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Tris(4-aminophenyl)methanol

Tris(4-aminophenyl)methanol structure

Tris(4-aminophenyl)methanol 

structure
  • CAS No:

    467-62-9

  • Formula:

    C19H19N3O

  • Chemical Name:

    Tris(4-aminophenyl)methanol

  • Synonyms:

    Benzenemethanol,4-amino-α,α-bis(4-aminophenyl)-;Methanol,tris(p-aminophenyl)-;Parafuchsin carbinol;4-Amino-α,α-bis(4-aminophenyl)benzenemethanol;Tris(p-aminophenyl)methanol;Tris(4-aminophenyl)methanol

  • Categories:

    Biochemical Engineering  >  Biochemical Reagents

Description

purple to dark purple crystalline powder

Tris(4-aminophenyl)methanol Basic Attributes

305.37

305.37

207-395-0

5YB58864V4

DTXSID7060049

29252900

Characteristics

98.29000

4.46100

purple Crystalline Powder

1.287 g/cm3

240-243 °C

598.9ºC at 760 mmHg

316ºC

The hydrochloride salt, basic parafuchsine and this cmpd (the free base) are readily converted in aq soln from one to another by the addition of acid or base.|dye content approx 95%

Safety Information

NONH for all modes of transport

3

40

36/37

Xn

P281

H351

Dissolve or mix material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber.

ITC/USEPA; Information Review #347 (Revised Draft) Pararosaniline (1984)

Toxicity

Releases from manufacturing and processing sites are expected to occur in aqueous effluents and solid wastes. /Pararosaniline/

Worker exposure during shipping, handling and downstream use is expected to occur primarily via the dermal and inhalation routes. /Pararosaniline/|Consumers may be exposed through contact with products colored with the compound. /Pararosaniline/

Drug Information

Treatment for exposure to aniline is related to the percentage of methemoglobinemia: 30% or less, rest patient in bed, provide fruit drinks (sweetened); above 30%, provide oxygen; above 50%, IV infusion of a 5% dextrose solution (1000 cc) together with ascorbic acid; above 60% or more, provide treatment with 10-20% of a 1% methylene blue IV infusion.

Tris(4-aminophenyl)methanol Use and Manufacturing

Methods of Manufacturing

TEN TRIS(P-AMINOPHENYL)CARBONIUM SALTS, INCLUDING TRIS(P-AMINOPHENYL)METHANOL, WERE PREPARED AS WATER SOLUBLE SALTS & WATER INSOLUBLE ETHERS WHICH COULD BE USED FOR THE STERILIZATION OF BLOOD CONTAMINATED BY TRYPANOSOMA CRUZI.

Uses

Component of basic fuchsin, a dye which is used in the coloring of textiles, leather, paper products and china clay products, as a filter dye in photography, as a microbiological stain and as a dye intermediate. /Pararosaniline/|Used in the preparation of organic pigments for printing inks and for the paper printing trade, for high speed photoduplicating and photoimaging systems; in the manufacture of carbon paper; in ink for typewriter ribbons; in jet printing for high speed computer applications; in the coloration of fur, anodized aluminum, glass, waxes, polishes, soaps, plastics, drugs and cosmetics, and in specialty applications such as tinting automobile antifreeze solutions and toilet sanitary preparations /Triphenylmethane/

Production

(1977) 1 to 10 million lb /free base and hydrochloride salt/

Benzenemethanol, 4-amino-.alpha.,.alpha.-bis(4-aminophenyl)-: ACTIVE|The literature is frequently ambiguous when referring to pararosaniline; sometimes the term signifies the free base, tris(p-aminophenol) methanol (CAS # 467-62-9) but more often it signifies the hydrochloride salt form of the compound (CAS # 569-61-9)

Computed Properties

Molecular Weight:305.4
XLogP3:2.2
Hydrogen Bond Donor Count:4
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:3
Exact Mass:305.152812238
Monoisotopic Mass:305.152812238
Topological Polar Surface Area:98.3
Heavy Atom Count:23
Complexity:310
Covalently-Bonded Unit Count:1
Compound Is Canonicalized:Yes

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