic anhydride 2051-76-5 C6H6O3

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Unit Price: Get Latest Price
CAS No.:

2051-76-5

Grade:

Industrail Grade

Content:

99%

Port:

shanghai

Brand:

Orient

Packaging:

25L, 200L, 1000L, customized

Price valid (until):

2026-01-17

Company Type:
Trader
Location:
China
Qualification:
Main Products:

pharmaceutical intermediates,peptides,electronic chemicals

  • Product Description

  • Seller Information

  • Inquiry History

  • Description
    Product Name: Acrylic anhydride
    Synonyms: ACRYLIC ANHYDRIDE;ACRYLIC ACID ANHYDRIDE;2-PROPENOIC ACID ANHYDRIDE;Acyrlic acid anhydride;PROPENOIC ANHYDRIDE;Diacrylic anhydride;acrylic acid acryloyl ester;prop-2-enoyl prop-2-enoate
    CAS: 2051-76-5
    MF: C6H6O3
    MW: 126.11
    EINECS: 218-128-2
    Product Categories: monomer;Organic acids
    Mol File: 2051-76-5.mol
    Shop Acrylic anhydride 2051-76-5 C6H6O3-Detailed Image 1

    Acrylic anhydride Chemical Properties
    Melting point  -20 °C
    Boiling point  85-86°C 17mm
    density  1,094 g/cm3
    Fp  77°C
    storage temp.  2-8°C
    solubility  Chloroform (Sparingly), Ethyl Acetate (Slightly)
    form  clear liquid
    color  Colorless to Almost colorless
    Stability: Moisture sensitive
    InChI InChI=1S/C6H6O3/c1-3-5(7)9-6(8)4-2/h3-4H,1-2H2
    InChIKey ARJOQCYCJMAIFR-UHFFFAOYSA-N
    SMILES C(=O)(C=C)OC(=O)C=C
    CAS DataBase Reference 2051-76-5(CAS DataBase Reference)

    Safety Information
    Risk Statements  14-20/21/22-34
    Safety Statements  26-36/37/39-45
    RIDADR  3265
    HazardClass  8
    PackingGroup  II
    HS Code  2916199590
    MSDS Information


    Acrylic anhydride Usage And Synthesis
    Description Acrylic anhydride is used to prepare specialty acrylate, acrylamide monomers. Forms cyclic anhydrides on polymerization and does not produce crosslinks in polymers. It is used in the preparation of acrylic resin. And it is also used in organic synthesis. For example: it can react with adamantan-1-ol to get acrylic acid adamantan-1-yl ester. This reaction needs catalytic agent acidic catalyst and solvent cyclohexane by heating. The yield is 95%.
    Uses Acrylic anhydride can be used to prepare specialty acrylate, acrylamide monomers or acrylic resin. It forms cyclic anhydrides on polymerization and can not be used as a crosslinker.
    Synthesis The synthesis of Acrylic anhydride is as follows:
    In a 3-liter, four-necked glass reactor provided with a thermometer and a stirrer were placed, in a dry air atmosphere, 1,240 g of methylene chloride, 1.08 g (0.5% by mass) of Sumilizer GM, 0.65 g (0.3% by mass) of Sumilizer TP-D, 0.65 g (0.3% by mass) of Sumilizer WX-R, 216 g (3.0 mol) of acrylic acid and 264 g (1.5 mol) of benzenesulfonyl chloride. The mixture was cooled to 5°C. Then, 304 g (3.0 mol, 1 equivalent relative to the acids generated from benzenesulfonyl chloride) of triethylamine was dropwise added in 2 hours with the temperature of the reaction mixture being controlled at 30°C or lower. After the completion of the dropwise addition, stirring was made for 1 hour with the same temperature being kept. The reaction mixture was analyzed by GC, which indicated that the conversion of acrylic acid was 99%. After the completion of the reaction, 375 g of water was added to the reaction mixture to wash the reaction mixture. The reaction mixture was further washed twice each time with 563 g of water, after which distillation was conducted to remove methylene chloride. The yield of the acrylic acid anhydride obtained was 172 g and 91% and its purity by GC analysis was 99%, and no high-molecular by-product was detected.
    Shop Acrylic anhydride 2051-76-5 C6H6O3-Detailed Image 2

    First aid measures

    If inhaled

    Move the victim into fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration and consult a doctor immediately. Do not use mouth to mouth resuscitation if the victim ingested or inhaled the chemical.

    Following skin contact

    Take off contaminated clothing immediately. Wash off with soap and plenty of water. Consult a doctor.

    Following eye contact

    Rinse with pure water for at least 15 minutes. Consult a doctor.

