Bromoacetyl bromide | 598-21-0, Bromoacetyl bromide Formula

Description

dark brown-yellow liquid

Bromoacetyl bromide appears as a water-white liquid with a pungent odor. Denser than water. Irritates skin, eyes and mucous membranes. May be toxic by ingestion, inhalation and skin absorption. Used to make other chemicals.

Bromoacetyl bromide Basic Attributes

Molecular Weight：

201.84

Exact Mass：

201.84

EC Number：

209-923-5

UN Number：

2513

DSSTox ID：

DTXSID1060506

HScode：

29159080

Characteristics

PSA：

17.1

XLogP3：

1.6

Appearance：

Bromoacetyl bromide appears as a water-white liquid with a pungent odor. Denser than water. Irritates skin, eyes and mucous membranes. May be toxic by ingestion, inhalation and skin absorption. Used to make other chemicals.

Density：

2.324 g/mL at 20 °C

Melting Point：

148.5°C (estimate)

Boiling Point：

148.5 °C

Flash Point：

> 110ºC

Refractive Index：

1.545-1.547

Water Solubility：

REACTS

Storage Conditions：

Refrigerator (+4ºC)

Vapor Pressure：

3.8 mm Hg ( 25 °C)

Air and Water Reactions：

Fumes in air. Reacts violently with water to form hydrobromic acid (HBr) (USCG 1991).

Reactive Group：

Halogenated Organic Compounds

Reactivity Alerts：

Water-Reactive

Reactivity Profile：

BROMOACETYL BROMIDE is incompatible with water, with bases (including amines), with strong oxidizing agents, with alcohols. May react vigorously or explosively if mixed with diisopropyl ether or other ethers in the presence of trace amounts of metal salts [J. Haz. Mat., 1981, 4, 291]. Decomposes when heated with evolution of highly toxic and irritating hydrogen bromide and bromophosgene vapors.

Safety Information

Packing level：

II

Hazard category：

8

Transport codes：

2513

wgk germany：

3

hazard class code：

R14; R34

safety instructions：

26-36/37/39-45-8-30-25

Marks：

C

Stability/Shelf Life：

Stable, but reacts violently with water. Incompatible with water, moisture, alcohols, strong bases, strong oxidizing agents.

Precautionary statement(s)：

P260, P264, P280, P301+P330+P331, P303+P361+P353, P304+P340, P305+P351+P338, P310, P321, P363, P405, P501

Hazard Statements：

H314

Fire Hazards：

Special Hazards of Combustion Products: Heat of fire can cause decomposition, with evolution of highly toxic and irritating hydrogen bromide and bromophosgene vapors. Behavior in Fire: Highly irritating (tear gas) vapors released when heated. Hydrogen bromide gas is released if in contact with water. (USCG, 1999)|Corrosives, Reactive - 2nd degree

GHS Classification：

|Danger|H314 (100%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]|P260, P264, P280, P301+P330+P331, P303+P361+P353, P304+P340, P305+P351+P338, P310, P321, P363, P405, and P501|Aggregated GHS information provided by 70 companies from 8 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.|Not Classified

Fire Fighting：

Excerpt from ERG Guide 156 [Substances - Toxic and/or Corrosive (Combustible / Water-Sensitive)]: Note: Most foams will react with the material and release corrosive/toxic gases. SMALL FIRE: CO2, dry chemical, dry sand, alcohol-resistant foam. LARGE FIRE: Water spray, fog or alcohol-resistant foam. FOR CHLOROSILANES, DO NOT USE WATER; use AFFF alcohol-resistant medium-expansion foam. Move containers from fire area if you can do it without risk. Use water spray or fog; do not use straight streams. FIRE INVOLVING TANKS OR CAR/TRAILER LOADS: Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. Do not get water inside containers. Cool containers with flooding quantities of water until well after fire is out. Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. ALWAYS stay away from tanks engulfed in fire. (ERG, 2016)

