2-(1-Methylethyl)furan

General procedure: Cross coupling reactions of Grignard reagents with other hete-rocyclics such as furan and dioxane were performed according tothe following general method.An aliquot of Catalyst 1 (0.5 mg, 0.87 mol) in diethyl ether wasadded using a gas-tight syringe to a 5 mL round bottom flask purgedwith argon. To this solution, phenylmagnesium chloride in ether(0.92 mmol) followed by dibromoethane (90 L, 1.04 mol) wereadded and allowed to stir at room temperature. Samples for anal-ysis were collected at the appointed time intervals over a period of60 min. Excess Grignard reagent was destroyed using methanol andthe reaction products were quantitated by GC-MS using an internalstandard 2-methyltetrahydrofuran. Product yields were reportedin turnover number (TON: moles of product formed per mole of cat-alyst used) and turnover frequency (TOF: moles of product formedper mole of catalyst in unit time). For large scale synthesis, thecompound was worked up and isolated as mentioned above.

Molecular Weight:110.15
XLogP3:2.1
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:1
Exact Mass:110.073164938
Monoisotopic Mass:110.073164938
Topological Polar Surface Area:13.1
Heavy Atom Count:8
Complexity:68.8
Covalently-Bonded Unit Count:1
Compound Is Canonicalized:Yes