(T-4)-Dichlorodioxochromium

154.9

153.86800

239-056-8

JQU316FZ5W

0854

1758

Deep red liquid; appears black under reflected light|Mobile, dark-red liquid|Blood red oily liquid

2914700090

2

1.14140

red liquid

1.91 g/cm³ @ Temp: 25 °C

-96.5 °C

117 °C

117°C

soluble in carbon tetrachloride, carbon disulfide, benzene, nitrobenzene, chloroform, and POCL3. Insoluble in water(Reacts).

Protect from light and moisture.

Vapour pressure, kPa at 20°C: 2.67

Relative vapour density (air = 1): 5.3

Reacts with water to form toxic hydrogen chloride and chlorine gas

Pungent odor|Musty, burning, acrid odor

Strong oxidizing agent; non-conductor of electricity|Decomposes in cold or hot water, and in alcohol|Vapor (Gas) Specific Gravity: 5.3|Ratio of Specific Heats of Vapor (Gas): 1.2832|For more Other Experimental Properties (Complete) data for CHROMYL CHLORIDE (12 total), please visit the HSDB record page.

Fumes in moist air. Hydrolyzes exothermically and vigorously on contact with water to generate chromic acid, hydrochloric acid and some chlorine [Merck, 11th ed., 1989]. Chromium oxychloride reacts with water to generate gaseous HCl. Based on a scenario where the chemical is spilled into an excess of water (at least 5 fold excess of water), half of the maximum theoretical yield of Hydrogen Chloride gas will be created in 10 minutes. Experimental details are in the following: "Development of the Table of Initial Isolation and Protective Distances for the 2008 Emergency Response Guidebook", ANL/DIS-09-2, D.F. Brown, H.M. Hartmann, W.A. Freeman, and W.D. Haney, Argonne National Laboratory, Argonne, Illinois, June 2009.

Oxidizing Agents, Strong

Strong Oxidizing Agent

CHROMIUM OXYCHLORIDE is a powerful and often violent oxidizing agent. Reacts readily with many inorganic and organic materials in the absence of a dilutent. Contact with hydrogen sulfide or phosphine can cause ignition. Contact with phosphorus tribromide, acetone, ethanol, ether, and turpentine causes ignition. Contact with moist phosphorus or with phosphorus trichloride leads to explosive reaction. Contact with ammonia causes incandescence. Reacts with sodium azide to form chromyl azide, which is explosive in the absence of a dilutent. Causes ignition of flowers of sulfur and of urea on contact. [Bretherick, 1979, p. 822-823].

12.60 eV

Noncombustible Liquid, but a powerful oxidizer.

Will cause severe corrosion of common metals.

113 Btu/lb = 62.6 cal/g = 2.62X10+5 J/kg

I

8

UN 3244 8/PG 2

3

49-46-8-35-43-50/53-34-23/24/25-45

53-45-60-61-36/37/39-27-26-17

GB5775000

O,T,C,N

The warehouse is ventilated, low temperature and dry; stored separately from alkalis and food additives

Fumes in moist air. Its solution in /carbon tetrachloride/ is fairly stable. Liquid /chromyl chloride/ is stable indefinitely in glass, aluminum, stainless steel containers if protected from light and moisture.

P201-P210-P273-P280-P303 + P361 + P353-P305 + P351 + P338

H271-H314-H317-H340-H350i-H410

Generators of waste (equal to or greater than 100 kg/mo) containing this contaminant, EPA hazardous waste number D007, must conform with USEPA regulations in storage, transportation, treatment and disposal of waste. /Chromium/|Product: Burn in a chemical incinerator equipped with an afterburner and scrubber but exert extra care in igniting as this material is highly flammable. Offer surplus and non-recyclable solutions to a licensed disposal company. Contact a licensed professional waste disposal service to dispose of this material. Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber; Contaminated packaging: Dispose of as unused product.|SRP: Wastewater from contaminant suppression, cleaning of protective clothing/equipment, or contaminated sites should be contained and evaluated for subject chemical or decomposition product concentrations. Concentrations shall be lower than applicable environmental discharge or disposal criteria. Alternatively, pretreatment and/or discharge to a permitted wastewater treatment facility is acceptable only after review by the governing authority and assurance that "pass through" violations will not occur. Due consideration shall be given to remediation worker exposure (inhalation, dermal and ingestion) as well as fate during treatment, transfer and disposal. If it is not practicable to manage the chemical in this fashion, it must be evaluated in accordance with EPA 40 CFR Part 261, specifically Subpart B, in order to determine the appropriate local, state and federal requirements for disposal.|The following wastewater treatment technology has been investigated for chromium: Concentration process: Biological Treatment. /Chromium/|For more Disposal Methods (Complete) data for CHROMYL CHLORIDE (10 total), please visit the HSDB record page.

