Selenium oxychloride
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Selenium oxychloride
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CAS No:
7791-23-3
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Formula:
Cl2OSe
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Chemical Name:
Selenium oxychloride
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Synonyms:
Seleninyl chloride;Selenium oxychloride;Seleninyl dichloride;Selenium oxydichloride;Selenium chloride oxide (SeCl2O);Selenium dichloride oxide;Selenium oxychloride (SeOCl2);Selenyl dichloride (SeOCl2);Dichlorooxoselenium
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CAS No:
Description
Selenium Oxychloride is a colorless to yellow, fuming liquid. Insoluble in water and denser than water. Selenium Oxychloride is toxic and extremely vesicant. When 0.01 cc is applied to the skin of rabbits,death occurs in less than 24 hours. It readily destroys skin on contact, causing third-degree burns unless immediately removed with water.
The first record of the use of selenium oxychloride in organic reactions dates back to the year 1879, when Friedrich Clausnizer1 obtained ace
Selenium oxychloride appears as a colorless to light-colored liquid. Insoluble in water and denser than water. Contact may severely irritate skin, eyes and mucous membranes. May be toxic by ingestion, inhalation and skin absorption. Used to make other chemicals.|YELLOWISH OR COLOURLESS LIQUID.
Selenium oxychloride appears as a colorless to light-colored liquid. Insoluble in water and denser than water. Contact may severely irritate skin, eyes and mucous membranes. May be toxic by ingestion, inhalation and skin absorption. Used to make other chemicals.
Selenium oxychloride Basic Attributes
165.865
165.87
232-244-0
1G57T5401W
0948
2879
Nearly colorless or yellowish liquid
28121099
Characteristics
17.07000
0.87940
Selenium oxychloride appears as a colorless to light-colored liquid. Insoluble in water and denser than water. Contact may severely irritate skin, eyes and mucous membranes. May be toxic by ingestion, inhalation and skin absorption. Used to make other chemicals.
2.44 g/cm3 @ Temp: 16 °C
8.5 °C
180 °C
176.4°C
1.651
decomposed in H2O to HCl, selenious acid; miscible with CCl4, CHCl3, CS2, benzene, toluene [MER06]
1 mm Hg at 34.8 deg C
5.7 (air = 1)
LD50 s.c. in rabbits: 7 mg/kg (Wilber)
Pungent odor
Critical volume = 235 cu cm/mol|Hydrolyzes to hydrochloric acid|Reactive with water|Solidifies at about 5 °C; decomposed by water into hydrochloric acid and selenious acid; fumes in air|Dielectric constant: 46.2 at 293.2 K
Fumes in air. Insoluble in water and denser than water. Decomposed in water or moist air to form hydrochloric acid and selenious acid [Merck 11th ed. 1989].
Acyl Halides, Sulfonyl Halides, and Chloroformates
Water-Reactive
Red phosphorus reacts in the cold with SELENIUM OXYCHLORIDE evolving light and heat; white phosphorus reacts explosively [Mellor 10:906 1946-47]. When potassium is brought into contact with selenium oxychloride in the cold, an explosion occurs [Mellor 10:908 1946-47]. May react vigorously or explosively if mixed with diisopropyl ether or other ethers in the presence of trace amounts of metal salts [J. Haz. Mat., 1981, 4, 291]. Powdered antimony ignites on contact with the chloride, [Mellor, 1947, Vol. 10, 906]. With metal oxides, i.e. silver oxide, light is evolved and heat sufficient to decompose the mixture, [Mellor, 1947, Vol. 10, 909].
Corrosive
Critical temp: 730 K; critical pressure: 7.09 MPa
Safety Information
I
8
UN 2879 8/PG 1
3
R14
S26-S36/37/39-S45-S60-S61
VS7000000
T: Toxic;N: Dangerous for the environment;
Separated from metal oxides, strong bases and food and feedstuffs. Dry. Ventilation along the floor.
Stable, but reacts with water and moisture. Incompatible with water, potassium, phosphorus.
