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1-Chloro-3-nitrobenzene121-73-3

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CAS No.:

121-73-3

Grade:

Industrial Grade

Content:

99.5%

Port:

上海

Brand:

OORENT

Packaging:

Vial/Bottle/Bag/Carton

Price valid (until):

2026-07-17

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Product Description
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Description

Product Detail

1-Chloro-3-nitrobenzene Basic information

Product Name:	1-Chloro-3-nitrobenzene
Synonyms:	1-chloronitrobenzene;1-nitro-3-chlorobenzene;3-Chloro-1-nitrobenzene;Benzene,1-chloro-3-nitro-;Chloro-m-nitrobenzene;Metachloronitrobenzene;m-nitrochlorobenzene(1-chloro-3-nitrobenzene);Nitrochlorobenzene, meta-
CAS:	121-73-3
MF:	C6H4ClNO2
MW:	157.55
EINECS:	204-496-1
Product Categories:	Benzene derivates;Agrochemical Intermediates;Intermediates of Dyes and Pigments;Alpha Sort;Analytical Standards;AromaticsVolatiles/ Semivolatiles;Nitro Compounds;Nitrogen Compounds;C;CAlphabetic;CHChemical Class;Chemical Class;ChloroAnalytical Standards;Halogenated;Organic Building Blocks
Mol File:	121-73-3.mol

1-Chloro-3-nitrobenzene Chemical Properties

Melting point	43-47 °C(lit.)
Boiling point	236 °C(lit.)
density	1.534 g/mL at 25 °C(lit.)
vapor pressure	1.9Pa at 25℃
refractive index	1.5545 (estimate)
Fp	218 °F
storage temp.	Store below +30°C.
solubility	alcohol: freely soluble (hot)(lit.)
form	powder to lump to clear liquid
color	White or Colorless to Yellow
PH	7 (0.26g/l, H2O, 20℃)
Water Solubility	INSOLUBLE
Merck	14,2151
BRN	1907947
Henry's Law Constant	1.4×10⁰ mol/(m³Pa) at 25℃, Chao et al. (2017)
Stability:	Stable. Incompatible with strong oxidizing agents, strong acids, strong reducing agents.
LogP	2.49
CAS DataBase Reference	121-73-3(CAS DataBase Reference)
NIST Chemistry Reference	Benzene, 1-chloro-3-nitro-(121-73-3)
EPA Substance Registry System	m-Chloronitrobenzene (121-73-3)

Safety Information

Hazard Codes	Xn,N,T
Risk Statements	22-50/53-23/24/25
Safety Statements	22-24/25-60-61-45-38-36/37/39-28A
RIDADR	UN 1578 6.1/PG 2
WGK Germany	2
RTECS	CZ0940000
Autoignition Temperature	500 °F
TSCA	TSCA listed
HazardClass	6.1
PackingGroup	II
HS Code	29049085
Hazardous Substances Data	121-73-3(Hazardous Substances Data)
Toxicity	mouse,LD50,oral,380mg/kg (380mg/kg),Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 25(8), Pg. 50, 1981.

MSDS Information

Provider	Language
1-Chloro-3-nitrobenzene	English
ACROS	English
SigmaAldrich	English
ALFA	English

1-Chloro-3-nitrobenzene Usage And Synthesis

Chemical Properties	Moist tan or pale yellow crystalline solid
Uses	Intermediate for dyes. 1-Chloro-3-nitrobenzene was used in the preparation of aromatic azo compounds using gold (Au) nanoparticles supported on TiO2 as a catalyst. It was also used as surrogate standard to evaluate the removal of 2,4-dinitrotoluene from contaminated soils using enhanced electrokinetic remediation.
Production Methods	m-Chloronitrobenzene is of lesser economic importance than its ortho- and para-isomers, with no U.S. production reported. The annual production in Germany was reported to be on the order of 1000–3000 metric tons. It has limited use in the manufacturing of dyes and agricultural chemicals. There is no information on potential exposure. Chloronitrobenzene has been detected in the surface water of the Rhine River with concentrations between 20 and 500 ng/L and in fish at levels of up to 1 mg/kg.
Definition	ChEBI: 1-chloro-3-nitrobenzene is a C-nitro compound that is nitrobenzene in which one of the meta- hydrogens has been replaced by chlorine. It is a C-nitro compound and a member of monochlorobenzenes.
General Description	Pale yellow crystals. Insoluble in water.
Air & Water Reactions	Insoluble in water.
Reactivity Profile	3-Nitrochlorobenzene can react with oxidizing materials. .
Hazard	Toxic by inhalation and ingestion. Combustible. Questionable carcinogen.
Fire Hazard	Flash point data for 3-Nitrochlorobenzene are not available. 3-Nitrochlorobenzene is probably combustible.
Flammability and Explosibility	Not classified
Safety Profile	Poison by ingestion and inhalation. It forms methemoglobin in the body and gves rise to cyanosis and blood changes. Its effects are cumulative and analogous to those of nitrobenzene. The para compound is thought to be somewhat less toxic than the ortho compound. Chemically, it is probably converted in the body to chloroaniline, whch is also poisonous. In industry, it is the dust of hs material that is most often the source of intoxication. Flammable liquid and dangerous fire hazard when exposed to heat or flame. It can react with oxidizing materials. When heated to decomposition it emits toxic fumes of Cl-, NOx, and phosgene. See also other chloronitrobenzene entries and NITRO COMPOUNDS of AROMATIC HYDROCARBONS.
Synthesis	1-Chloro-3-nitrobenzene was synthesised from 4-chloro-2-nitro-benzoic acid by adding copper iodide, triethylamine and dimethyl sulfoxide in the presence of inert gas using the Schlenk technique.
Purification Methods	Crystallise the nitrobenzene from MeOH or 95% EtOH (charcoal), then pentane. [Beilstein 5 IV 722.]

