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Home > Encyclopedia > Citral diethyl acetal

Citral diethyl acetal

Citral diethyl acetal structure

Citral diethyl acetal 

structure
  • CAS No:

    7492-66-2

  • Formula:

    C14H26O2

  • Chemical Name:

    Citral diethyl acetal

  • Synonyms:

    2,6-Octadiene,1,1-diethoxy-3,7-dimethyl-;2,6-Octadienal,3,7-dimethyl-,diethyl acetal;Citral diethyl acetal;1,1-Diethoxy-3,7-dimethyl-2,6-octadiene;1,1-Diethoxy-3,7-dimethylocta-2,6-diene;Citrathal R

  • Categories:

    Cosmetic Ingredient  >  Perfuming

Description

colourless liquid Citral Diethyl Acetal is a colorless liquid with a floral, warm, woody citrus odor. It is relatively stable in alkali and can, therefore, be used in soap. Citral diethyl acetal has a mild, green, citrus odor and a green, oily, citrus-peel flavor.


Citral diethyl acetal is a clear colorless liquid. (NTP, 1992)|colourless liquid with a mild, green, citrusy, herbaceous odour


Citral diethyl acetal is a clear colorless liquid. (NTP, 1992)

Citral diethyl acetal Basic Attributes

226.36

226.35

231-323-7

1993

DTXSID1024837

2911000000

Characteristics

18.5

4.83

Citral diethyl acetal is a clear colorless liquid. (NTP, 1992)

0.8730 g/cm3 @ Temp: 20 °C

117-118 °C @ Press: 10 Torr

174 °F

1.453

less than 0.1 mg/mL at 72° F (NTP, 1992)

Keep in a cool, dry, dark location in a tightly sealed container or cylinder. Keep away from incompatible materials, ignition sources and untrained individuals. Secure and label area. Protect containers/cylinders from physical damage.

19.1 mm Hg at 64.4° F ; 30.7 mm Hg at 86.0° F (NTP, 1992)

This chemical may be sensitive to prolonged exposure to moisture. Insoluble in water.

Ethers

Decomposes at Elevated Temperatures (

CITRAL DIETHYL ACETAL may be sensitive to prolonged exposure to moisture. It will decompose on heating. (NTP, 1992)

Safety Information

III

3.2

1993

2

RG5080000

Stable. Combustible. Incompatible with strong oxidizing agents. May be sensitive to moisture.

P264, P273, P280, P302+P352, P321, P332+P313, P362, P501

H315

Flash point data for this chemical are not available. It is probably combustible. (NTP, 1992)

Fires involving this material can be controlled with a dry chemical, carbon dioxide or Halon extinguisher. (NTP, 1992)

Excerpt from ERG Guide 128 [Flammable Liquids (Water-Immiscible)]: As an immediate precautionary measure, isolate spill or leak area for at least 50 meters (150 feet) in all directions. LARGE SPILL: Consider initial downwind evacuation for at least 300 meters (1000 feet). FIRE: If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2016)

SMALL SPILLS AND LEAKAGE: If you spill this chemical, FIRST REMOVE ALL SOURCES OF IGNITION. Then, use absorbent paper to pick up all liquid spill material. Your contaminated clothing and absorbent paper should be sealed in a vapor-tight plastic bag for eventual disposal. Solvent wash all contaminated surfaces with 60-70% ethanol followed by washing with a soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned. STORAGE PRECAUTIONS: You should store this chemical under refrigerated temperatures, and protect it from moisture. (NTP, 1992)

RECOMMENDED RESPIRATOR: Where the neat test chemical is weighed and diluted, wear a NIOSH-approved half face respirator equipped with an organic vapor/acid gas cartridge (specific for organic vapors, HCl, acid gas and SO2) with a dust/mist filter. (NTP, 1992)

Drug Information

Excerpt from ERG Guide 128 [Flammable Liquids (Water-Immiscible)]: Inhalation or contact with material may irritate or burn skin and eyes. Fire may produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution. (ERG, 2016)

EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop. SKIN: IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water. If symptoms such as redness or irritation develop, IMMEDIATELY call a physician and be prepared to transport the victim to a hospital for treatment. INHALATION: IMMEDIATELY leave the contaminated area; take deep breaths of fresh air. If symptoms (such as wheezing, coughing, shortness of breath, or burning in the mouth, throat, or chest) develop, call a physician and be prepared to transport the victim to a hospital. Provide proper respiratory protection to rescuers entering an unknown atmosphere. Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used; if not available, use a level of protection greater than or equal to that advised under Protective Clothing. INGESTION: DO NOT INDUCE VOMITING. If the victim is conscious and not convulsing, give 1 or 2 glasses of water to dilute the chemical and IMMEDIATELY call a hospital or poison control center. Be prepared to transport the victim to a hospital if advised by a physician. If the victim is convulsing or unconscious, do not give anything by mouth, ensure that the victim's airway is open and lay the victim on his/her side with the head lower than the body. DO NOT INDUCE VOMITING. IMMEDIATELY transport the victim to a hospital. (NTP, 1992)

Citral diethyl acetal Use and Manufacturing

Methods of Manufacturing

By the reaction of ethyl formate and citral.

Uses

GB 2760-96 stipulates the allowable food flavors. It is mainly used to prepare lemon and other citrus and assorted fruit flavors, which can produce very natural lemon and white lemon green peel fragrance.

Food additives -> Flavoring Agents

Flavoring Agents

Computed Properties

Molecular Weight:226.35
XLogP3:4.2
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:8
Exact Mass:226.193280068
Monoisotopic Mass:226.193280068
Topological Polar Surface Area:18.5
Heavy Atom Count:16
Complexity:219
Undefined Bond Stereocenter Count:1
Covalently-Bonded Unit Count:1
Compound Is Canonicalized:Yes

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