Isolation and Evacuation：

Excerpt from ERG Guide 156 [Substances - Toxic and/or Corrosive (Combustible / Water-Sensitive)]: As an immediate precautionary measure, isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids. SPILL: Increase, in the downwind direction, as necessary, the isolation distance shown above. FIRE: If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2016)

Nonfire Spill Response：

Excerpt from ERG Guide 156 [Substances - Toxic and/or Corrosive (Combustible / Water-Sensitive)]: ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). All equipment used when handling the product must be grounded. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Stop leak if you can do it without risk. A vapor-suppressing foam may be used to reduce vapors. FOR CHLOROSILANES, use AFFF alcohol-resistant medium-expansion foam to reduce vapors. DO NOT GET WATER on spilled substance or inside containers. Use water spray to reduce vapors or divert vapor cloud drift. Avoid allowing water runoff to contact spilled material. Prevent entry into waterways, sewers, basements or confined areas. SMALL SPILL: Cover with DRY earth, DRY sand or other non-combustible material followed with plastic sheet to minimize spreading or contact with rain. Use clean, non-sparking tools to collect material and place it into loosely covered plastic containers for later disposal. (ERG, 2016)

Personal Protective Equipment：

Acid-type canister mask; self-contained breathing apparatus (full face); rubber gloves and full protective clothing. (USCG, 1999)

Drug Information

Health Hazards：

Inhalation causes severe irritation of upper respiratory system. External contact causes severe irritation of eyes and skin. Ingestion causes severe irritation of mouth and stomach. (USCG, 1999)

First Aid：

INHALATION: Remove from exposure; support respiration, call physician. SKIN: Wash with large amounts of water; treat burns as required. INGESTION: Do NOT induce vomiting; give large amounts of water, call a physician. (USCG, 1999)

Bromoacetyl bromide Use and Manufacturing

Manufacturing Info：

Acetyl bromide, 2-bromo-: ACTIVE

Use Classification：

Fire Hazards -> Corrosives, Reactive - 2nd degree

Computed Properties

Molecular Weight:201.84
XLogP3:1.6
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:1
Exact Mass:201.84519
Monoisotopic Mass:199.84724
Topological Polar Surface Area:17.1
Heavy Atom Count:5
Complexity:42.9
Covalently-Bonded Unit Count:1
Compound Is Canonicalized:Yes

Material

Acetic acid

Recommended Suppliers of Bromoacetyl bromide

Greenbo Biochem Contact Supplier

CN
5 YRS

Business licensed Certified factory

Manufactory Supplier of Active Pharm Ingredients,Chemical Catalyst,Pharmaceutical Intermediates,Flavors and Fragrances,Agrochemicals,Chemical Pesticides,Organic Intermediates,OLED Intermediates