P261-P273-P301 + P310-P311-P501
H301-H331-H373-H410
Generators of waste (equal to or greater than 100 kg/mo) containing this contaminant, EPA hazardous waste number D010, must conform with USEPA regulations in storage, transportation, treatment and disposal of waste.
Red phosphorus evolves light & heat in contact with /seleninyl/ chloride while white phosphorus explodes.|In contact with silver oxide, light is evolved and sufficient heat to decompose some of it. Similar effects were observed with lead(II) oxide, lead(IV) oxide and lead (II)(IV) oxide.|Potassium explodes violently in contact with the liguid.|When potassium is brought in contact with selenium oxychloride in the cold, a violent explosion occurs.|For more Hazardous Reactivities and Incompatibilities (Complete) data for SELENIUM OXYCHLORIDE (7 total), please visit the HSDB record page.
WHO; Environ Health Criteria: Selenium 58: 1-306 (1987). EHC are designed for scientists and administrators responsible for the establishment of safety standards and regulations and provide basic scientific risk evaluations of a wide range of chemicals and groups of chemicals.[Available from, as of April 1, 2011: http://www.inchem.org/documents/ehc/ehc/ehc58.htm#SectionNumber:7.1]
When this material is heated to decomposition, or in contact with acids or acid fumes, highly toxic chloride and selenium fumes are evolved. Hydrochloric acid and selenious acid are produced by reaction with water. Decomposed by water. Reacts violently with powdered antimony, red and white phosphorus, disilver oxide, lead oxides, and potassium. Avoid water, moist air. (EPA, 1998)|Not combustible. Gives off irritating or toxic fumes (or gases) in a fire.|Corrosives, Reactive - 2nd degree
|Danger|H301 (100%): Toxic if swallowed [Danger Acute toxicity, oral]|P260, P261, P264, P270, P271, P273, P280, P301+P310, P301+P330+P331, P303+P361+P353, P304+P340, P305+P351+P338, P310, P311, P314, P321, P330, P363, P391, P403+P233, P405, and P501|Aggregated GHS information provided by 42 companies from 2 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
Excerpt from ERG Guide 157 [Substances - Toxic and/or Corrosive (Non-Combustible / Water-Sensitive)]: As an immediate precautionary measure, isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids. SPILL: Increase, in the downwind direction, as necessary, the isolation distance shown above. FIRE: If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2016)
Excerpt from ERG Guide 157 [Substances - Toxic and/or Corrosive (Non-Combustible / Water-Sensitive)]: ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). All equipment used when handling the product must be grounded. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Stop leak if you can do it without risk. A vapor-suppressing foam may be used to reduce vapors. DO NOT GET WATER INSIDE CONTAINERS. Use water spray to reduce vapors or divert vapor cloud drift. Avoid allowing water runoff to contact spilled material. Prevent entry into waterways, sewers, basements or confined areas. SMALL SPILL: Cover with DRY earth, DRY sand or other non-combustible material followed with plastic sheet to minimize spreading or contact with rain. Use clean, non-sparking tools to collect material and place it into loosely covered plastic containers for later disposal. (ERG, 2016)
For emergency situations, wear a positive pressure, pressure-demand, full facepiece self-contained breathing apparatus (SCBA) or pressure- demand supplied air respirator with escape SCBA and a fully-encapsulating, chemical resistant suit. (EPA, 1998)|Wear appropriate personal protective clothing to prevent skin contact. /Selenium/|Facilities for quickly drenching the body should be provided within the immediate work area for emergency use where there is a possibility of exposure. [Note: It is intended that these facilities provide a sufficient quantity or flow of water to quickly remove the substance from any body areas likely to be exposed. The actual determination of what constitutes an adequate quick drench facility depends on the specific circumstances. In certain instances, a deluge shower should be readily available, whereas in others, the availability of water from a sink or hose could be considered adequate.] /Selenium/|Respirator Recommendations: Up to 1 mg/cu m: /Selenium/ [Table#1972]|Respirator Recommendations: Emergency or planned entry into unknown concentrations or IDLH conditions: /Selenium/ [Table#1973]|Respirator Recommendations: Escape conditions: /Selenium/ [Table#1974]
If material on fire or involved in fire: Extinguish fire using agent suitable for type of surrounding fire. Material itself does not burn or burns with difficulty. Use dry chemical, dry sand, or carbon dioxide. Do not use water on material itself. If large quantities of combustibles are involved, use water in flooding quantities as spray and fog. Keep run-off water out of sewers and water sources. Use water spray to knock down vapors.|Wear appropriate chemical protective gloves, boots, and goggles. Wear positive pressure self-contained breathing apparatus when fighting fires involving this material. If contact with the material is anticipated, wear appropriate chemical protective clothing.