    Following ingestion

    Rinse mouth with water. Do not induce vomiting. Never give anything by mouth to an unconscious person. Call a doctor or Poison Control Center immediately.

    Accidental release measures


    Personal precautions, protective equipment and emergency procedures

    Avoid dust formation. Avoid breathing mist, gas or vapours.Avoid contacting with skin and eye. Use personal protective equipment.Wear chemical impermeable gloves. Ensure adequate ventilation.Remove all sources of ignition. Evacuate personnel to safe areas.Keep people away from and upwind of spill/leak. Environmental precautions

    Prevent further spillage or leakage if it is safe to do so. Do not let the chemical enter drains. Discharge into the environment must be avoided. Methods and materials for containment and cleaning up

    Collect and arrange disposal. Keep the chemical in suitable and closed containers for disposal. Remove all sources of ignition. Use spark-proof tools and explosion-proof equipment. Adhered or collected material should be promptly disposed of, in accordance with appropriate laws and regulations.

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    ——  Q&A  ——

    Q1:Do you provide sample?

    A: Yes, we can provide free sample, you only need pay the shipping cost.

    Q2: What is the lead time?

    A: For stock goods, it usually take about 5-7 days by air, 15-30 days by sea,For customized products, the delivery time needs to be confirmed based on the actual situation.

    Q3: How can I buy? What is the payment method?

    A: You can contract us through Email or you can browse our website:orientchem.cc, we have bank transfer, 

    Q4:What if there are quality issues?

    A:We attach great importance to after-sales service of our products. If there are any quality issues, please contact us within 30 days of receiving the goods and we will handle returns and exchanges for you.



    Certificates

    Basic Info
    Product Name:

    Acrylic anhydride

    Other Name:

    2-Propenoic acid,1,1′-anhydride;Acrylic anhydride;2-Propenoic acid,anhydride;Acrylic acid anhydride;NSC 32616;Diacrylic acid anhydride;Prop-2-enoyl prop-2-enoate;2055573-70-9

    CAS No.:

    2051-76-5

    Molecular Formula:

    C6H6O3

    InChIKeys:

    InChIKey=ARJOQCYCJMAIFR-UHFFFAOYSA-N

    Molecular Weight:

    126.110

    Exact Mass:

    126.11

    EC Number:

    218-128-2

    NSC Number:

    32616

    HScode:

    2916190090

    Characteristics
    PSA:

    43.37000

    XLogP3:

    0.71

    Density:

    1.1±0.1 g/cm3

    Melting Point:

    -20 °C

    Boiling Point:

    60-66 °C @ Press: 10-12 Torr

    Flash Point:

    85.7±15.9 °C

    Refractive Index:

    1.438

    Vapor Pressure:

    0.272mmHg at 25°C

    Hazard Identification

    Classification of the substance or mixture

    Not classified.

    GHS label elements, including precautionary statements

    Pictogram(s)
    Signal word

    Danger

    Hazard statement(s)

    H302 Harmful if swallowed

    H312 Harmful in contact with skin

    H314 Causes severe skin burns and eye damage

    H332 Harmful if inhaled

    Precautionary statement(s)
    Prevention

    none

    Response

    none

    Storage

    none

    Disposal

    none

    Other hazards which do not result in classification

    no data available

    Handling and Storage

    Precautions for safe handling

    Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.

    Conditions for safe storage, including any incompatibilities

    Store the container tightly closed in a dry, cool and well-ventilated place. Store apart from foodstuff containers or incompatible materials.

  • Seller Information
    Business Type:

    Trader

    Main Products:

    pharmaceutical intermediates,peptides,electronic chemicals

    Location:

    Room 102, 1st Floor, East Office Building, No. 45 Pengwan Road, Qianwan Bonded Port Area, Qingdao Zone, China (Shandong) Pilot Free Trade Zone

    Payment Terms:

    100% TT in advance

    Average lead Time:

    10

    Total Annual Revenue:

    $10 million-$25 million

    Total Employees:

    51-100

    Year of Establishment:

    2024

    A reliable supplier is like insurance.

    We are mainly specilized in supply of pharmaceutical intermediates, electronic chemicals,food additives, and other fine chemical products.
    Integrity is the foundation, quality is life. We would like to work together with you to build a greener and brighter future.

    Website: orientchem.cc
    Email: scarlett@orientchem.cc
    WhatsApp: +86 17753254221

  • Inquiry History
    3 Inquiries
    Country Product Purchase Quantity Date Posted
    South Korea

    Acrylic anhydride

    200 KG Dec 16, 2025
    India

    Acrylic anhydride

    1 KG Oct 31, 2024
    India

    Acrylic anhydride

    1 KG Nov 22, 2024
    Post an enquiry for this product
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