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CAS No.:

92-67-1

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Pharmaceutical Grade

Content:

99.99%

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Shanghai

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Orient

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2026-07-24

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As an integrated chemical foreign trade firm, we combine independent R&D, manufacturing, bespoke production and global distribution, focusing on delivering high-quality chemical supplies and comprehensive professional services to clients around the globe.

With rich experience accumulated in the chemical sector, we have built a complete industrial layout. Stable product performance, flexible custom manufacturing solutions and thoughtful customer support have won wide recognition from partners worldwide.

We own a modern, well-equipped chemical manufacturing plant equipped with intelligent automated production lines and strict quality inspection systems. Built in accordance with international standards and certified by relevant industrial authorities, our plant adopts standardized, safe and environmentally compliant production procedures. Every link from raw material procurement to finished product packaging is operated and monitored by professional teams to maintain stable and consistent product quality.

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4-Aminobiphenyl Basic information

Product Name:	4-Aminobiphenyl
Synonyms:	4-adp;[1,1'-BIPHENYL]-4-AMINE;AKOS BBS-00000786;4-BIPHENYLAMINE;4-BIPHENYLYLAMINE;4-AMINOBIPHENYL;4-PHENYLANILINE;4-phenylbenzenamine
CAS:	92-67-1
MF:	C12H11N
MW:	169.22
EINECS:	202-177-1
Product Categories:	Amines;Aromatics;Mutagenesis Research Chemicals
Mol File:	92-67-1.mol

4-Aminobiphenyl Chemical Properties

Melting point	52-54 °C(lit.)
Boiling point	191 °C15 mm Hg(lit.)
density	1.1154 (rough estimate)
vapor pressure	6 x 10^-5 mmHg at 20–30 °C (quoted, Mercer et al., 1990)
refractive index	1.5785 (estimate)
Fp	>110°C
storage temp.	-20°C Freezer
solubility	Soluble in Dichloromethane, DMSO and Methanol
form	powder
pka	4.35(at 18℃)
color	Brown to Dark Yellow
Water Solubility	842 mg/L at 20–30 °C (quoted, Mercer et al., 1990)
Merck	13,1235
BRN	386533
Henry's Law Constant	(x 1010 atmm³/mol): 3.89 at 25 °C (calculated, Mercer et al., 1990)
Stability:	Stable, but slowly reacts with oxygen in the air. Combustible. Incompatible with strong oxidizing agents, acids, acid anhydrides, acid chlorides.
InChI	1S/C12H11N/c13-12-8-6-11(7-9-12)10-4-2-1-3-5-10/h1-9H,13H2
InChIKey	DMVOXQPQNTYEKQ-UHFFFAOYSA-N
SMILES	Nc1ccc(cc1)-c2ccccc2
CAS DataBase Reference	92-67-1(CAS DataBase Reference)
IARC	1 (Vol. 1, Sup 7, 99, 100F) 2012
NIST Chemistry Reference	4-Aminobiphenyl(92-67-1)
EPA Substance Registry System	4-Aminobiphenyl (92-67-1)

Safety Information

Hazard Codes	T,Xn
Risk Statements	45-22-36/37/38-20/21/22
Safety Statements	53-45-36-26
RIDADR	UN 3077 9/PG 3
WGK Germany	3
RTECS	DU8925000
Autoignition Temperature	842 °F
TSCA	TSCA listed
HazardClass	6.1(a)
PackingGroup	I
HS Code	29214990
Storage Class	6.1C - Combustible acute toxic Cat.3 toxic compounds or compounds which causing chronic effects
Hazard Classifications	Acute Tox. 4 Oral Carc. 1A
Hazardous Substances Data	92-67-1(Hazardous Substances Data)
Toxicity	Acute oral LD₅₀ for rats 200 mg/kg, mice 50 mg/kg (quoted, Verschueren, 1983).

