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Dimethyldiethoxysilane

Dimethyldiethoxysilane structure

Dimethyldiethoxysilane 

structure
  • CAS No:

    78-62-6

  • Formula:

    C6H16O2Si

  • Chemical Name:

    Dimethyldiethoxysilane

  • Synonyms:

    Silane,diethoxydimethyl-;Diethoxydimethylsilane;Dimethyldiethoxysilane;Dimethylsilicondiethoxide;KBE 22;SZ 6078;LS 1370;TSL 8122;NSC 77085;DP 322;CG-N 222;202756-41-0

  • Categories:

    Chemical Reagents  >  Organic Reagents

Description

Colorless clear liquid


Dimethyldiethoxysilane appears as a colorless liquid. Less dense than water and insoluble in water. Vapors heavier than air.|Liquid


Dimethyldiethoxysilane appears as a colorless liquid. Less dense than water and insoluble in water. Vapors heavier than air.

Dimethyldiethoxysilane Basic Attributes

148.28

148.28

1736110

201-127-6

I3931J3ZJ2

77085

2380

DTXSID6052538

29319090

Characteristics

18.5

0.61

≤25(APHA)

0.839 g/cm3

-87 °C

114 °C

53 °F

1.393

H2O: may decompose

Flammables area

20.00 mmHg

Oral-rat LD50: 9280 mg/kg; inhalation-rat LD50: 20 g/m3/8 hours

Inflammable in case of open flame, high temperature, oxidant; burning produces irritating smoke

Highly flammable. Insoluble in water.

Siloxanes

Highly Flammable

These substances undergo chemical reactions only under relatively severe circumstances or in the presence of an effective catalyst that promotes reaction. They are resistant to ignition, although they may become flammable at very high temperatures. They will be resistant to oxidation/reduction, except in the most severe conditions. These materials may be nontoxic.

Safety Information

II

3

UN 1993 3/PG 2

2

11-36/38-20

26-36-16

VV3590000

F,Xi,Xn

The warehouse is ventilated, low temperature and dry; stored separately from oxidants and acids

P210-P305 + P351 + P338

H225-H315-H319-H332

Excerpt from ERG Guide 127 [Flammable Liquids (Water-Miscible)]: HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Those substances designated with a (P) may polymerize explosively when heated or involved in a fire. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water. (ERG, 2016)|Flammable - 3rd degree

|Danger|H225 (100%): Highly Flammable liquid and vapor [Danger Flammable liquids]|P210, P233, P240, P241, P242, P243, P261, P264, P271, P280, P302+P352, P303+P361+P353, P304+P312, P304+P340, P305+P351+P338, P312, P321, P332+P313, P337+P313, P362, P370+P378, P403+P233, P403+P235, P405, and P501|Aggregated GHS information provided by 241 companies from 9 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.|H225: Highly Flammable liquid and vapor [Danger Flammable liquids]|P210, P233, P240, P241, P242, P243, P280, P303+P361+P353, P370+P378, P403+P235, and P501

Excerpt from ERG Guide 127 [Flammable Liquids (Water-Miscible)]: CAUTION: All these products have a very low flash point: Use of water spray when fighting fire may be inefficient. CAUTION: For fire involving UN1170, UN1987 or UN3475, alcohol-resistant foam should be used. SMALL FIRE: Dry chemical, CO2, water spray or alcohol-resistant foam. LARGE FIRE: Water spray, fog or alcohol-resistant foam. Do not use straight streams. Move containers from fire area if you can do it without risk. FIRE INVOLVING TANKS OR CAR/TRAILER LOADS: Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. Cool containers with flooding quantities of water until well after fire is out. Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. ALWAYS stay away from tanks engulfed in fire. For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible, withdraw from area and let fire burn. (ERG, 2016)

Excerpt from ERG Guide 127 [Flammable Liquids (Water-Miscible)]: As an immediate precautionary measure, isolate spill or leak area for at least 50 meters (150 feet) in all directions. LARGE SPILL: Consider initial downwind evacuation for at least 300 meters (1000 feet). FIRE: If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2016)

Excerpt from ERG Guide 127 [Flammable Liquids (Water-Miscible)]: ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). All equipment used when handling the product must be grounded. Do not touch or walk through spilled material. Stop leak if you can do it without risk. Prevent entry into waterways, sewers, basements or confined areas. A vapor-suppressing foam may be used to reduce vapors. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. Use clean, non-sparking tools to collect absorbed material. LARGE SPILL: Dike far ahead of liquid spill for later disposal. Water spray may reduce vapor, but may not prevent ignition in closed spaces. (ERG, 2016)

Excerpt from ERG Guide 127 [Flammable Liquids (Water-Miscible)]: Wear positive pressure self-contained breathing apparatus (SCBA). Structural firefighters' protective clothing will only provide limited protection. (ERG, 2016)

Toxicity

practically nontoxic

Drug Information

Excerpt from ERG Guide 127 [Flammable Liquids (Water-Miscible)]: Inhalation or contact with material may irritate or burn skin and eyes. Fire may produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control may cause pollution. (ERG, 2016)

Excerpt from ERG Guide 127 [Flammable Liquids (Water-Miscible)]: Ensure that medical personnel are aware of the material(s) involved and take precautions to protect themselves. Move victim to fresh air. Call 911 or emergency medical service. Give artificial respiration if victim is not breathing. Administer oxygen if breathing is difficult. Remove and isolate contaminated clothing and shoes. In case of contact with substance, immediately flush skin or eyes with running water for at least 20 minutes. Wash skin with soap and water. In case of burns, immediately cool affected skin for as long as possible with cold water. Do not remove clothing if adhering to skin. Keep victim calm and warm. (ERG, 2016)

Dimethyldiethoxysilane Use and Manufacturing

Uses

Diethoxydimethylsilane may be used to modify epoxy resin6 and the surfaces of pure silica and Pd/SiO2 hydrogen gas sensors. Surface modification results in enhanced gas sensing properties of the sensors. It may be used as a precursor for the synthesis of ultrafine SiC powder. Diethoxydimethylsilane is an intermediate silane useful for blocking hydroxyl and amino groups in organic synthesis reactions. This silylating step allows subsequent reactions to be carried out which would be adversely affected by the presence of active hydrogen in the hydroxyl or amine groups. Following the reaction step, hydroxyl or amine groups blocked with diethoxydimethylsilane may be recovered by a hydrolysis procedure. It is also used for preparing hydrophobic and release materials as well as enhancing flow of powders. Studies report its use as a precursor for ORMOSIL (Organically modified SILicates) and thin a-SiOxCyHz films.


Intermediates

All other basic inorganic chemical manufacturing|Silane, diethoxydimethyl-: ACTIVE

Fire Hazards -> Flammable - 3rd degree

Computed Properties

Molecular Weight:148.28
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:4
Exact Mass:148.091956283
Monoisotopic Mass:148.091956283
Topological Polar Surface Area:18.5
Heavy Atom Count:9
Complexity:65.5
Covalently-Bonded Unit Count:1
Compound Is Canonicalized:Yes

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