Trichloro(chloromethyl)silane

183.92

183.92

1811640

216-316-9

03TZM169KH

139830

3389|1295

DTXSID2061779

29319090

0

4.42

Trichloro(chloromethyl)silane is a liquid. (EPA, 1998)

1.465 g/cm³

118 °C

69 °C

n 20/D 1.454(lit.)

H2O: slightly soluble ; Reacts vigorously with water to form hydrogen chloride (hydrochloric acid)

Store below +30°C.

20.7mmHg at 25°C

Oral-mouse LDL0: 100 mg/kg; inhalation-rat LC> 5 mg/m3/2 hours

Flammable; toxic silicon oxide and chloride fumes are emitted from the fire

Highly flammable. Reacts vigorously with water to form hydrogen chloride (hydrochloric acid)

Halogenated Organic Compounds

Highly Flammable

Chlorosilanes, such as TRICHLORO(CHLOROMETHYL)SILANE, are compounds in which silicon is bonded to from one to four chlorine atoms with other bonds to hydrogen and/or alkyl groups. Chlorosilanes react with water, moist air, or steam to produce heat and toxic, corrosive fumes of hydrogen chloride. They may also produce flammable gaseous H2. They can serve as chlorination agents. Chlorosilanes react vigorously with both organic and inorganic acids and with bases to generate toxic or flammable gases.

II

8

UN 3389 6.1/PG 1

3

14-26-34

26-28-36/37/39-45-8-28A

VV2200000

T+

Low temperature, ventilated, dry warehouse; moisture-proof, airtight

Reacts violently with water; emits corrosive substances such as hydrogen chloride

P260, P264, P271, P280, P284, P301+P330+P331, P303+P361+P353, P304+P340, P305+P351+P338, P310, P320, P321, P363, P403+P233, P405, P501

H314

SRP: At the time of review, criteria for land treatment or burial (sanitary landfill) disposal practices are subject to significant revision. Prior to implementing land disposal of waste residue (including waste sludge), consult with environmental regulatory agencies for guidance on acceptable disposal practices.

USEPA; Chemical Profile: Trichloro(chloromethyl)silane (1985). Chemical safety information sheet.

(Non-specific -- Methyl Trichloro- silane) Flammable/Combustible material; may be ignited by heat, sparks, or flames. Vapors may travel to a source of ignition and flash back. Container may explode in heat of fire. Vapor explosion hazard indoors, outdoors, or in sewers. Runoff to sewer may create fire or explosion hazard. May react violently with water. (EPA, 1998)|Corrosives, Flammable - 2nd degree, Reactive - 2nd degree

|Danger|H314 (100%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]|P260, P264, P271, P280, P284, P301+P330+P331, P303+P361+P353, P304+P340, P305+P351+P338, P310, P320, P321, P363, P403+P233, P405, and P501|Aggregated GHS information provided by 70 companies from 4 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

(Non-specific -- Methyl Trichlorosilane) Move container from fire area if you can do it without risk. Do not get water inside container. Cool containers that are exposed to flames with water from the side until well after fire is out. Stay away from ends of tanks. Withdraw immediately in case of rising sound from venting safety device or any discoloration of tank due to fire. (Non-Specific -- Methyl Trichlorosilane) Small fires: Dry chemical, CO2, halon, water spray, or standard foam. Large fires: Water spray, fog, or standard foam is recommended. (EPA, 1998)

Excerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]: As an immediate precautionary measure, isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids. SPILL: See ERG Table 1 - Initial Isolation and Protective Action Distances on the UN/NA 3389 datasheet. FIRE: If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2016)

Caution : Extremely flammable; may spontaneously ignite. Avoid sources of extreme heat or ignition including sparks or fire. Trichloro (chloromethyl) silane will liberate hydrochloric acid upon contact with water. (Non-Specific -- Methyl Trichlorosilane) Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas. If water pollution occurs, notify appropriate authorities. Shut off ignition sources; no flares, smoking or flames in hazard area. Do not touch spilled material; stop leak if you can do so without risk. Use water spray to reduce vapors; do not get water inside container. Small spills: flush area with flooding amounts of water. Large spills: dike far ahead of spill for later disposal. (EPA, 1998)