SRP: Wastewater from contaminant suppression, cleaning of protective clothing/equipment, or contaminated sites should be contained and evaluated for subject chemical or decomposition product concentrations. Concentrations shall be lower than applicable environmental discharge or disposal criteria. Alternatively, pretreatment and/or discharge to a permitted wastewater treatment facility is acceptable only after review by the governing authority and assurance that "pass through" violations will not occur. Due consideration shall be given to remediation worker exposure (inhalation, dermal and ingestion) as well as fate during treatment, transfer and disposal. If it is not practicable to manage the chemical in this fashion, it must be evaluated in accordance with EPA 40 CFR Part 261, specifically Subpart B, in order to determine the appropriate local, state and federal requirements for disposal.|Environmental considerations: Air spill: Apply water spray or mist to knock down vapors.|Environmental considerations: Water spill: Use natural barriers or oil spill control booms to limit spill travel. Remove trapped material with suction hoses.|Environmental considerations: Land spill: Dig a pit, pond, lagoon, holding area to contain liquid or solid material. /SRP: If time permits, pits, ponds, lagoons, soak holes, or holding areas should be sealed with an impermeable flexible membrane liner./ Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete. Absorb bulk liquid with fly ash, cement powder, or commerical sorbents. /Selenium oxychloride, poisonous liquid, N.O.S./|1. Ventilate area of spill. 2. Collect spilled material in most convenient & safe manner & deposit in sealed containers for reclamation or for disposal in a secured sanitary landfill. Liq containing selenium & its inorganic cmpd should be absorbed in vermiculite, dry sand, earth, or similar material.
If material not on fire and not involved in fire: Keep material out of water sources and sewers. Neutralize spilled material with crushed limestone, soda ash, or lime.|Personnel protection: Avoid breathing dusts, and fumes from burning material. Keep upwind. Avoid bodily contact with the material. Do not handle broken packages unless wearing appropriate personal protective equipment. Wash away any material which may have contacted the body with copious amounts of soap and water.|SRP: Contaminated protective clothing should be segregated in such a manner so that there is no direct personal contact by personnel who handle, dispose, or clean the clothing. The completeness of the cleaning procedures should be considered before the decontaminated protective clothing is returned for reuse by the workers. Contaminated clothing should not be taken home at the end of shift, but should remain at employee's place of work for cleaning.|SRP: Wastewater from contaminant suppression, cleaning of protective clothing/equipment, or contaminated sites should be contained and evaluated for subject chemical or decomposition product concentrations. Concentrations shall be lower than applicable environmental discharge or disposal criteria. Alternatively, pretreatment and/or discharge to a permitted wastewater treatment facility is acceptable only after review by the governing authority and assurance that "pass through" violations will not occur. Due consideration shall be given to remediation worker exposure (inhalation, dermal and ingestion) as well as fate during treatment, transfer and disposal. If it is not practicable to manage the chemical in this fashion, it must be evaluated in accordance with EPA 40 CFR Part 261, specifically Subpart B, in order to determine the appropriate local, state and federal requirements for disposal.|For more Preventive Measures (Complete) data for SELENIUM OXYCHLORIDE (11 total), please visit the HSDB record page.