Incompatible materials: Reacts violently with water, organic materials, alcohols|The substance is a strong oxidant and reacts violently with combustible and reducing materials. Reacts violently with water, non-metal halides, non-metal hydrides, ammonia and certain common solvents such as alcohol, ether, acetone, turpentine, causing fire and explosion hazard. Attacks many metals in presence of water. Incompatible with plastics.|Phosphorus tribromide may also ignite with chromyl chloride.|Chromyl chloride explodes with moistened phosphorus. Light is emitted at the same time.|For more Hazardous Reactivities and Incompatibilities (Complete) data for CHROMYL CHLORIDE (19 total), please visit the HSDB record page.

DHHS/ATSDR; Toxicological profile for chromium (September 2012).[DHHS/ATSDR; Toxicological profile for chromium (September 2012); Available from, as of February 8, 2016: ww.atsdr.cdc.gov/toxprofiles/tp7.pdf]

Behavior in Fire: Vapors are very irritating to eyes and mucous membranes. May increase severity of fire. (USCG, 1999)|Not combustible but enhances combustion of other substances. Many reactions may cause fire or explosion.|Corrosives, Reactive - 2nd degree

|Danger|H271: May cause fire or explosion; strong Oxidizer [Danger Oxidizing liquids; Oxidizing solids]|P201, P202, P210, P220, P221, P260, P261, P264, P272, P273, P280, P281, P283, P301+P330+P331, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P306+P360, P308+P313, P310, P321, P333+P313, P363, P370+P378, P371+P380+P375, P391, P405, and P501|H271 (100%): May cause fire or explosion; strong Oxidizer [Danger Oxidizing liquids; Oxidizing solids]|Aggregated GHS information provided by 42 companies from 2 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.|P201, P202, P210, P220, P221, P260, P261, P264, P270, P271, P272, P273, P280, P281, P283, P284, P285, P301+P310, P301+P330+P331, P302+P352, P303+P361+P353, P304+P340, P304+P341, P305+P351+P338, P306+P360, P308+P313, P310, P312, P314, P320, P321, P322, P330, P333+P313, P342+P311, P361, P363, P370+P378, P371+P380+P375, P391, P403+P233, P405, and P501|H314: Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]|P201, P202, P260, P261, P264, P270, P272, P280, P281, P285, P301+P330+P331, P302+P352, P303+P361+P353, P304+P340, P304+P341, P305+P351+P338, P307+P311, P308+P313, P310, P314, P321, P333+P313, P342+P311, P363, P405, and P501

Excerpt from ERG Guide 137 [Substances - Water-Reactive - Corrosive]: As an immediate precautionary measure, isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids. SPILL: See ERG Table 1 - Initial Isolation and Protective Action Distances on the UN/NA 1758 datasheet. FIRE: If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2016)

Excerpt from ERG Guide 137 [Substances - Water-Reactive - Corrosive]: Fully encapsulating, vapor-protective clothing should be worn for spills and leaks with no fire. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Stop leak if you can do it without risk. Use water spray to reduce vapors; do not put water directly on leak, spill area or inside container. Keep combustibles (wood, paper, oil, etc.) away from spilled material. SMALL SPILL: Cover with DRY earth, DRY sand or other non-combustible material followed with plastic sheet to minimize spreading or contact with rain. Use clean, non-sparking tools to collect material and place it into loosely covered plastic containers for later disposal. Prevent entry into waterways, sewers, basements or confined areas. (ERG, 2016)

