Solvent Violet 13
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Solvent Violet 13
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CAS No:
81-48-1
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Formula:
C21H15NO3
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Chemical Name:
Solvent Violet 13
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Synonyms:
9,10-Anthracenedione,1-hydroxy-4-[(4-methylphenyl)amino]-;Anthraquinone,1-hydroxy-4-p-toluidino-;1-Hydroxy-4-[(4-methylphenyl)amino]-9,10-anthracenedione;C.I. 60725;Ahcoquinone Blue IR Base;Alizarine Irisol R Base;Alizarine Violet 3B Base;N-(4-Hydroxy-1-anthraquinonyl)-4-methylaniline;Irisol base;Oil Violet IRS;Oil Violet ZIRS;11092 Violet;Waxoline Purple A;Alizurol Purple;C.I. Solvent Violet 13;D and C Violet No. 2;1-Hydroxy-4-(p-toluidino)anthraquinone;1-Hydroxy-4-(4-methylanilino)anthraquinone;Solvent Violet 13;1-Hydroxy-4-p-toluidino-9,10-anthraquinone;C.I. Disperse Blue 72;Duranol Brilliant Violet TG;Sumikaron Violet B;Resolin Blue RRL;Resiren Blue TR;Dispersol Violet B-G;Transetile Violet P 3B;Sumikaron Violet 3BL;Alizarine Violet 3B;1-p-Toluidino-4-hydroxyanthraquinone;Orient Oil Violet 730;Alizarin violet 3B;Macrolex Violet B;1-Hydroxy-4-(p-tolylamino)-9,10-anthraquinone;C.I. Solvent Blue 90;Diaresin Blue G;Lurafix Blue 590;Disperse Blue 72;Solvent Blue 90;Teraprint Blue 6R;Solvaperm Blue B;Calco Oil Violet ZIRS;Pyla-Cert D and C Violet 2;Alizurol Purple SS;Japan Violet 201;Violet No. 201;Japan Violet No. 201;Japan Purple 201;1-Hydroxy-4-[(4-methylphenyl)-9,10-anthracenedione;Thermoplast Blue 684;Kayaset Blue A 2R;Sumiplast Violet B;D&C Violet No. 2;Sandoplast Violet RSB;Oplas Violet 730;D&C Violet 2;NSC 2856;Violet 2;Plast Violet 8840;Quinizarin Blue;1342-19-4;12217-81-1;50922-59-3;54328-11-9;59459-27-7;64925-48-0;70956-28-4;74665-60-4;143928-77-2;666832-51-5
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CAS No:
Solvent Violet 13 Basic Attributes
329.34900
329.35
601-910-6
350KA7O6HK
2856
DTXSID1026293
2922509090
Safety Information
R36/37/38
S26-S36/37/39
CB7700000
P261, P272, P273, P280, P302+P352, P321, P333+P313, P363, P501
H317
D & C VIOLET NUMBER 2 IS PERMANENTLY LISTED UNDER FEDERAL FOOD, DRUG, & COSMETIC ACT FOR USE IN EXTERNALLY APPLIED DRUGS & COSMETICS.
|Warning|H317 (99.66%): May cause an allergic skin reaction [Warning Sensitization, Skin]|P261, P272, P273, P280, P302+P352, P321, P333+P313, P363, and P501|Aggregated GHS information provided by 2718 companies from 6 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
WATER, FOAM, CARBON DIOXIDE, WATER SPRAY OR MIST, DRY CHEMICAL...
Toxicity
IN GENERAL, DYES & PIGMENTS DO NOT PRESENT SERIOUS TOXIC HAZARDS TO WORKMEN IN CONDITIONS OF INDUSTRIAL EXPOSURE. HAZARDS OF DYESTUFFS MFR ARISE LARGELY FROM THE PRIMARY & INTERMEDIATE COMPD, & FROM REAGENTS...& SOLVENTS USED IN SYNTHESIS. /DYES & DYESTUFFS/|PROBABLY GREATEST PROBLEM IN WORKMEN HANDLING DYES IS...SUPERFICIAL LAYERS OF SKIN BECOME DYED. ...SODIUM HYPOCHLORITE...BLEACHES DYED SKIN. HYPOCHLORITE IS...POWERFUL IRRITANT... IT MUST BE...WASHED OFF WITH WATER...TRACES NEUTRALIZED WITH SODIUM BISULFITE SOLN. /DYES & DYESTUFFS/
Drug Information
CAUTION: LOW SYSTEMIC TOXICITY, BUT MAY CAUSE SKIN IRRITATION, SENSITIZATION. /ANTHRAQUINONE/|/RED URINE COLORATION IS A SYMPTOM OF ANTHRAQUINONE DYE POISONING./ /ANTHRAQUINONE DYES/|...DYES IN GENERAL HAVE LITTLE IRRITANT EFFECT. /DYES & DYESTUFFS/|SECONDARY IRRITANTS ARE THOSE COMPD THAT HAVE IRRITANT ACTION ON MUCOUS MEMBRANES...MORE SIGNIFICANT SYSTEMIC EFFECT RESULTING FROM ABSORPTION OF COMPD. EXAMPLES OF SECONDARY IRRITANTS ARE...MANY OF THE AROMATIC HYDROCARBONS... /AROMATIC HYDROCARBONS/|EXCEPT FOR REPORTS OF ALLERGIC REACTIONS IN HUMANS, NO TOXICITY DATA WERE LOCATED. /1,2-DIHYDROXYANTHRAQUINONE/
Solvent Violet 13 Use and Manufacturing
