Bis(η6-benzene)di-μ-chlorodichlorodiruthenium
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Bis(η6-benzene)di-μ-chlorodichlorodiruthenium
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CAS No:
37366-09-9
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Formula:
C12H12Cl4Ru2
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Chemical Name:
Bis(η6-benzene)di-μ-chlorodichlorodiruthenium
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Synonyms:
Ruthenium,bis(η6-benzene)di-μ-chlorodichlorodi-;Benzene,ruthenium complex;Bis(η6-benzene)di-μ-chlorodichlorodiruthenium;(Benzene)dichlororuthenium dimer;Benzeneruthenium dichloride dimer;Bis(π-benzeneruthenium dichloride);Dibenzenetetrachlorodiruthenium;Bis[dichloro[η6-(benzene)]ruthenium];Bis(benzene)tetrachlorodiruthenium;Bis(η6-benzene)tetrachlorodiruthenium;Bis((η6-benzene)dichlororuthenium);Bis((η6-benzene)chloro(μ-chloro)ruthenium);Benzeneruthenium(II) chloride dimer;Bis(benzene)di-μ-chlorodichlorodiruthenium;μ-Dichloro-bis(benzenechlororuthenium(II));Bis[(benzene)dichlororuthenium];59391-40-1;265323-98-6
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CAS No:
Bis(η6-benzene)di-μ-chlorodichlorodiruthenium Basic Attributes
500.18
499.778076
DTXSID40449898
28439000
Safety Information
NONH for all modes of transport
3
36/37/38
26-37/39
Xi
P261-P305 + P351 + P338
H315-H319-H335
|Warning|H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]|P261, P264, P271, P280, P302+P352, P304+P340, P305+P351+P338, P312, P321, P332+P313, P337+P313, P362, P403+P233, P405, and P501|Aggregated GHS information provided by 41 companies from 4 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
Bis(η6-benzene)di-μ-chlorodichlorodiruthenium Use and Manufacturing
Synthesis of theruthenium dimer: [Ru(ηAccording to the synthesis of the references (Inorg. Synth., (1982, 21, 74)A mixture of 2 OOg RuCl3.3H20 (9.64 mmol)And 10. 0 mL of 1, 4-cyclohexanediol (106 mmol) were dissolved in 100 mL of ethanol at a temperature of 80 to 85 ° C and heated to reflux for 12 h. After cooling, the resulting brown mixture was suction filtered to give a brown powder which was washed with a small amount of methanol and dried in vacuo to give 1.96 g of a brown solid, yield: 81percent
Catalyst for SNAr reaction of fluorinated aromatic hydrocarbon and cyclic amine; pre-catalyst for hydrogenation reaction of β-ketoester; used as precursor for preparation of other ruthenium catalysts
Computed Properties
Molecular Weight:500.2
Exact Mass:503.77613
Monoisotopic Mass:499.777992
Heavy Atom Count:18
Complexity:18.3
Covalently-Bonded Unit Count:4
Compound Is Canonicalized:Yes
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Bis(η6-benzene)di-μ-chlorodichlorodiruthenium
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