Diammonium tartrate
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Diammonium tartrate
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CAS No:
3164-29-2
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Formula:
C4H6O6.2H3N
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Chemical Name:
Diammonium tartrate
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Synonyms:
Butanedioic acid,2,3-dihydroxy- (2R,3R)-,ammonium salt (1:2);Tartaric acid,diammonium salt;Ammonium tartrate ((NH4)2O6C4H4);Butanedioic acid,2,3-dihydroxy- [R-(R*,R*)]-,diammonium salt;Butanedioic acid,2,3-dihydroxy- (2R,3R)-,diammonium salt;Diammonium tartrate;Ammonium d-tartrate;L-Tartaric acid ammonium salt;Diammonium L-(+)-tartrate;Diammonium d-tartrate;Ammonium tartrate;(2R,3R)-2,3-Dihydroxysuccinic acid diammonia salt;113131-84-3
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CAS No:
Description
white crystalline powder Ammonium tartrate is a colorless crystalline or white granular solid.
Ammonium tartrate is a white crystalline solid. It is soluble in water. The primary hazard is the threat to the environment. Immediate steps should be taken to limit its spread to the environment. It is used to manufacture fabrics and in medicine.
Ammonium tartrate is a white crystalline solid. It is soluble in water. The primary hazard is the threat to the environment. Immediate steps should be taken to limit its spread to the environment. It is used to manufacture fabrics and in medicine.
Characteristics
120.72000
log Kow = -2.79 (est)
White semi-transparent crystalline
1.601 g/cm3
decomposes [CRC10]
399.3ºC at 760mmHg
209.4ºC
H2O: 63 g/L (15 ºC)
Store in a cool, dry place. Store in a tightly closed container.
7.1X10-16 mm Hg at 25 °C
32.4 º (c=1.84, H2O)
Odorless
pH of a 0.2 molar aqueous solution: 6.5
Water soluble.
Salts, Acidic
Acidic salts, such as AMMONIUM TARTRATE, are generally soluble in water. The resulting solutions contain moderate concentrations of hydrogen ions and have pH's of less than 7.0. They react as acids to neutralize bases. These neutralizations generate heat, but less or far less than is generated by neutralization of inorganic acids, inorganic oxoacids, and carboxylic acid. They usually do not react as either oxidizing agents or reducing agents but such behavior is not impossible. Many of these compounds catalyze organic reactions. Special Hazards of Combustion Products: Toxic oxides of nitrogen or ammonia gas may form in fires (USCG, 1999).
Safety Information
6.1
UN 3077 9 / PGIII
3
20/21/22-36/37/38
24/25-36-26
WW8050000
Xn
Stable. Incompatible with strong acids.
Special Hazards of Combustion Products: Toxic oxides of nitrogen or ammonia gas may form in fires. (USCG, 1999)
Excerpt from ERG Guide 171 [Substances (Low to Moderate Hazard)]: SMALL FIRE: Dry chemical, CO2, water spray or regular foam. LARGE FIRE: Water spray, fog or regular foam. Do not scatter spilled material with high-pressure water streams. Move containers from fire area if you can do it without risk. Dike fire-control water for later disposal. FIRE INVOLVING TANKS: Cool containers with flooding quantities of water until well after fire is out. Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. ALWAYS stay away from tanks engulfed in fire. (ERG, 2016)
Excerpt from ERG Guide 171 [Substances (Low to Moderate Hazard)]: As an immediate precautionary measure, isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids. SPILL: Increase, in the downwind direction, as necessary, the isolation distance shown above. FIRE: If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2016)
Excerpt from ERG Guide 171 [Substances (Low to Moderate Hazard)]: Do not touch or walk through spilled material. Stop leak if you can do it without risk. Prevent dust cloud. Avoid inhalation of asbestos dust. SMALL DRY SPILL: With clean shovel, place material into clean, dry container and cover loosely; move containers from spill area. SMALL SPILL: Pick up with sand or other non-combustible absorbent material and place into containers for later disposal. LARGE SPILL: Dike far ahead of liquid spill for later disposal. Cover powder spill with plastic sheet or tarp to minimize spreading. Prevent entry into waterways, sewers, basements or confined areas. (ERG, 2016)
Dust mask; goggles or face shield; rubber gloves (USCG, 1999)
Drug Information
Contact with solid may irritate eyes. (USCG, 1999)
EYES: flush with water. (USCG, 1999)
(R*,R*)-(+-)-2,3-dihydroxybutanedioic acid, monoammonium monosodium salt
Diammonium tartrate Use and Manufacturing
(1) Use tartaric acid and ammonium carbonate to dissolve tartaric acid in water, and slowly add ammonium carbonate until the solution is weakly alkaline to phenolphthalein. Boil for 20-30min. Evaporate on a water bath, filter quickly when a crystalline film appears, cool the filtrate, filter, and dry the crystal at 40°C to obtain the finished product. The yield is 80%. (2) Reacting tartaric acid and ammonia in ethanol, passing ammonia gas into the ethanol solution of tartaric acid to form an amorphous powdery precipitate. Filter, wash with ethanol and ether, and dry to obtain the finished product.
Masking agents for the determination of lead, nickel, phosphorus and niobium. As analytical reagents and organic synthesis intermediates.
Butanedioic acid, 2,3-dihydroxy- (2R,3R)-, ammonium salt (1:?): ACTIVE
Computed Properties
Molecular Weight:167.12
Hydrogen Bond Donor Count:5
Hydrogen Bond Acceptor Count:7
Rotatable Bond Count:3
Exact Mass:167.04298701
Monoisotopic Mass:167.04298701
Topological Polar Surface Area:116
Heavy Atom Count:11
Complexity:134
Defined Atom Stereocenter Count:2
Covalently-Bonded Unit Count:2
Compound Is Canonicalized:Yes
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