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Home > Encyclopedia > Bis(η6-benzene)di-μ-chlorodichlorodiruthenium

Bis(η6-benzene)di-μ-chlorodichlorodiruthenium

Bis(η6-benzene)di-μ-chlorodichlorodiruthenium structure

Bis(η6-benzene)di-μ-chlorodichlorodiruthenium 

structure
  • CAS No:

    37366-09-9

  • Formula:

    C12H12Cl4Ru2

  • Chemical Name:

    Bis(η6-benzene)di-μ-chlorodichlorodiruthenium

  • Synonyms:

    Ruthenium,bis(η6-benzene)di-μ-chlorodichlorodi-;Benzene,ruthenium complex;Bis(η6-benzene)di-μ-chlorodichlorodiruthenium;(Benzene)dichlororuthenium dimer;Benzeneruthenium dichloride dimer;Bis(π-benzeneruthenium dichloride);Dibenzenetetrachlorodiruthenium;Bis[dichloro[η6-(benzene)]ruthenium];Bis(benzene)tetrachlorodiruthenium;Bis(η6-benzene)tetrachlorodiruthenium;Bis((η6-benzene)dichlororuthenium);Bis((η6-benzene)chloro(μ-chloro)ruthenium);Benzeneruthenium(II) chloride dimer;Bis(benzene)di-μ-chlorodichlorodiruthenium;μ-Dichloro-bis(benzenechlororuthenium(II));Bis[(benzene)dichlororuthenium];59391-40-1;265323-98-6

  • Categories:

    Organic Chemistry  >  Organometallic Compounds

Description

Orange crystal powder

Bis(η6-benzene)di-μ-chlorodichlorodiruthenium Basic Attributes

500.18

499.778076

DTXSID40449898

28439000

Characteristics

0

orange Powder

250℃

Safety Information

NONH for all modes of transport

3

36/37/38

26-37/39

Xi

P261-P305 + P351 + P338

H315-H319-H335

|Warning|H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]|P261, P264, P271, P280, P302+P352, P304+P340, P305+P351+P338, P312, P321, P332+P313, P337+P313, P362, P403+P233, P405, and P501|Aggregated GHS information provided by 41 companies from 4 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Bis(η6-benzene)di-μ-chlorodichlorodiruthenium Use and Manufacturing

Methods of Manufacturing

Synthesis of theruthenium dimer: [Ru(ηAccording to the synthesis of the references (Inorg. Synth., (1982, 21, 74)A mixture of 2 OOg RuCl3.3H20 (9.64 mmol)And 10. 0 mL of 1, 4-cyclohexanediol (106 mmol) were dissolved in 100 mL of ethanol at a temperature of 80 to 85 ° C and heated to reflux for 12 h. After cooling, the resulting brown mixture was suction filtered to give a brown powder which was washed with a small amount of methanol and dried in vacuo to give 1.96 g of a brown solid, yield: 81percent

Uses

Catalyst for SNAr reaction of fluorinated aromatic hydrocarbon and cyclic amine; pre-catalyst for hydrogenation reaction of β-ketoester; used as precursor for preparation of other ruthenium catalysts

Computed Properties

Molecular Weight:500.2
Exact Mass:503.77613
Monoisotopic Mass:499.777992
Heavy Atom Count:18
Complexity:18.3
Covalently-Bonded Unit Count:4
Compound Is Canonicalized:Yes

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