Skin: Wear appropriate personal protective clothing to prevent skin contact. Eyes: Wear appropriate eye protection to prevent eye contact. Wash skin: The worker should immediately wash the skin when it becomes contaminated. Remove: Work clothing that becomes wet or significantly contaminated should be removed and replaced. Change: No recommendation is made specifying the need for the worker to change clothing after the work shift. Provide: Eyewash fountains should be provided in areas where there is any possibility that workers could be exposed to the substance; this is irrespective of the recommendation involving the wearing of eye protection. Facilities for quickly drenching the body should be provided within the immediate work area for emergency use where there is a possibility of exposure. [Note: It is intended that these facilities provide a sufficient quantity or flow of water to quickly remove the substance from any body areas likely to be exposed. The actual determination of what constitutes an adequate quick drench facility depends on the specific circumstances. In certain instances, a deluge shower should be readily available, whereas in others, the availability of water from a sink or hose could be considered adequate.] (NIOSH, 2016)|Eye/face protection: Tightly fitting safety goggles. Faceshield (8-inch minimum). Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).|Skin protection: Handle with gloves.|Body Protection: Complete suit protecting against chemicals. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.|Respiratory protection: Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multipurpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).|For more Personal Protective Equipment (PPE) (Complete) data for CHROMYL CHLORIDE (15 total), please visit the HSDB record page.|(See protection codes)

Not combustible but enhances combustion of other substances. Many reactions may cause fire or explosion.|Ignites or explodes on contact with nonmetal halides (e.g., disulfur dichloride, phosphorus trichloride, amd phosphorus tribromide), nonmetal hydrides (e.g., hydrogen sulfide and hydrogen phosphide), flowers of sulfur, moist phosphorus, sodium azide, and urea.

Suitable extinguishing media: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.|Advice for firefighters: Wear self-contained breathing apparatus for firefighting if necessary.|Use water spray to cool unopened containers.|Carbon dioxide. Special powder. NO hydrous agents. In case of fire in the surroundings: use no water unless protected against toxic gases.|For more Fire Fighting Procedures (Complete) data for CHROMYL CHLORIDE (9 total), please visit the HSDB record page.

May increase the fire hazard on mixture with organic matter.|Chromium chloride does not burn, but it will increase the intensity of a fire since it is an oxidizer.|Vapors may travel to a source of ignition and flash back.|Containers may explode in fire especially if water gets in them. From a secure, explosion-proof location, use water spray to cool exposed containers. If cooling streams are ineffective (ventilating sound increases in volume and pitch, tank discolors, or shows any signs of deforming), withdraw immediately to a secure position.

ACCIDENTAL RELEASE MEASURES: Personal precautions, protective equipment and emergency procedures: Use personal protective equipment. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas; Environmental precautions: Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided; Methods and materials for containment and cleaning up: Contain spillage, and then collect with an electrically protected vacuum cleaner or by wet-brushing and place in container for disposal according to local regulations.|Evacuate danger area! Ventilation. Collect leaking liquid in sealable containers. Absorb remaining liquid in sand or inert absorbent and remove to safe place. Do NOT wash away into sewer. Do NOT absorb in saw-dust or other combustible absorbents. NEVER direct water jet on liquid. (Extra personal protection: chemical protection suit including self-contained breathing apparatus.)|Isolate the area until the release is under full control. Use water spray to cool and disperse vapors and protect personnel.|Evacuate and restrict persons not wearing protective equipment from area of spill or leak until cleanup is complete. Remove all ignition sources. Ventilate area of spill or leak. Absorb liquids in vermiculite, dry sand, earth, peat, carbon, or similar material and deposit in sealed containers. Keep this chemical out of confined spaces, such as a sewer, because of the potential for an explosion, unless the sewer is designed to prevent the buildup of explosive concentrations. It may be necessary to contain and dispose of this chemical as a hazardous waste. If material or contaminated runoff enters waterways, notify downstream users of potentially contaminated waters.|For more Cleanup Methods (Complete) data for CHROMYL CHLORIDE (6 total), please visit the HSDB record page.