MSDS Information

Provider	Language
SigmaAldrich	English

4-Aminobiphenyl Usage And Synthesis

Description	4-Aminobiphenyl is an aromatic amine (arylamine) that exists at room temperature as a colorless crystalline solid with a floral odor. It is slightly soluble in cold water, but readily soluble in hot water. It is soluble in ethanol, ether, acetone, chloroform, and lipids. It oxidizes in air and emits toxic fumes when heated to decomposition (Akron 2009).
Chemical Properties	Colorless or slightly purple-yellow crystal. Melting point 52.9-53.6 ℃, boiling point 302 ℃, 191 ℃ (2.0kPa), 166 ℃ (0.67kPa), can be volatile with water vapor. Soluble in hot water, soluble in ethanol, ether chloroform and methanol, slightly soluble in cold water.
Physical properties	Colorless to yellow-brown crystalline solid with a floral-like odor. Becomes purple on exposure to air.
Uses	In the United States, 4-aminobiphenyl now is used only in laboratory research. It formerly was used commercially as a rubber antioxidant, as a dye intermediate, and in the detection of sulfates (HSDB 2009).
Uses	In the detection of sulfates. Formerly as rubber antioxidant. As carcinogen in cancer research, induces chromosomal instability in human cancer cells.
Uses	Previously used as a rubber antioxidant; no longer produced on a commercial scale
Definition	ChEBI: 4-Aminobiphenyl is an aminobiphenyl that is biphenyl substituted by an amino group at position 4. It has a role as a carcinogenic agent. It derives from a hydride of a biphenyl.
Synthesis Reference(s)	Journal of the American Chemical Society, 97, p. 7184, 1975 DOI: 10.1021/ja00857a049 Tetrahedron Letters, 39, p. 1313, 1998 DOI: 10.1016/S0040-4039(97)10877-2
General Description	Colorless to yellowish-brown crystals or light brown solid.
Air & Water Reactions	Is oxidized by air (darkens on oxidation). Insoluble in water.
Reactivity Profile	4-AMINOBIPHENYL is a weak base. Incompatible with acids and acid anhydrides. Forms salts with hydrochloric acid and sulfuric acid. Can be diazotized, acetylated and alkylated. . May react with strong oxidizing agents.
Hazard	Toxic by ingestion, inhalation, skin absorp- tion. Confirmed carcinogen. Bladder and liver can- cer.
Health Hazard	4-Aminodiphenyl exposure is associated with a high incidence of bladder cancer in humans.
Fire Hazard	4-AMINOBIPHENYL is probably combustible.
Safety Profile	Confirmed human carcinogen with experimental carcinogenic and tumorigenic data. Poison by ingestion and intraperitoneal routes. Human mutation data reported. An irritant. Effects resemble those of benzidine. See also BENZIDINE. Slight to moderate fire hazard when exposed to heat, flames (sparks), or powerful oxidzers. To fight fire, use water spray, mist, dry chemical. When heated to decomposition it emits toxic fumes of NOx,. See also AROMATIC AMINES.
Synthesis	4-aminobiphenyl is prepared by reduction of 4-nitrobiphenyl, which, together with the 2-nitro derivatives, is obtained by nitration of biphenyl.
Potential Exposure	4-Aminobiphenyl is no longer manufactured commercially and is only used for research purposes. 4-Aminobiphenyl was formerly used as a rubber antioxidant and as a dye intermediate. Is a contaminant in 2-aminobiphenyl.
Carcinogenicity	4-Aminobiphenyl is known to be a human carcinogen based on sufficient evidence of carcinogenicity from studies in humans. Cancer of the urinary bladder was first reported to be associated with occupational exposure to 4-aminobiphenyl in a descriptive epidemiological study (published in the mid 1950s), in which 11% (19 of 171) of workers in a plant manufacturing 4-aminobiphenyl developed urinary-bladder cancer. These workers had been exposed to 4-aminobiphenyl for 1.5 to 19 years between 1935 and 1955. Publication of this study led to an effort to discontinue production and useof 4-aminobiphenyl. Starting in 1955, 541 workers who had been exposed to 4-aminobiphenyl were followed for an additional 14 years; 43 men (7.9%) developed histologically confirmed urinary-bladder cancer. In a survey of workers at a plant producing a variety of chemicals, the risk