In a 500 mL pressure vessel equipped with a mechanical stirrer and a thermometer, 40 g of soft water was added, Hydrochloric acid 15 g, , 40 g of 4-dihydroxyanthraquinone, 25 g of p-toluidine (purchased), 160 ml of methanol, 11 g of benzoic acid, 6 g of polyethylene glycol, Slowly heated to 60 ° C, the slow addition of zinc powder 5g, The temperature at 70 ° C for 2 hours, and then heated to 90 ° C for 8 hours, then continue to constant temperature to 110 ° C for 6 hours, Continue heating to 116 ° C for 3 hours.After completion of the reaction, the temperature was lowered to 60 ° C. After passing the air, the intermediate was rapidly oxidized and filtered. The filter cake was washed successively with methanol and hot water, and 50 g of solvent violet 13 was obtained. The purity was 93percent, the yield was 84.7percent, DC was -0.5, DH was -0.3 and the intensity was 99.50In a 500 mL autoclave equipped with a mechanical stirrer and a thermometer, 60 g of methanol, 1, 4-dihydroxyanthraquinone24 g of p-nitrotoluene, 2 g of iron powder and 4 g of boric acid, and the inside of the autoclave was purged with nitrogen, followed by heating to 60 ° C with stirringHydrogenation was started and hydrogenation was carried out at a temperature of 60 ° C. When the reaction system stopped hydrogen absorption, control at 65 ° CInsulation reaction, hydrogen absorption enhancement, heat reaction time of 3h. After the completion of the reaction, the temperature was raised to 10 ° C, followed by condensation reaction with TC, & Lt;The reaction time was 5h. After the reaction, cool to 60 ° C, Pressure relief, access to air, the rapid oxidation of intermediates, and finally add hydrochloric acid 16g beating, beating temperature of 65 ° C, filtration, washing, Dried to give the desired product 50. 5 g of solvent violet 13 with a purity of 96percent, a yield of 88.3percent, a DC of 2.5, a DH of 2.0 and an intensity of 100.50.
1. Mainly used for dyeing pure polyester or acetate fiber. It can also be used for direct printing and transfer printing. Often with Disperse Red 3B; Disperse Yellow RL make up the three primary colors. Reactive dyes or direct dyes can dye polyester/viscose blended fabrics in the same bath. 2. Mainly used for coloring of polystyrene, ABS, rigid PVC resin and polyester fiber pulp and cosmetics.
Dyes
Air care products
< 25,000 lb|(1977) PROBABLY GREATER THAN 6.81X10+6 GRAMS|(1979) PROBABLY GREATER THAN 6.81X10+6 GRAMS
ESSENTIALLY 100% AS A DYE
Plastic material and resin manufacturing|9,10-Anthracenedione, 1-hydroxy-4-[(4-methylphenyl)amino]-: ACTIVE|/IN DYES/ THE QUALITY OF IMPARTING COLOR IS RELATED TO SPECIFIC CHEMICAL STRUCTURES OF WHICH /THE MOST IMPORTANT ARE...ANTHRAQUINONE DERIVATIVES... /DYES & DYESTUFFS/|...BASIC CHEMICAL STRUCTURES /SUCH AS ANTHRAQUINONE/...ARE MODIFIED BY THE INTRODUCTION OF SUBSTITUENT GROUPS, EG -OH, -NH2, -CL...OR -COOH. THE NATURE & POSITION OF SUBSTITUENT GROUPS INFLUENCE BOTH COLOR & OTHER PHYSICAL CHARACTERISTICS OF THE PRODUCT. /DYES & DYESTUFFS/|THE COAL TAR DYES INCLUDE MORE THAN A DOZEN WELL-DEFINED GROUPS AMONG WHICH ARE...ANTHRAQUINONES... /ANTHRAQUINONES/|...DISPERSE DYES /ARE/ USED FOR ACETATE, RAYON, & SYNTHETIC FIBERS... /DISPERSE DYES/
THE IDENTIFICATION OF DYES IN COSMETICS BY THIN-LAYER CHROMATOGRAPHY.|RECOVERIES AVERAGING 104% FOR D & C VIOLET NUMBER 2 BY HIGH PERFORMANCE LIQUID CHROMATOGRAPHY DETERMINATION.|PARTICULARS OF A GRAVIMETRIC METHOD OF ANALYSIS ARE AVAILABLE FROM BAYER LEVERKUSEN. /ANTHRAQUINONE/|METHODS TO DETERMINE WHETHER COLOR ADDITIVES ARE IN COMPLIANCE WITH SPECIFICATIONS CONCERNING THEIR SAFE USE IN FOODS, DRUGS, OR COSMETICS.
Cosmetics -> Cosmetic colorant; Hair dyeing
Computed Properties
Molecular Weight:329.3
XLogP3:5.5
Hydrogen Bond Donor Count:2
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:2
Exact Mass:329.10519334
Monoisotopic Mass:329.10519334
Topological Polar Surface Area:66.4
Heavy Atom Count:25
Complexity:525
Covalently-Bonded Unit Count:1
Compound Is Canonicalized:Yes
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