ACCIDENTAL RELEASE MEASURES: Personal precautions, protective equipment and emergency procedures: Use personal protective equipment. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas; Environmental precautions: Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided.|Precautions for safe handling: Avoid contact with skin and eyes. Avoid inhalation of vapor or mist. Keep away from sources of ignition - No smoking.|Appropriate engineering controls: Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.|Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands.|For more Preventive Measures (Complete) data for CHROMYL CHLORIDE (12 total), please visit the HSDB record page.

If ... THERE IS NO FIRE, go directly to the Table of Initial Isolation and Protective Action Distances /(see table below)/ ... to obtain initial isolation and protective action distances. IF THERE IS A FIRE, or IF A FIRE IS INVOLVED, go directly to the appropriate guide /(see guide(s) below)/ and use the evacuation information shown under PUBLIC SAFETY.|Table of Water-Reactive Materials Which Produce Toxic Gases.|/GUIDE 137 SUBSTANCES - WATER-REACTIVE - CORROSIVE/ Fire or Explosion: EXCEPT FOR ACETIC ANHYDRIDE (UN1715), THAT IS FLAMMABLE, some of these materials may burn, but none ignite readily. May ignite combustibles (wood, paper, oil, clothing, etc.). Substance will react with water (some violently), releasing corrosive and/or toxic gases and runoff. Flammable/toxic gases may accumulate in confined areas (basement, tanks, hopper/tank cars, etc.). Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated or if contaminated with water. Substance may be transported in a molten form.|/GUIDE 137 SUBSTANCES - WATER-REACTIVE - CORROSIVE/ Health: CORROSIVE and/or TOXIC; inhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance may cause severe injury, burns or death. Fire will produce irritating, corrosive and/or toxic gases. Reaction with water may generate much heat that will increase the concentration of fumes in the air. Contact with molten substance may cause severe burns to skin and eyes. Runoff from fire control or dilution water may cause pollution.|For more DOT Emergency Guidelines (Complete) data for CHROMYL CHLORIDE (10 total), please visit the HSDB record page.

No person may /transport,/ offer or accept a hazardous material for transportation in commerce unless that person is registered in conformance ... and the hazardous material is properly classed, described, packaged, marked, labeled, and in condition for shipment as required or authorized by ... /the hazardous materials regulations (49 CFR 171-177)./|The International Air Transport Association (IATA) Dangerous Goods Regulations are published by the IATA Dangerous Goods Board pursuant to IATA Resolutions 618 and 619 and constitute a manual of industry carrier regulations to be followed by all IATA Member airlines when transporting hazardous materials. Chromium oxychloride is included on the dangerous goods list.|The International Maritime Dangerous Goods Code lays down basic principles for transporting hazardous chemicals. Detailed recommendations for individual substances and a number of recommendations for good practice are included in the classes dealing with such substances. A general index of technical names has also been compiled. This index should always be consulted when attempting to locate the appropriate procedures to be used when shipping any substance or article. Chromium oxychloride is included on the dangerous goods list.

The strong oxidizing potential of Chromium(VI) compounds explain much of their irritating and toxic properties. /Chromium (VI) compounds/|Chromic acid mist & chromate dusts may cause severe irritation of the nose, throat, bronchial tubes, and lung. /Chromic acid mist & chromate dusts/

Permissible Exposure Limit: Table Z-1 8-hr Time Weighted Avg: 1 mg/cu m. /Chromium metal and insoluble salts, as Cr/|Permissible Exposure Limit: Table Z-1 8-hr Time Weighted Avg: 0.5 mg/cu m. /Chromium(II) compounds, as Cr/|Permissible Exposure Limit: Table Z-1 8-hr Time Weighted Avg: 0.5 mg/cu m. /Chromium(III) compounds, as Cr/|Permissible Exposure Limit: Table Z-2 Acceptable Ceiling Concentration: 1 mg/10 cu m. /Chromic acid and chromates (as CrO3)/