of mortality from urinary-bladder cancer was elevated tenfold, and all of the men who died of urinary-bladder cancer had worked at the plant during the period when 4-aminobiphenyl was used (1941 through 1952). The International Agency for Research onCancer concluded that there was sufficient evidence of the carcinogenicity of 4-aminobiphenyl in humans (IARC 1972, 1987). Since 4-aminobiphenyl was listed in the First Annual Report on Carcinogens, most research on its carcinogenicity has focused on exposure from cigarette smoking. Epidemiological studies have reported the incidence of urinary-bladder cancer to be 2 to 10 times as high among cigarette smokers as among nonsmokers. Higher levels of 4-aminobiphenyl adducts (4-aminobiphenyl metabolites bound to DNA or protein) were detected in bladder tumors (DNA adducts) and red blood cells (hemoglobin adducts) from smokers thanfrom nonsmokers (Feng et al. 2002). In a case-control study, levels of 4-aminobiphenyl–hemoglobin adducts were higher in smokers with urinary-bladder cancer than in a control group of similarly exposed smokers (Del Santo et al. 1991). A Taiwanese study reported that 4-aminobiphenyl–hemoglobin adducts were associated with increased risk of liver cancer (Wang et al. 1998).
Environmental Fate	4-Aminobiphenyl is one of a number of chemicals that cause methemoglobinemia, or conversion of hemoglobin to methemoglobin, which reduces the ability of the blood to carry oxygen to the tissues. In addition, the active metabolite is believed to produce cancer through its reaction with cellular DNA. In animal studies, the observed incidence of 4-aminobiphenyl adducts with bladder epithelium DNA correlated well with the observed bladder tumor incidence.
Metabolic pathway	Ring oxidation of 4-aminobiphenyl occurred only to a minor extent in microsomes. In contrast, N-oxidation of 4,4'-methylene-bis-(2-chloroaniline) is preferentially catalyzed by the phenobarbital-induced enzymes P- 450PB-B and P-450PB-D to cause ring oxidation and methylene carbon oxidation. 4,4'-Methylene-bis-(2- chloroaniline) ring oxidation and methylene carbon oxidation show varied cytochrome P-450 selectivity and accounted for 14-79% of total oxidation products.
Shipping	UN2811 Toxic solids, organic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required. UN3143 Dyes, solid, toxic, n.o.s. or Dye intermediates, solid, toxic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required
Purification Methods	Crystallise it from water or EtOH. [Beilstein 12 IV 3241.] CARCINOGENIC.
Toxicity evaluation	4-Aminobiphenyl may have been released into the environment during its production and use as a rubber antioxidant and dye intermediate; however, sources suggest that it was no longer in significant production by the early 1970s. 4-Aminobiphenyl is easily oxidizable and probably undergoes photolysis but there is little actual data on these processes. If released on land it is expected to adsorb moderately to soil, probably binding to humic materials, and undergo redox reactions. If released to surface water, it is expected to adsorb to sediment, and probably undergo photolysis and oxidation. It may be degraded by oxidation by alkoxy radicals, which are photochemically produced in eutrophic waters, with an estimated half-life of 14 days. 4-Aminobiphenyl is biodegradable and biodegradation may well occur in both soil and water but there are no rates available for soil or surface waters. It has a low potential for bioconcentration. In the atmosphere, degradation should occur due to direct photolysis, oxidation by ambient oxygen, and photochemically produced hydroxyl radicals (estimated half-life 6–7 h in the vapor phase).
Incompatibilities	Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides and acid anhydrides.
Waste Disposal	Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant (≥100 kg/mo) must conform with EPA regulations governing storage, transportation, treatment, and waste disposal. Controlled incineration whereby oxides of nitrogen are removed from the effluent gas by scrubber, catalytic or thermal devices.

