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Home > Encyclopedia > 3,5-Diiodo-DL-tyrosine

3,5-Diiodo-DL-tyrosine

3,5-Diiodo-DL-tyrosine structure

3,5-Diiodo-DL-tyrosine 

structure
  • CAS No:

    66-02-4

  • Formula:

    C9H9I2NO3

  • Chemical Name:

    3,5-Diiodo-DL-tyrosine

  • Synonyms:

    3,5-Diiodo-DL-tyrosine;L-Tyr(3',5'-I2);3,5-diiodo-tyrosin;apothyrin;cemiod;flaianina;jodgorgon;H-DL-Tyr(3,5-I2)-OH

  • Categories:

    Biochemical Engineering  >  Amino Acids and Derivatives

Description

A product from the iodination of MONOIODOTYROSINE. In the biosynthesis of thyroid hormones, diiodotyrosine residues are coupled with other monoiodotyrosine or diiodotyrosine residues to form T4 or T3 thyroid hormones (THYROXINE and TRIIODOTHYRONINE).


DL-3,5-Diiodotyrosine is a lamellar crystal. Decomposed at about 200℃. Solubility in water: 0.149g/L at 0°C, 0.340g/L at 25°C, 0.773g/L at 50°C. Soluble in dilute alkali. Boiled and cooled water and alcohol solution will not produce gel-like precipitate. In contrast, L-3,5-diiodotyrosine crystallizes and dissolves after boiling in dilute alcoholic solution, and a gel-like precipitate is formed by continued boiling.

3,5-Diiodo-DL-tyrosine Basic Attributes

432.98

432.98

200-620-3

97936|208959|4143

DTXSID50110067

Pale Beige to Light Beige

29214980

Characteristics

83.6

-0.5

Clear slightly yellow liquid.

2.1461 (estimate)

213°C (rough estimate)

410.5±45.0 °C(Predicted)

202.1±28.7 °C

1.748

339.9mg/L(25 ºC)

Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

2.17±0.30(Predicted)

159.4 Ų [M-H]-

under inert gas (nitrogen or Argon) at 2–8 °C

Safety Information

Stable under normal temperatures and pressures.

P261, P264, P270, P271, P280, P301+P312, P302+P352, P304+P340, P305+P351+P338, P312, P321, P330, P332+P313, P337+P313, P362, P403+P233, P405, P501

H302

|Warning|H302 (97.44%): Harmful if swallowed [Warning Acute toxicity, oral]|P261, P264, P270, P271, P280, P301+P312, P302+P352, P304+P340, P305+P351+P338, P312, P321, P330, P332+P313, P337+P313, P362, P403+P233, P405, and P501|Aggregated GHS information provided by 39 companies from 2 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Drug Information

Acid, Iodogorgoic

3,5-Diiodo-DL-tyrosine Use and Manufacturing

Methods of Manufacturing

Derived from tyrosine by iodination.

Uses

3,5-Diiodo-DL-tyrosine is used for diagnosis of hypothyroidism caused by DEHAL1 gene defects.

L-Tyrosine, 3,5-diiodo-: INACTIVE

Computed Properties

Molecular Weight:432.98
XLogP3:-0.5
Hydrogen Bond Donor Count:3
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:3
Exact Mass:432.86719
Monoisotopic Mass:432.86719
Topological Polar Surface Area:83.6
Heavy Atom Count:15
Complexity:227
Undefined Atom Stereocenter Count:1
Covalently-Bonded Unit Count:1
Compound Is Canonicalized:Yes

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