/GUIDE 157: SUBSTANCES - TOXIC AND/OR CORROSIVE (NON-COMBUSTIBLE/WATER -SENSITIVE)/ Health: TOXIC; inhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance may cause severe injury, burns, or death. Reaction with water or moist air will release toxic, corrosive or flammable gases. Reaction with water may generate much heat which will increase the concentration of fumes in the air. Fire will produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.|/GUIDE 157: SUBSTANCES - TOXIC AND/OR CORROSIVE (NON-COMBUSTIBLE/WATER -SENSITIVE)/ Fire or Explosion: Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Vapors may accumulate in confined areas (basement, tanks, hopper/tank cars etc.). Substance will react with water (some violently), releasing corrosive and/or toxic gases. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated or contaminated with water.|/GUIDE 157: SUBSTANCES - TOXIC AND/OR CORROSIVE (NON-COMBUSTIBLE/WATER -SENSITIVE)/ Public Safety: CALL Emergency Response Telephone Number ... As an immediate precautionary measure, isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids. Keep unauthorized personnel away. Stay upwind. Keep out of low areas. Ventilate enclosed areas.|/GUIDE 157: SUBSTANCES - TOXIC AND/OR CORROSIVE (NON-COMBUSTIBLE/WATER -SENSITIVE)/ Protective Clothing: Wear positive pressure self-contained breathing apparatus (SCBA). Wear chemical protective clothing that is specifically recommended by the manufacturer. It may provide little or no thermal protection. Structural firefighters' protective clothing provides limited protection in fire situations ONLY; it is not effective in spill situations where direct contact with the substance is possible.|For more DOT Emergency Guidelines (Complete) data for SELENIUM OXYCHLORIDE (8 total), please visit the HSDB record page.
No person may /transport,/ offer or accept a hazardous material for transportation in commerce unless that person is registered in conformance ... and the hazardous material is properly classed, described, packaged, marked, labeled, and in condition for shipment as required or authorized by ... /the hazardous materials regulations (49 CFR 171-177)./|The International Air Transport Association (IATA) Dangerous Goods Regulations are published by the IATA Dangerous Goods Board pursuant to IATA Resolutions 618 and 619 and constitute a manual of industry carrier regulations to be followed by all IATA Member airlines when transporting hazardous materials.|The International Maritime Dangerous Goods Code lays down basic principles for transporting hazardous chemicals. Detailed recommendations for individual substances and a number of recommendations for good practice are included in the classes dealing with such substances. A general index of technical names has also been compiled. This index should always be consulted when attempting to locate the appropriate procedures to be used when shipping any substance or article.
Permissible Exposure Limit: 8 Hr Time Weighted Avg: 0.2 mg/cu m. /Selenium compounds (as Se)/
Recommended Exposure Limit: 10 Hr Time-Weighted Avg: 0.2 mg/cu m. /Selenium; The REL also apply to other selenium compounds (as Se) except selenium hexafluoride./
Personal protection: complete protective clothing including self-contained breathing apparatus. Ventilation. Collect leaking and spilled liquid in sealable containers as far as possible. Absorb remaining liquid in dry sand or inert absorbent. Then store and dispose of according to local regulations.
Separated from metal oxides, strong bases and food and feedstuffs. Dry. Ventilation along the floor.
A harmful contamination of the air can be reached rather quickly on evaporation of this substance at 20 °C.
The substance is corrosive to the eyes, skin and respiratory tract. Inhalation of the vapour may cause lung oedema. Medical observation is indicated.
Repeated or prolonged contact may cause skin sensitization. The substance may have effects on the respiratory tract, gastrointestinal tract, central nervous system and liver. This may result in nasal irritation, persistent garlic odour, stomach pain, nervousness and liver impairment.
STRICT HYGIENE!
Use ventilation, local exhaust or breathing protection.
Protective gloves. Protective clothing.
Wear face shield or eye protection in combination with breathing protection.
