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Home > Encyclopedia > Di-μ-chlorotetrakis[(1,2-η)-cyclooctene]dirhodium

Di-μ-chlorotetrakis[(1,2-η)-cyclooctene]dirhodium

Di-μ-chlorotetrakis[(1,2-η)-cyclooctene]dirhodium structure

Di-μ-chlorotetrakis[(1,2-η)-cyclooctene]dirhodium 

structure
  • CAS No:

    12279-09-3

  • Formula:

    C32H56Cl2Rh2

  • Chemical Name:

    Di-μ-chlorotetrakis[(1,2-η)-cyclooctene]dirhodium

  • Synonyms:

    Rhodium,di-μ-chlorotetrakis[(1,2-η)-cyclooctene]di-;Rhodium,di-μ-chlorotetrakis(cyclooctene)di-;Cyclooctene,rhodium complex;Di-μ-chlorotetrakis[(1,2-η)-cyclooctene]dirhodium;Di-μ-Chlorotetrakis(cyclooctene)dirhodium;Chlorobis(cyclooctene)rhodium(I) dimer;Chlorobis(cyclooctene)rhodium dimer;Bis(chlorobis(cyclooctene)rhodium);Bis((μ-chloro)bis(cyclooctene)rhodium);Bis(μ-chloro)tetracyclooctenedirhodium;Bis((μ-chloro)bis(η2-cyclooctene)rhodium);Di-μ-chlorotetrakis(η2-cyclooctene)dirhodium(I);[RhCl(coe)2]2;[Rh(coe)2Cl]2;12112-71-9;32799-26-1;41619-49-2

  • Categories:

    Organic Chemistry  >  Organometallic Compounds

Di-μ-chlorotetrakis[(1,2-η)-cyclooctene]dirhodium Basic Attributes

717.5

716.186890

1592732-453-0

DTXSID00693673

28439000

Characteristics

0

12.96620

orange to red crystal

140 °C (decomp)

Freezer

Safety Information

3

20/21/22-36/37/38

26-37/39

Xn

P261, P264, P270, P271, P280, P301+P312, P302+P352, P304+P312, P304+P340, P305+P351+P338, P312, P321, P322, P330, P332+P313, P337+P313, P362, P363, P403+P233, P405, P501

H302

|Warning|H302 (97.5%): Harmful if swallowed [Warning Acute toxicity, oral]|P261, P264, P270, P271, P280, P301+P312, P302+P352, P304+P312, P304+P340, P305+P351+P338, P312, P321, P322, P330, P332+P313, P337+P313, P362, P363, P403+P233, P405, and P501|Aggregated GHS information provided by 40 companies from 3 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Di-μ-chlorotetrakis[(1,2-η)-cyclooctene]dirhodium Use and Manufacturing

The precursor of rhodium (I) is used as a front-end catalyst in various reactions, including aryl and vinyl-CH bond activation, cyclization isomer polymerization and CC bond activation

Computed Properties

Molecular Weight:717.5
Hydrogen Bond Acceptor Count:2
Exact Mass:716.18690
Monoisotopic Mass:716.18690
Heavy Atom Count:36
Formal Charge:-2
Complexity:62.1
Defined Bond Stereocenter Count:4
Covalently-Bonded Unit Count:8
Compound Is Canonicalized:Yes

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