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Tetrahydro-2H-pyran-4-carboxaldehyde

Tetrahydro-2H-pyran-4-carboxaldehyde structure

CAS No:
50675-18-8
Formula:
C6H10O2
Chemical Name:
Tetrahydro-2H-pyran-4-carboxaldehyde
Synonyms:
2H-Pyran-4-carboxaldehyde,tetrahydro-;Pyran-4-carboxaldehyde,tetrahydro-;Tetrahydro-2H-pyran-4-carboxaldehyde;Tetrahydropyran-4-carboxaldehyde;4-Formyltetrahydropyran;4-Tetrahydropyrancarbaldehyde;Tetrahydropyranyl-4-carboxaldehyde;Oxane-4-carboxaldehyde
Categories:
Pharmaceutical Intermediates > Heterocyclic Compound

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Description

Colorless liquid

Tetrahydro-2H-pyran-4-carboxaldehyde Basic Attributes

Molecular Weight：

114.14

Exact Mass：

114.14

EC Number：

700-032-1

DSSTox ID：

DTXSID50433349

HScode：

29339900

Characteristics

PSA：

26.3

XLogP3：

Density：

1.1±0.1 g/cm3

Boiling Point：

74-77 °C @ Press: 11 Torr

Flash Point：

>23℃

Refractive Index：

1.513

Storage Conditions：

Keep Cold

Safety Information

Transport codes：

1993

hazard class code：

36-20/21/22

safety instructions：

26-36/37-24/25

Marks：

Hazard note：

Irritant/Keep Cold

Precautionary statement(s)：

P261, P264, P272, P280, P302+P352, P305+P351+P338, P321, P333+P313, P337+P313, P363, P501

Hazard Statements：

H317

GHS Classification：

|Warning|H317 (97.78%): May cause an allergic skin reaction [Warning Sensitization, Skin]|P261, P264, P272, P280, P302+P352, P305+P351+P338, P321, P333+P313, P337+P313, P363, and P501|Aggregated GHS information provided by 91 companies from 5 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Tetrahydro-2H-pyran-4-carboxaldehyde Use and Manufacturing

To 5.00 g (43.0 mmol) of (tetrahydro-pyran-yl)-methanol in DCM (50 mL) are added 67 mg of 2, 2, 6, 6-tetramethyl-1-piperidinyloxy (0.43 mmol), a solution of 9.04 g (108 mmol) NaHCOTo 5.00 g (43.0 mmol) of (tetrahydro-pyran-yl)-methanol in DCM (50 mL) are added 67 mg of 2, 2, 6, 6-tetramethyl-1 -piperidinyloxy (0.43 mmol), a solution of 9.04 g (108 mmol) NaHC0Reference Tetrahydropyran-4-carbaldehyde. To a solution of tetrahydro pyran-4-carbonitrile (1.0 g, 9.0 mmol) in toluene (10 mL) was added diisobutylaluminium hydride solution (DIBAL-H, 10.8 mL, 10.8 mrnol, 10 IM in toluene) at -78°C. The reaction was stirred at -78

Computed Properties

Molecular Weight:114.14
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:1
Exact Mass:114.068079557
Monoisotopic Mass:114.068079557
Topological Polar Surface Area:26.3
Heavy Atom Count:8
Complexity:74.6
Covalently-Bonded Unit Count:1
Compound Is Canonicalized:Yes

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CAS No.: 50675-18-8

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Guide of Tetrahydro-2H-pyran-4-carboxaldehyde

Description
Basic Attributes
Characteristics
Safety Information
Use and Manufacturing
Computed Properties
Recommended Suppliers
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Tetrahydro-2H-pyran-4-carboxaldehyde

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