Recommended Exposure Limit: 8-hour Time-Weighted Average: 0.5 mg Cr/cu m. /Chromium metal, chromium(II) and chromium(III) compounds/|Recommended Exposure Limit: 8-hour Time-Weighted Average: 0.0002 mg Cr(VI)/cu m. NIOSH considers all Cr(VI) compounds (including chromic acid, tert-butyl chromate, zinc chromate, and chromyl chloride) to be potential occupational carcinogens. /All hexavalent chromium (Cr(VI) compounds/|NIOSH usually recommends that occupational exposures to carcinogens be limited to the lowest feasible concentration. /Chromic acid and chromates/

Evacuate danger area! Personal protection: chemical protection suit including self-contained breathing apparatus. Ventilation. Collect leaking and spilled liquid in sealable containers as far as possible. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations. Do NOT wash away into sewer. Do NOT absorb in saw-dust or other combustible absorbents. NEVER direct water jet on liquid.

Fireproof. Separated from combustible substances, reducing agents and food and feedstuffs. Dry. Keep in the dark. Keep in a well-ventilated room.

A harmful contamination of the air can be reached very quickly on evaporation of this substance at 20 °C.

The substance is corrosive to the eyes, skin and respiratory tract. Corrosive on ingestion. Inhalation of the vapour may cause lung oedema.

Repeated or prolonged contact with skin may cause dermatitis. Repeated or prolonged contact may cause skin sensitization. This substance is probably carcinogenic to humans.

NO contact with flammables.

AVOID ALL CONTACT! IN ALL CASES CONSULT A DOCTOR!

Use ventilation, local exhaust or breathing protection.

Protective gloves. Protective clothing.

Wear face shield or eye protection in combination with breathing protection.

... Substances for which a Federal Register notice has been published that included consideration of the serious health effects, including cancer, from ambient air exposure to the substance. Chromium is included on this list. /Chromium/|Listed as a hazardous air pollutant (HAP) generally known or suspected to cause serious health problems. The Clean Air Act, as amended in 1990, directs EPA to set standards requiring major sources to sharply reduce routine emissions of toxic pollutants. EPA is required to establish and phase in specific performance based standards for all air emission sources that emit one or more of the listed pollutants. Chromium compounds is included on this list. /Chromium compounds/

D007; A waste containing chromium may or may not be characterized as a hazardous waste following testing by the Toxicity Characteristic Leaching Procedure as prescribed by the Resource Conservation and Recovery Act (RCRA) regulations. /Chromium/

D007; A solid waste containing chromium may or may not become characterized as a hazardous waste when subjected to the Toxicity Characteristic Leaching Procedure listed in 40 CFR 261.24, and if so characterized, must be managed as a hazardous waste. /Chromium/

IDENTIFICATION AND USE: Chromyl chloride (CC) is a deep red liquid, which appears black under reflected light. It is used as a catalyst for polymerization of olefins; oxidation of hydrocarbons; in Etard reaction for production of aldehydes and ketones; in the prepn of various coordination complexes of Cr. HUMAN EXPOSURE AND TOXICITY: There is no data available. ANIMAL STUDIES: CC was assayed for mutagenicity in the Ames reversion test. The liquid phase of CC elicited dose-related mutations in Salmonella typhimurium, strain TA100, although it had a limited range of activity because of its toxicity to the bacteria. The mutagenic potency and the toxic activity were of the same order of magnitude as all the water-soluble Cr6+ compounds so far tested. Toxic and mutagenic activities could also be clearly detected by using a variety of modifications of the Ames test in CC vapors which indicates the particular danger of this chromium compound. In analogy with the other Cr6+ compounds previously tested, all the effects observed were decreased in the presence of S-9 mix containing rat liver post-mitochondrial fractions.

Chromyl chloride is easily hydrolyzed(1). Chromyl chloride can react violently in water forming chromic acid, chromic chloride, hydrochloric acid and chlorine(2). It decomposes in daylight within a week via CrO2 and Cl2 to form a series of chromium oxides and chlorides with a low degree of oxidation(1).

Food chain concn potential: none

NIOSH (NOES Survey 1981-1983) has statistically estimated that 35 workers (0 of these are female) were potentially exposed to chromyl chloride in the US(1).