Listed as a hazardous air pollutant (HAP) generally known or suspected to cause serious health problems. The Clean Air Act, as amended in 1990, directs EPA to set standards requiring major sources to sharply reduce routine emissions of toxic pollutants. EPA is required to establish and phase in specific performance based standards for all air emission sources that emit one or more of the listed pollutants. Selenium oxychloride is included on this list.
D002; A waste containing selenium oxychloride may (or may not) be characterized as a hazardous waste following testing for corrosivity characteristics as prescribed by the Resource Conservation and Recovery Act (RCRA) regulations.|D003; A waste containing selenium oxychloride may (or may not) be characterized as a hazardous waste following testing for the reactivity characteristics as prescribed by the Resource Conservation and Recovery Act (RCRA) regulations.|D010; A waste containing selenium (such as selenium oxychloride) may or may not be characterized a hazardous waste following testing by the Toxicity Characteristic Leaching Procedure as prescribed by the Resource Conservation and Recovery Act (RCRA) regulations.[40 CFR 261.24 (USEPA); U.S. National Archives and Records Administration's Electronic Code of Federal Regulations. Available from, as of March 8, 2011: http://www.ecfr.gov]
Releases of CERCLA hazardous substances are subject to the release reporting requirement of CERCLA section 103, codified at 40 CFR part 302, in addition to the requirements of 40 CFR part 355. Selenium oxychloride is an extremely hazardous substance (EHS) subject to reporting requirements when stored in amounts in excess of its threshold planning quantity (TPQ) of 500 lbs.
D002; A solid waste containing selenium oxychloride may become characterized as a hazardous waste when subjected to testing for corrosivity as stipulated in 40 CFR 261.22, and if so characterized, must be managed as a hazardous waste.|D003; A solid waste containing selenium oxychloride may become characterized as a hazardous waste when subjected to testing for reactivity as stipulated in 40 CFR 261.23, and if so characterized, must be managed as a hazardous waste.|D010; A solid waste containing selenium (such as selenium oxychloride) may or may not become characterized as a hazardous waste when subjected to the Toxicity Characteristic Leaching Procedure listed in 40 CFR 261.24, and if so characterized, must be managed as a hazardous waste.
Toxicity
... Applicants who will be working with more reactive ... cmpd such as ... selenium oxychloride should /be protected if they/ have had history of dermatitis, chronic bronchitis or any ... skin allergy of resp tract infection. Also those ... with history of liver or kidney disease, jaundice or albuminuria should be excluded. Careful consideration must be given to /SRP: protecting employees during their reproductive years/.
Selenium oxychloride may enter the body through the skin.|... by skin absorption and by inhalation.
Drug Information
Selenium oxychloride ... was readily absorbed through the skin.
This material is very toxic and may cause death or permanent injury after very short exposures to small quantities. Inhalation of small quantities may be corrosive and irritating to the respiratory tract. It can burn and irritate the skin and eyes and cause burns when ingested. Long-term exposure to selenium compounds may be a cause of amyotrophic lateral sclerosis in humans. Populations at special risk include those with a history of dermatitis, chronic bronchitis, skin allergies, respiratory tract infections, liver or kidney disease, jaundice, or albuminuria. Women of child-bearing age are also considered at risk. (EPA, 1998)
