[1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II)
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![[1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II) structure](https://file.echemi.com/fileManage/upload/cas/24/06e6245c-b55f-47d3-81f8-abb080bdc950.gif "[1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II)")
[1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II)
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CAS No:
67292-34-6
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Formula:
C34H28Cl2FeNiP2 10*
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Chemical Name:
[1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II)
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Synonyms:
Ni(dppf)Cl2;[1,1'-Bis(diphenylphosphino)ferrocene]nickel(II) chloride, 99%;[1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(Ⅱ);[1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II),98%;Dichloro[1,1'-bis(diphenylphosphino)ferrocene]nickel(II),98% (DPPF)NiCl2;[1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II)Dichloro[1,1'-bis(diphenylphosphino)ferrocene]nickel(II);[1,1'-Bis(diphenylphosphiNA)ferrocene]dichloronickel(II);[1,1'-Bis(diphenylphosphino)fe
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CAS No:
[1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II) Basic Attributes
683.98
681.974609
29319090
[1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II) Use and Manufacturing
General procedure: A mixture of M(kappa2P, P-dppf)X2 (1.00 mmol) and EtOCS2K(0.320 g, 2.00 mmol) in 50 mL of tetrahydrofuran is stirredfor one hour at room temperature. The solution's colorlightened and a precipitate is formed. The solution is filteredand the volatiles of the filtrate are removed under vacuum.The resulting solid was recrystallized from CH2Cl2/hexaneat 4 C.General procedure: (CH3O)2PS2NH2Et2 (0.231g, 1mmol) was added to a CH2Cl2 solution (25mL) of (dppf)NiCl2 (0.342g, 0.5mmol), then the mixture was stirred at room temperature for 3h and resulted in a red solution. The solvent was removed under reduced pressure on a rotary evaporator. The residue was subjected to PTLC using CH2Cl2/THF (v/v=8:1) as eluent, and the red band was collected. Complex 1 (0.341g, 90.3%) was obtained as a red solid. Mp>250C (decomposed).General procedure: (CH3O)2PS2NH2Et2 (0.231g, 1mmol) was added to a CH2Cl2 solution (25mL) of (dppf)NiCl2 (0.342g, 0.5mmol), then the mixture was stirred at room temperature for 3h and resulted in a red solution. The solvent was removed under reduced pressure on a rotary evaporator. The residue was subjected to PTLC using CH2Cl2/THF (v/v=8:1) as eluent, and the red band was collected. Complex 1 (0.341g, 90.3%) was obtained as a red solid. Mp>250C (decomposed).
suzuki reaction
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[1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II)
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