3-AMINO-6-METHOXY-2-PICOLINE
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3-AMINO-6-METHOXY-2-PICOLINE
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CAS No:
52090-56-9
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Formula:
C7H10N2O
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Chemical Name:
3-AMINO-6-METHOXY-2-PICOLINE
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Synonyms:
3-AMINO-6-METHOXY-2-PICOLINE;5-AMINO-2-METHOXY-6-PICOLINE;6-Methoxy-2-methyl-3-pyridylamine;2-Methoxy-5-amino-6-methylpyridine;2-Methyl-6-methoxypyridin-3-amine;6-Methoxy-2-methyl-3-pyridinamine;6-Methoxy-2-methyl-pyridin-3-ylamine;3-Pyridinamine,6-methoxy-2-methyl
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CAS No:
Safety Information
|Warning|H302 (100%): Harmful if swallowed [Warning Acute toxicity, oral]|P261, P264, P270, P271, P280, P301+P312, P302+P352, P304+P340, P305+P351+P338, P312, P321, P330, P332+P313, P337+P313, P362, P403+P233, P405, and P501|The GHS information provided by 1 company from 1 notification to the ECHA C&L Inventory.
3-AMINO-6-METHOXY-2-PICOLINE Use and Manufacturing
To a solution of intermediate 74 (2 g, 0.012 mol) in H20/MEOH 1: 1 (40 mL), were added NH4CI (2.2 g, 3.5 eq. ) and Fe powder (2.3 g, 3.5 eq. ). The reaction mixture was stirred at 80°C for 16 hr. Fe was then filtered and washed with MeOH. The MeOH was evaporated, H20 was added and the aqueous solution was extracted with EtOAc (3X50 mL). The combined organic extracts were dried over anh. NA2SO4, the solids were filtered and the solvent evaporated to dryness to give the title compound (1.35 g, 81 percent) as a brown oil. NMR (APOS;H, CDCI3) : 8 6.9 (d, 1 H), 6.4 (d, 1 H), 3.8 (s, 3H), 2.33 (s, 3H).
Computed Properties
Molecular Weight:138.17
XLogP3:0.9
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:1
Exact Mass:138.079312947
Monoisotopic Mass:138.079312947
Topological Polar Surface Area:48.1
Heavy Atom Count:10
Complexity:108
Covalently-Bonded Unit Count:1
Compound Is Canonicalized:Yes
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