Signs and Symptoms of Selenium Oxychloride Exposure: Signs and symptoms of acute exposure to selenium oxychloride may include dermatitis and burns to the skin, eye and nasal irritation, a burning sensation in the nostrils, headache, a garliclike odor on the breath, fever, nausea, and vomiting (coffee grounds in appearance). Irritation of the gastrointestinal tract may also be observed. Lassitude, dizziness, hypotension (low blood pressure), decreased peripheral pulse, dyspnea (difficulty in breathing), pulmonary edema, cardiopulmonary arrest, and coma have also been reported. Emergency Life-Support Procedures: Acute exposure to selenium oxychloride may require decontamination and life support for the victims. Emergency personnel should wear protective clothing appropriate to the type and degree of contamination. Air-purifying or supplied-air respiratory equipment should also be worn, as necessary. Rescue vehicles should carry supplies such as plastic sheeting and disposable plastic bags to assist in preventing spread of contamination. Inhalation Exposure: 1. Move victims to fresh air. Emergency personnel should avoid self-exposure to selenium oxychloride. 2. Evaluate vital signs including pulse and respiratory rate, and note any trauma. If no pulse is detected, provide CPR. If not breathing, provide artificial respiration. If breathing is labored, administer 100% humidified oxygen or other respiratory support. 3. Obtain authorization and/or further instructions from the local hospital for performance of other invasive procedures. 4. Rush to a health care facility. Dermal/Eye Exposure: 1. Remove victims from exposure. Emergency personnel should avoid self-exposure to selenium oxychloride. 2. Evaluate vital signs including pulse and respiratory rate, and note any trauma. If no pulse is detected, provide CPR. If not breathing, provide artificial respiration. If breathing is labored, administer 100% humidified oxygen or other respiratory support. 3. Remove contaminated clothing as soon as possible. 4. If eye exposure has occurred, eyes must be flushed with lukewarm water for at least 15 minutes. 5. Wash exposed skin areas thoroughly with soap and water. 6. Obtain authorization and/or further instructions from the local hospital for performance of other invasive procedures. 7. Rush to a health care facility. Ingestion Exposure: 1. Evaluate vital signs including pulse and respiratory rate, and note any trauma. If no pulse is detected, provide CPR. If not breathing, provide artificial respiration. If breathing is labored, administer 100% humidified oxygen or other respiratory support. 2. Obtain authorization and/or further instructions from the local hospital for administration of an antidote or performance of other invasive procedures. 3. DO NOT induce vomiting. 4. Activated charcoal may be administered if victims are conscious and alert. Use 15 to 30 g (1/2 to 1 oz) for children, 50 to 100 g (1-3/4 to 3-1/2 oz) for adults, with 125 to 250 mL (1/2 to 1 cup) of water. 5. Promote excretion by administering a saline cathartic or sorbitol to conscious and alert victims. Children require 15 to 30 g (1/2 to 1 oz) of cathartic; 50 to 100 g (1-3/4 to 3-1/2 oz) is recommended for adults. 6. Rush to a health care facility. (EPA, 1998)
Fresh air, rest. Half-upright position. Artificial respiration may be needed. Refer for medical attention.
Remove contaminated clothes. Rinse skin with plenty of water or shower. Refer for medical attention .
First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.
Immediate first aid: Ensure that adequate decontamination has been carried out. If patient is not breathing, start artificial respiration, preferably with a demand-valve resuscitator, bag-valve-mask device, or pocket mask, as trained. Perform CPR as necessary. Immediately flush contaminated eyes with gently flowing water. Do not induce vomiting. If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain an open airway and prevent aspiration. Keep patient quiet and maintain normal body temperature. Obtain medical attention. /Selenium and Related Compounds/|Basic treatment: Establish a patent airway (oropharyngeal or nasopharyngeal airway, if needed). Suction if necessary. Watch for signs of respiratory insufficiency and assist ventilations if necessary. Administer oxygen by nonrebreather mask at 10 to 15 L/min. Monitor for shock and treat if necessary ... . Monitor for pulmonary edema and treat if necessary ... . Treat seizures if necessary ... . For eye contamination, flush eyes immediately with water. Irrigate each eye continuously with 0.9% saline (NS) during transport ... . Do not use emetics. For ingestion, rinse mouth and administer 5 mL/kg up to 200 mL of water for dilution if the patient can swallow, has a strong gag reflex, and does not drool. Administer activated charcoal ... . /Selenium and Related Compounds/|Advanced