4-Aminobiphenyl Preparation Products And Raw materials

Raw materials	Potassium carbonate-->Sodium hypochlorite-->Triphenylphosphine-->Biphenyl-->Palladium (II) Acetate-->Diphenylphosphoryl azide-->4-Bromoaniline-->4-Biphenylcarboxylic acid-->Phenylboronic acid-->4-Nitrobiphenyl
Preparation Products	Acid Orange 67-->4-Iodobiphenyl-->4-methoxy-2-phenylaniline-->N-(4-biphenyl)-(9,9-dimethylfluoren-2--yl)Amine-->[1,1':2',1''-Terphenyl]-4'-amine-->[1,1'-Biphenyl]sulfonic acid, 4,4''-[(9,10-dihydro-9,10-dioxo-1,4-anthracenediyl)diimino]bis-, disodium salt

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ECHEMI Editorial Reference

4-Aminobiphenyl is a combustible, colorless to tan crystalline solid that turns purple on exposure to air. May be used in a liquid solution. Floral odor.

Research & Reference Note

4-Aminobipheny | Pharmaceutical Grade | 99.99% Purity | 10mg 20mg 30mg Vials | Lyophilized Powder | CAS 92-67-1 is listed on ECHEMI for industrial / laboratory sourcing. This listing is for industrial and laboratory research use. Product information on ECHEMI is provided for sourcing and specification reference. It is not medical advice, a clinical recommendation, or an approved therapy description. Always verify regulatory status, purity, and intended use with the supplier and applicable authorities before purchase or use.

Authoritative sources

Disclaimer: This listing is for industrial and laboratory research use. Product information on ECHEMI is provided for sourcing and specification reference. It is not medical advice, a clinical recommendation, or an approved therapy description. Always verify regulatory status, purity, and intended use with the supplier and applicable authorities before purchase or use.

Reviewed by ECHEMI Scientific Review - Platform editorial review for research chemicals

Certificates

Basic Info

Product Name:

4-Aminobiphenyl

Other Name:

[1,1′-Biphenyl]-4-amine;4-Biphenylamine;p-Aminobiphenyl;4-Aminobiphenyl;p-Aminodiphenyl;4-Aminodiphenyl;p-Phenylaniline;Xenylamine;p-Biphenylamine;p-Xenylamine;4-Biphenylylamine;4-Phenylaniline;4-Phenylbenzenamine;(1,1′-Biphenyl-4-yl)amine;NSC 7660;4-Amino-1,1′-biphenyl;p-Aminophenyl benzene

CAS No.:

92-67-1

Molecular Formula:

C12H11N

InChIKeys:

InChIKey=DMVOXQPQNTYEKQ-UHFFFAOYSA-N

Molecular Weight:

169.22

Exact Mass:

169.22

EC Number:

202-177-1

HScode:

29214990

Categories:

Blood Glucose Regulators

Characteristics

PSA:

XLogP3:

2.9

Appearance:

4-aminobiphenyl appears as colorless to yellowish-brown crystals or light brown solid. (NTP, 1992)

Density:

1.16 g/cm³

Melting Point:

53.5 °C

Boiling Point:

302 °C

Flash Point:

>110°C

Refractive Index:

1.619

Water Solubility:

soluble in Dichloromethane, DMSO and Methanol

Storage Conditions:

-20°C Freezer

Vapor Pressure:

Vapour pressure, Pa at 25°C: 0.077

Vapor Density:

Relative vapour density (air = 1): 5.8

Toxicity:

Oral-rat LD50: 500 mg/kg; Oral-Mouse LD50: 205 mg/kg

Flammability characteristics:

Open flame, near heat, Mars and flammable in case of strong oxidants; emit toxic nitrogen oxide gas when heated

Odor:

Floral odor

See More 4-Aminobiphenyl Properties 

Hazard Identification

Classification of the substance or mixture

Acute toxicity - Category 4, Oral

Carcinogenicity, Category 1A

GHS label elements, including precautionary statements

Precautionary statement(s)
Pictogram(s)
Signal word	Danger
Hazard statement(s)	H302 Harmful if swallowed H350 May cause cancer
Prevention	P264 Wash ... thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P203 Obtain, read and follow all safety instructions before use. P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/...
Response	P301+P317 IF SWALLOWED: Get medical help. P330 Rinse mouth. P318 IF exposed or concerned, get medical advice.
Storage	P405 Store locked up.
Disposal	P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.

Other hazards which do not result in classification

no data available

Handling and Storage

Precautions for safe handling

NO open flames. Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.

Conditions for safe storage, including any incompatibilities

Separated from strong oxidants and acids. Well closed.Keep container tightly closed in a dry and well-ventilated place.

See More 4-Aminobiphenyl Safety Data Sheet 

Seller Information

Business Type:
Trader

Main Products:
pharmaceutical intermediates,peptides,electronic chemicals

Location:
Room 102, 1st Floor, East Office Building, No. 45 Pengwan Road, Qianwan Bonded Port Area, Qingdao Zone, China (Shandong) Pilot Free Trade Zone

Payment Terms:
100% TT in advance

Average lead Time:
10 days

Total Annual Revenue:
$10 million-$25 million

Total Employees:
51-100

Year of Establishment:
2024

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4-Aminobipheny | Pharmaceutical Grade | 99.99% Purity | 10mg 20mg 30mg Vials | Lyophilized Powder | CAS 92-67-1

Product Description

Seller Information

Classification of the substance or mixture

GHS label elements, including precautionary statements

Other hazards which do not result in classification

Precautions for safe handling

Conditions for safe storage, including any incompatibilities

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