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Home > Encyclopedia > Aluminum stearate

Aluminum stearate

pharmaceutical raw materials
Aluminum stearate structure

Aluminum stearate 

structure
  • CAS No:

    637-12-7

  • Formula:

    C18H36O2.1/3Al

  • Chemical Name:

    Aluminum stearate

  • Synonyms:

    Octadecanoic acid,aluminum salt (3:1);Aluminum stearate;Stearic acid,aluminum salt;Octadecanoic acid,aluminum salt;Metasap XX;Tribasic aluminum stearate;Rofob 3;Aluminum stearate (1:3);Alugel 34TN;Aluminium stearate;SA 1500;Aluminum tristearate;Aluminum(III) stearate;SA 1000;Alugel 44M;Thompson's Water Seal;Alugel 30DF;SA 2000;SA 100;SA 100 (stearate);Daiwax WA 1;Arusute 30;Liga TR;Aluminum Stearate 900;Alugel 34TH;SA 1500 (stearate);AL 103;Aluminum Tristearate 900;M 132HG;65324-35-8

  • Categories:

    Cosmetic Ingredient  >  Emulsion Stabilising

Description

solid


DryPowder


Aluminium tristearate is an aluminium salt. It contains an octadecanoate.|Aluminum Stearate is the aluminum salt of the fatty acid, stearic acid.

Aluminum stearate Basic Attributes

877.38900

876.77300

211-279-5

U6XF9NP8HM

DTXSID0027278

C61631

White powder|Hard material

2915709000

Characteristics

78.90000

18.76620

White Powder

1.070 g/cm3

118 °C

359.4ºC at 760 mmHg

162.4ºC

Insoluble in alcohol, ether; soluble in alkali

Keep in a cool, dry, dark location in a tightly sealed container or cylinder. Keep away from incompatible materials, ignition so

Violently explosive when they come into contact with water. /Aluminum alkyls/

Forms gel with aliphatic and aromatic hydrocarbons.|Hard material, passes into plastic form on heating

Safety Information

3

R36/37/38

S22-S24/25

BD0707000

Xi

Stable. Incompatible with strong oxidizing agents.

P261, P264, P271, P280, P302+P352, P304+P340, P305+P351+P338, P312, P321, P332+P313, P337+P313, P362, P403+P233, P405, P501

H315

Aluminum compounds are treated under anhydrous conditions to prevent violent reactions, recover solvent, and form Al compounds suitable for landfill by reaction with anhydrous hydrolysis agent, eg calcium hydroxide. /Aluminum compounds/|SRP: The most favorable course of action is to use an alternative chemical product with less inherent propensity for occupational exposure or environmental contamination. Recycle any unused portion of the material for its approved use or return it to the manufacturer or supplier. Ultimate disposal of the chemical must consider: the material's impact on air quality; potential migration in soil or water; effects on animal, aquatic, and plant life; and conformance with environmental and public health regulations.

Extremely reactive with air, moisture, and compounds containing active hydrogen... /Alkyl aluminum compounds/|Reacts violently with a broad range of materials including air & water. /Aluminum alkyls/

Substances classified as stabilizers, when migrating from food-packaging material shall incl: Aluminum tristearate.|Fatty acids derived from animal or vegetable fats and oils; and salts or such acids, single or mixed are indirect food additives for use only as a component of adhesives. /Fatty acid aluminum salts/

Cosmetic, Toiletry and Fragrance Assoc; J Am Coll Toxicol 1 (2): 143-77 (1982). A review with 89 references on the chemical and physical properties, biological and toxicological properties of lithium stearate, aluminum distearate, aluminum stearate, aluminum tristearate, ammonium stearate, calcium stearate, magnesium stearate, potassium stearate, sodium stearate, and zinc stearate.