For emergency situations, wear a positive pressure, pressure-demand, full facepiece self-contained breathing apparatus (SCBA) or pressure- demand supplied air respirator with escape SCBA and a fully-encapsulating, chemical resistant suit. (EPA, 1998)

highly toxic

(Non-Specific -- Methyl Trichlorosilane) If inhaled, may be harmful; contact may cause burns to skin and eyes. Runoff from fire control or dilution water may cause pollution. (EPA, 1998)

Signs and Symptoms of Acute Trichloro (Chloromethyl) Silane Exposure: Signs and symptoms of acute ingestion of trichloro (chloromethyl) silane may be severe, and include increased salivation, intense thirst, difficulty swallowing, chills, pain, and shock. Oral, esophageal, and stomach burns are common. Vomitus generally has a coffee-ground appearance. The potential for circulatory collapse is high following ingestion of trichloro (chloromethyl) silane. Acute inhalation exposure may result in sneezing, choking, laryngitis, dyspnea (shortness of breath), respiratory tract irritation, and chest pain. Bleeding of nose and gums, ulceration of the nasal and oral mucosa, pulmonary edema, chronic bronchitis, and pneumonia may also occur. If the eyes have come in contact with trichloro (chloromethyl) silane, irritation, pain, swelling, corneal erosion, and blindness may result. Dermatitis (red, inflamed skin), severe burns, pain, and shock generally follow dermal exposure. Emergency Life-Support Procedures: Acute exposure to trichloro (chloromethyl) silane may require decontamination and life support for the victims. Emergency personnel should wear protective clothing appropriate to the type and degree of contamination. Air-purifying or supplied-air respiratory equipment should also be worn, as necessary. Rescue vehicles should carry supplies such as plastic sheeting and disposable plastic bags to assist in preventing spread of contamination. Inhalation Exposure: 1. Move victims to fresh air. Emergency personnel should avoid self-exposure to trichloro (chloromethyl) silane. 2. Evaluate vital signs including pulse and respiratory rate, and note any trauma. If no pulse is detected, provide CPR. If not breathing, provide artificial respiration. If breathing is labored, administer oxygen or other respiratory support. 3. Obtain authorization and/or further instructions from the local hospital for administration of an antidote or performance of other invasive procedures. 4. RUSH to a health care facility. Dermal/Eye Exposure: 1. Remove victims from exposure. Emergency personnel should avoid self- exposure to trichloro (chloromethyl) silane. 2. Evaluate vital signs including pulse and respiratory rate, and note any trauma. If no pulse is detected, provide CPR. If not breathing, provide artificial respiration. If breathing is labored, administer oxygen or other respiratory support. 3. Remove contaminated clothing as soon as possible. 4. If eye exposure has occurred, eyes must be flushed with lukewarm water for at least 15 minutes. 5. Wash exposed skin areas THOROUGHLY with soap and water. 6. Obtain authorization and/or further instructions from the local hospital for administration of an antidote or performance of other invasive procedures. 7. RUSH to a health care facility. Ingestion Exposure: 1. Evaluate vital signs including pulse and respiratory rate, and note any trauma. If no pulse is detected, provide CPR. If not breathing, provide artificial respiration. If breathing is labored, administer oxygen or other respiratory support. 2. DO NOT induce vomiting or attempt to neutralize! 3. Rinse mouth with large amounts of water. Instruct victims not to swallow this water. 4. Obtain authorization and/or further instructions from the local hospital for administration of an antidote or performance of other invasive procedures. 5. Activated charcoal is of no value. 6. Give the victims water or milk: children up to 1 year old, 125 mL (4 oz or 1/2 cup); children 1 to 12 years old, 200 mL (6 oz or 3/4 cup); adults, 250 mL (8 oz or 1 cup). Water or milk should be given only if victims are conscious and alert. 7. RUSH to a health care facility. (EPA, 1998)

Silane, trichloro(chloromethyl)-: ACTIVE

Fire Hazards -> Corrosives, Flammable - 2nd degree, Reactive - 2nd degree