treatment: Consider orotracheal or nasotracheal intubation for airway control in the patient who is unconscious, has severe pulmonary edema, or is in severe respiratory distress. Positive-pressure ventilation techniques with a bag valve mask device may be beneficial. Consider drug therapy for pulmonary edema ... . Consider administering a beta agonist such as albuterol for severe bronchospasm ... .Monitor cardiac rhythm and treat arrhythmias if necessary ... . Start IV administration of D5W /SRP: "To keep open", minimal flow rate/. Use 0.9% saline (NS) or lactated Ringer's (LR) if signs of hypovolemia are present. For hypotension with signs of hypovolemia, administer fluid cautiously. Consider vasopressors if patient is hypotensive with a normal fluid volume. Watch for signs of fluid overload ... . Treat seizures with diazepam or lorazepam ... . Use proparacaine hydrochloride to assist eye irrigation ... . /Selenium and Related Compounds/|Emergency and supportive measures. Maintain an open airway and assist ventilation if necessary. Administer supplemental oxygen. Treat coma, convulsions, bronchospasm, hypotension, and pulmonary edema if they occur. Since hypotension is often multifactorial, evaluate and optimize volume status, peripheral vascular resistance, and myocardial contractility. Observe for at least 6 hours after exposure. ... /Selenium/|Decontamination: Inhalation. Immediately remove the victim from exposure and give supplemental oxygen if available. Skin and eyes. Remove contaminated clothing and wash exposed skin with soap and copious water. Irrigate exposed eyes with copious tepid water or saline. Ingestion. Ingestion of elemental selenium or selenium salts does not usually benefit from GI decontamination. In light of the risk of severe corrosive GI injury, gastric lavage plus activated charcoal may be of value for ingestion s of selenious acid seen within 1 hour. Invitro experiments indicate that vitamin C can reduce selenium salts to elemental selenium, which poorly absorbed. Its use has not been studied in vivo, but oral or nasogastric administration of several grams of ascorbic acid has been recommended. /Selenium/
/SIGNS AND SYMPTOMS/ Short-term Exposure: Inhalation of large quantities of ... selenium oxychloride may cause severe breathing difficulties which may not appear for several hours after exposure. Skin contact with ... selenium oxychloride may cause skin burns.|/SIGNS AND SYMPTOMS/ Selenium oxychloride readily destroys skin on contact, causing third degree burns unless immediately removed with water.|/SIGNS AND SYMPTOMS/ Contact with the skin can cause severe burns. It is toxic by skin absorption and by inhalation.|/SIGNS AND SYMPTOMS/ Selenium oxychloride is strongly vesicant and will rapidly destroy the skin upon contact unless immediately removed by washing.|For more Human Toxicity Excerpts (Complete) data for SELENIUM OXYCHLORIDE (8 total), please visit the HSDB record page.
The substance can be absorbed into the body by inhalation of its vapour and by ingestion.
Burning sensation. Cough. Laboured breathing. Sore throat. Shortness of breath. Symptoms may be delayed.
Redness. Pain. Blisters. Skin burns.
Redness. Pain. Severe deep burns.
Selenium oxychloride Use and Manufacturing
Prepared by passing chlorine into SeO2 suspended in carbon tetrachloride ... By dehydration of dichloroselenious acid.|Selenium oxyhalides ... are prepared by the addition of a halogen to a dry mixture or a carbon tetrachloride suspension of selenium and selenium dioxide. /Selenium oxyhalides/|The action of halogens or halides on elemental selenium yields various selenium halides, depending on the temperature and stoichiometric ratio. /Selenium halides/|From SOCl2 and SeO2, ... FROM AlCl3 and SeO2.
Selenium oxychloride is a solvent for synthetic phenolic resins and many other substances. selenium oxychloride is used as solvent.
Liquid, 99% purity grade
Seleninyl chloride: ACTIVE
Fire Hazards -> Corrosives, Reactive - 2nd degree
Computed Properties
Molecular Weight:165.87
Hydrogen Bond Acceptor Count:1
Exact Mass:165.84914
Monoisotopic Mass:165.84914
Topological Polar Surface Area:17.1
Heavy Atom Count:4
Complexity:29
Covalently-Bonded Unit Count:1
Compound Is Canonicalized:Yes
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