Not Classified

Wear appropriate personal protective clothing to prevent skin contact. /Aluminum (soluble salts and alkyls, as Al/|Wear appropriate eye protection to prevent eye contact. /Aluminum (soluble salts and alkyls, as Al)/|Protective clothing and a high standard of training in the necessary precautionary measures are essential for the handling of the materials. /Aluminum alkyls/

Certain polymerization catalysts, such as aluminum alkyls, react & burn violently on contact with water. /Aluminum alkyls/|Aluminum alkyls are organic aluminum compounds that are highly reactive and dangerous because of spontaneous burning in air. /Aluminum alkyls/|Prophoric material in flammable solvent. Vapors are heavier than air & may travel to a source of ignition & flash back. /Aluminum alkyls/

...Violently explosive when they come into contact with water. /Aluminum alkyls/

Stop flow of liquid before extinguishing fire. Use dry chemical or carbon dioxide. DO NOT use water as straight stream directly on spilled material. Water fog can be used to control fire. DO NOT use halogenated extinguishing agents on spilled material. Violent reaction may result. Use water spray to keep fire-exposed containers cool. Fight fire from protected location or maximum possible distance. /Aluminum Alkyls/

SRP: The scientific literature for the use of contact lenses in industry is conflicting. The benefit or detrimental effects of wearing contact lenses depend not only upon the substance, but also on factors including the form of the substance, characteristics and duration of the exposure, the uses of other eye protection equipment, and the hygiene of the lenses. However, there may be individual substances whose irritating or corrosive properties are such that the wearing of contact lenses would be harmful to the eye. In those specific cases, contact lenses should not be worn. In any event, the usual eye protection equipment should be worn even when contact lenses are in place.|Work clothing that becomes wet or significantly contaminated should be removed and replaced. /Aluminum (soluble salts and alkyls, as Al)/|Workers whose clothing may have become contaminated should change into uncontaminated clothing before leaving the work premises. /Aluminum (soluble salts and alkyls, as Al)/|The worker should immediately wash the skin when it becomes contaminated. /Aluminum (soluble salts and alkyls, as Al)/|SRP: Contaminated protective clothing should be segregated in such a manner so that there is no direct personal contact by personnel who handle, dispose, or clean the clothing. Quality assurance to ascertain the completeness of the cleaning procedures should be implemented before the decontaminated protective clothing is returned for reuse by the workers. Contaminated clothing should not be taken home at end of shift, but should remain at employee's place of work for cleaning.

/GUIDE 135: SUBSTANCES - SPONTANEOUSLY COMBUSTIBLE/ Fire or Explosion: Flammable/combustible material. May ignite on contact with moist air or moisture. May burn rapidly with flare-burning effect. Some react vigorously or explosively on contact with water. Some may decompose explosively when heated or involved in a fire. May re-ignite after fire is extinguished. Runoff may create fire or explosion hazard. Containers may explode when heated. /Aluminum alkyls/|/GUIDE 135: SUBSTANCES - SPONTANEOUSLY COMBUSTIBLE/ Health: Fire will produce irritating, corrosive and/or toxic gases. Inhalation of decomposition products may cause severe injury or death. Contact with substance may cause severe burns to skin and eyes. Runoff from fire control may cause pollution. /Aluminum alkyls/|/GUIDE 135: SUBSTANCES - SPONTANEOUSLY COMBUSTIBLE/ Public Safety: CALL Emergency Response Telephone Number ... . As an immediate precautionary measure, isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids. Stay upwind. Keep unauthorized personnel away. Keep out of low areas. /Aluminum alkyls/|/GUIDE 135: SUBSTANCES - SPONTANEOUSLY COMBUSTIBLE/ Protective Clothing: Wear positive pressure self-contained breathing apparatus (SCBA). Wear chemical protective clothing that is specifically recommended by the manufacturer. It may provide little or no thermal protection. Structural firefighters' protective clothing will only provide limited protection. /Aluminum alkyls/|For more DOT Emergency Guidelines (Complete) data for ALUMINUM TRISTEARATE (8 total), please visit the HSDB record page.