1-Chloro-3-nitrobenzene Preparation Products And Raw materials

Raw materials	Sulfuric acid-->Nitric acid-->Chlorobenzene-->4-Chloronitrobenzene
Preparation Products	2-Nitrochlorobenzene-->3-Chloroaniline-->FAST ORANGE GC SALT-->3-CHLOROANILINE HYDROCHLORIDE-->3-CHLORO-N-METHYLANILINE-->2,6-Difluoronitrobenzene-->2,4-Dichloronitrobenzene-->3-AMINOBIPHENYL-->FAST ORANGE GC SALT

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Basic Info

Product Name:

1-Chloro-3-nitrobenzene

Other Name:

Benzene,1-chloro-3-nitro-;1-Chloro-3-nitrobenzene;3-Nitrochlorobenzene;3-Chloronitrobenzene;3-Chloro-1-nitrobenzene;m-Nitrochlorobenzene;m-Chloronitrobenzene;NSC 5502;3-Nitrophenyl chloride;3-Nitro-1-chlorobenzene;1-Nitro-3-chlorobenzene

CAS No.:

121-73-3

Molecular Formula:

C6H4ClNO2

InChIKeys:

InChIKey=KMAQZIILEGKYQZ-UHFFFAOYSA-N

Molecular Weight:

157.55

Exact Mass:

157.55

BRN:

1907947

EC Number:

204-496-1

UNII:

8XSA3GF8O1

ICSC Number:

1633

NSC Number:

5502

UN Number:

1578

DSSTox ID:

DTXSID4021971

Color/Form:

Pale-yellow orthorhombic prisms from alcohol

HScode:

29049085

Categories:

Hydrocarbons and Derivatives

Characteristics

PSA:

45.8

XLogP3:

2.41

Appearance:

3-chloronitrobenzene appears as pale yellow crystals. Insoluble in water. (NTP, 1992)

Density:

1.534 g/cm³ @ Temp: 20 °C

Melting Point:

46 °C

Boiling Point:

236 °C @ Press: 760 Torr

Flash Point:

218 °F

Refractive Index:

1.5545 (estimate)

Water Solubility:

H2O: INsoluble ;alcohol: freely soluble (hot)(lit.)

Storage Conditions:

Store below +30°C.

Vapor Pressure:

Vapour pressure, Pa at 20°C: 5

Vapor Density:

Relative vapour density (air = 1): 5.44

Toxicity:

Oral-rat LD50：420 mg/kg；Oral-Mouse LD50：380 mg/kg

Flammability characteristics:

Combustible in case of open fire; burning produces toxic chloride and nitrogen oxide fumes

Henrys Law Constant:

1.35e-05 atm-m3/mole|Henry's Law constant = 1.35X10-5 atm-cu m/mol at 25 °C

Experimental Properties:

Heat of fusion: 29.38 cal/g|CAN REACT WITH OXIDIZING MATERIALS|Hydroxyl radical reaction rate constant = 1.20X10-13 cu cm/molec-sec at 25 °C (est)

Air and Water Reactions:

Insoluble in water.

Reactive Group:

Nitro, Nitroso, Nitrate, and Nitrite Compounds, Organic

Reactivity Profile:

3-CHLORONITROBENZENE can react with oxidizing materials. (NTP, 1992).

Autoignition Temperature:

500 °F (260 °C)|500 °C

Heat of Combustion:

-2.82E+9 J/kmol

Flammable Limits:

Lower flammable limit: 1.4% by volume; Upper flammable limit: 8.7% by volume

Physical Dangers:

Dust explosion possible if in powder or granular form, mixed with air.

Heat of Vaporization:

5.58E+7 J/kmol at melting point at 317.65 deg K

Critical Temperature & Pressure:

Critical temperature = 742.0 deg K; Critical pressure = 3.98E+6 Pa

See More 1-Chloro-3-nitrobenzene Properties 

Hazard Identification

Classification of the substance or mixture

Acute toxicity - Category 4, Oral

Eye irritation, Category 2

GHS label elements, including precautionary statements

Precautionary statement(s)
Pictogram(s)
Signal word	Warning
Hazard statement(s)	H302 Harmful if swallowed H319 Causes serious eye irritation
Prevention	P264 Wash ... thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/...
Response	P301+P317 IF SWALLOWED: Get medical help. P330 Rinse mouth. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Storage	none
Disposal	P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.

Other hazards which do not result in classification

no data available

Handling and Storage

Precautions for safe handling

NO open flames. Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.

Conditions for safe storage, including any incompatibilities

Separated from combustible substances, reducing agents and food and feedstuffs. Store in an area without drain or sewer access. Provision to contain effluent from fire extinguishing.Store in a cool, dry, well ventilated location. Separate from alkalies and oxidizing materials.

See More 1-Chloro-3-nitrobenzene Safety Data Sheet 

Seller Information

Business Type:
Trader

Main Products:
pharmaceutical intermediates,peptides,electronic chemicals

Location:
Room 102, 1st Floor, East Office Building, No. 45 Pengwan Road, Qianwan Bonded Port Area, Qingdao Zone, China (Shandong) Pilot Free Trade Zone

Payment Terms:
100% TT in advance

Average lead Time:
10

Total Annual Revenue:
$10 million-$25 million

Total Employees:
51-100

Year of Establishment:
2024

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1-Chloro-3-nitrobenzene121-73-3

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