Bromoacetyl bromide 99.9% high purity certified Professional Producer Greenbo

CAS No.: 598-21-0

Grade: Industrial Grade

Content: 99.9%

Inquiry
Suqian City Hengliyuan Import and Export Trade Co., LTD Contact Supplier

CN
3 YRS

Business licensed

Trader Supplier of Acrylonitrile,Sodium biselenite methylamine solution,Methylamine [anhydrous],Zinc dust,Hydrogen peroxide solution [content >8%],Triisopropyl borate,Fuming sulfuric acid,Lithium borohydride,Triethyl borate,Ethyl propionate,Propionic anhydride,Propylarsinic acid,Aniline,4-Aminobiphenyl,4-Aminophenol,2-Aminopropane,Propane,0,0-Dimethyl-S-(2,3-dihydro-5-methoxy-2-oxo-1,3,4-thiadiazol-3-ylmethyl) dithiophosphate,Natural resin paint,Epoxy resin paint,Amino resin paint,Rubber paint,Organic silicon resin,Cyclopentene,n-Butylcyclopentane,N-n-Butylaniline,3-Ethoxyaniline,Ethyl acetate,Acetic acid solution [10%< content <80%],Sodium ethoxide ethanol solution,Ethylamine aqueous solution [concentration 50%~70%],Sodium oxide,Ethyl nitrite,Sodium nitrite,Bromocyclopentane,1-Bromopropane,Bromoacetone,2-Bromoaniline,2-Nitrobromobenzene,3-Nitrobenzyl chloride,4-Nitro-2-methylaniline,4-Nitro-1,3-dimethylbenzene,Valeryl chloride,Glutaronitrile,Lead tetraoxide,Silicon tetrachloride,1,1,3,3-Tetrachloroacetone,Tetrapropylene,2-tert-Butylphenol,Tetradecanoyl chloride,Trichloroacetic acid,Trichlorotoluene,Aluminum trichloride [anhydrous],Phosphorus trichloride,Trimethylcyclohexylamine,1,2,3-Trimethylbenzene,Trimethylchlorosilane,Solvent benzene,Sodium hydroxide,Potassium hydroxide solution [content >30%],Hydrobromic acid,Methyl chloroacetate,Butyl chloroacetate,3-Chloronitrobenzene,4-Chlorotoluene,1-Chloropropane,2-Chloropropionic acid,4-Chloroaniline,2-Chloroaniline,2-Chloro-4-nitroaniline,4-Chloro-2-nitrophenol,2,2',4,4',5,5'-Hexabromodiphenyl ether,Hexamethyldisiloxane,Diethyl sulfate,Thioacetic acid,Aluminum phosphide,o-Toluenesulfonyl chloride,Phthalimide,Potassium antimony tartrate,2-Methoxyaniline,Formic acid,1-Methylpentanol,Methyltriethoxysilane,2-Methylaniline,2-Methyl-1-propanol,Toluene diisocyanate,Cyclooctene,Cyclopentane,Cyclohexanone,Cyclohexylamine,Cyclopropane,2-Furanmethanol,N,N-Diethyl-p-toluidine,N,N-Diethyl-1,3-propanediamine,Sodium 2,4-dinitro-5-methylphenolate,3,5-Dinitroaniline,2,6-Dinitroaniline,3,6-Dihydroxyphthalonitrile,3,3'-Dichlorobenzidine,2,4-Dichloroaniline,1,3-Dichlorobenzene,2,2-Dimethylpropionate,3,4-Dimethylaniline,2,5-Dimethylaniline,3,3'-Dimethyl-4,4'-diaminobiphenyl,3,4-Dimethylphenol,1,4-Dimethylbenzene,N,N-Dibutylaniline,Bromoacetic acid,Bromacetyl bromide,Isooctane,Isooctene,Natural gas [rich in methane] (only for chemical raw material use,not for fuel use),Tributyltin acetate,Diphenylphosphine dichloride,Sodium chloroacetate,Dicyclohexylamine,Valeric acid,n-Propyl mercaptan,1,3-Dichloropropane,Dichloromethane,tert-Butyl chloride,Cyclopentyl chloride,Phosphorous acid,Cyclopentanone,Trichloroacetaldehyde [stabilized],Stannous octoate,Calcium resin,Cyclohexane,n-Octane,1,2-Dichloroethane,Thionyl chloride,tert-Butyl hydroperoxide [79%< content <90%,water content >10%],Isopropenyl acetate,Sodium dithionite,Sodium dithionate,Propionyl chloride,Benzene,Hydrobromic acid,Triethylamine,Cyclopentyl chloride,Iodine trichloride,Triethyl borate,Trimethyl borate,Toluene-2,4-diisocyanate,Hydrochloric acid,Chloroform,Benzyl cyanide,Acetone,Sulfuric acid,Toluene

Manufacturer 99% Bromoacetyl Bro Mide CAS 598-21 -0 in large stock

Unit Price: $101 /MT FOB

CAS No.: 598-21-0

Grade: Pharmaceutical Grade

Content: 99.5%

Inquiry