The International Maritime Dangerous Goods Code lays down basic principles for transporting hazardous chemicals. Detailed recommendations for individual substances and a number of recommendations for good practice are included in the classes dealing with such substances. A general index of technical names has also been compiled. This index should always be consulted when attempting to locate the appropriate procedures to be used when shipping any substance or article.|The International Air Transport Association (IATA) Dangerous Goods Regulations are published by the IATA Dangerous Goods Board pursuant to IATA Resolutions 618 and 619 and constitute a manual of industry carrier regulations to be followed by all IATA Member airlines when transporting hazardous materials.|No person may /transport,/ offer or accept a hazardous material for transportation in commerce unless that person is registered in conformance ... and the hazardous material is properly classed, described, packaged, marked, labeled, and in condition for shipment as required or authorized by ... /the hazardous materials regulations (49 CFR 171-177)./

Irritation of the eyes has been noted in patients who have been exposed /to aluminum alkyls/. /Aluminum alkyls/|May cause minor irritation to lungs or eyes. /Aluminum (dust or powder)/

Recommended Exposure Limit: 10-Hr Time-Weighted Avg: 10 mg/cu m (total). /Aluminum/|Recommended Exposure Limit: 10 Hr Time-Weighted Avg: 5 mg/cu m (resp). /Aluminum/|Recommended Exposure Limit: 10 Hr Time-Weighted Avg: 2 mg/cu m. /Aluminum (soluble salts and alkyls, as Al)/|Recommended Exposure Limit: 10 Hr Time-Weighted Avg: 5 mg/cu m. /Aluminum (pyro powders and welding fumes, as Al)/

Drug Information

/CASE REPORTS/ Pulmonary aluminosis first seen in Germany between 1938 and 1945... reappeared in United Kingdom between 1952 and 1959. All cases were associated with exposure to a submicron-sized aluminum polytechnic flake which was lubricated with stearic acid, which forms aluminum stearate to retard surface oxidation during milling of such flake. This lubricant could easily be washed off. In intracellular milieu, removal of such surface oil permits exposure of oxygen to aluminum; this results in exothermic reaction and potential for tissue damage. It appears that cases occured only where this oily lubricant was used to manufacture near submicron-sized pyrotechnic flake but never where similar flake has been manufactured using polar lubricants.

aluminum monostearate

Aluminum stearate Use and Manufacturing

Methods of Manufacturing

High quality aluminum tristearate is made by reaction of aluminum isopropoxide and stearic acid in anhydrous pyridine; the product precipitates as a pyridine complex. Infrared analysis indicates that no hydroxyl remains after the pyridine is removed under vacuum.|Reaction of aluminum isopropoxide with stearic acid in anhydrous pyridine or benzene

Uses

1. This product is used as a raw material for metal rust inhibitors, waterproofing agents for construction materials, polishing agents for inks, thickeners for cosmetics, etc. Aluminum stearate is used as a smoothing agent and thickening agent in coatings and also has the effect of improving the thixotropy of the coating film. 2. Used as waterproof agent, plastic auxiliary and lubricant. 3. Used as heat stabilizer of PVC plastic and anti-settling agent of paint industry, thickening agent of lubricating oil for waterproofing agent of drier fabric, etc.


Lubricants and lubricant additives


Paints and coatings

Production

(1979) 9.26X10+8 G (MONO & TRISTEARATE MIXT)|(1981) 3.67X10+8 G (MONO & TRISTEARATE MIXT)

Grade: Technical

Paint and coating manufacturing|Octadecanoic acid, aluminum salt (3:1): ACTIVE

Cosmetics -> Emollient; Emulsion stabilizing; Opacifying; Viscosity controlling

Computed Properties

Molecular Weight:877.4
Hydrogen Bond Acceptor Count:6
Rotatable Bond Count:45
Exact Mass:876.7726545
Monoisotopic Mass:876.7726545
Topological Polar Surface Area:120
Heavy Atom Count:61
Complexity:196
Covalently-Bonded Unit Count:4
Compound Is Canonicalized:Yes

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