Inhalation causes severe irritation of upper respiratory system. Contact with eyes or skin causes irritation and burning. Ingestion causes burning of mouth and stomach. (USCG, 1999)

Eye: If this chemical contacts the eyes, immediately wash the eyes with large amounts of water, occasionally lifting the lower and upper lids. Get medical attention immediately. Contact lenses should not be worn when working with this chemical. Skin: If this chemical contacts the skin, immediately flush the contaminated skin with water. If this chemical penetrates the clothing, immediately remove the clothing and flush the skin with water. Get medical attention promptly. Breathing: If a person breathes large amounts of this chemical, move the exposed person to fresh air at once. If breathing has stopped, perform mouth-to-mouth resuscitation. Keep the affected person warm and at rest. Get medical attention as soon as possible. Swallow: If this chemical has been swallowed, get medical attention immediately. (NIOSH, 2016)|(See procedures)

Fresh air, rest. Half-upright position. Artificial respiration may be needed. Refer for medical attention.

Remove contaminated clothes. Rinse skin with plenty of water or shower. Refer for medical attention .

First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.

Immediate first aid: Ensure that adequate decontamination has been carried out. If patient is not breathing, start artificial respiration, preferably with a demand valve resuscitator, bag-valve-mask device, or pocket mask, as trained. Perform CPR as necessary. Immediately flush contaminated eyes with gently flowing water. Do not induce vomiting. If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain an open airway and prevent aspiration. Keep patient quiet and maintain normal body temperature. Obtain medical attention. /Inorganic Acids and Related Compounds/|Basic treatment: Establish a patent airway (oropharyngeal or nasopharyngeal airway, if needed). Suction if necessary. Watch for signs of respiratory insufficiency and assist respirations if needed. Administer oxygen by nonrebreather mask at 10 to 15 L/min. Monitor for pulmonary edema and treat if necessary ... . Monitor for shock and treat if necessary ... . For eye contamination, flush eyes immediately with water. Irrigate each eye continuously with 0.9% saline (NS) during transport ... . Do not use emetics. Activated charcoal is not effective. For ingestion, rinse mouth and administer 5 mL/kg up to 200 mL of water for dilution if the patient can swallow, has a strong gag reflex, and does not drool ... . Do not attempt to neutralize, because of exothermic reaction. Cover skin burns with dry, sterline dressings after decontamination ... . /Ammonia and Related Compounds/|Advanced treatment: Consider orotracheal or nasotracheal intubation for airway control in the patient who is unconscious, has severe pulmonary edema, or is in severe respiratory distress. Early intubation, at the first sign of upper airway obstruction, may be necessary. Positive-pressure ventilation techniques with a bag-valve-mask device may be beneficial. Consider drug therapy for pulmonary edema ... . Consider administering a beta agonist such as albuterol for severe bronchospasm ... . Monitor cardiac rhythm and treat arrhythmias as necessary ... . Start IV administration of D5W TKO. Use 0.9% saline (NS) or lactated Ringer's (LR) if signs of hypovolemia are present. For hypotension with signs of hypovolemia, administer fluid cautiously. Consider vasopressors if patient is hypotensive with a normal fluid colume. Watch for signs of fluid overload ... . Use proparacaine hydrochloride to assist eye irrigation ... . /Inorganic Acids and Related Compounds/

The substance can be absorbed into the body by inhalation of its aerosol or vapour and by ingestion.|inhalation, skin absorption, ingestion, skin and/or eye contact

irritation eyes, skin, upper respiratory system; eye, skin burns [potential occupational carcinogen]

Cough. Laboured breathing. Shortness of breath. Sore throat.

Redness. Skin burns. Pain. Blisters.

Redness. Pain. Severe deep burns.

Eyes, skin, respiratory system

Chromium, dichlorodioxo-, (T-4)-: ACTIVE|Wet ashing techniques for chromium analysis involving evaporation to dryness may result in chromyl chloride formation.

Fire Hazards -> Corrosives, Reactive - 2nd degree