4-(Aminoiminomethyl)-1-tetrazene-1-carboximidic acid 2-nitrosohydrazide
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4-(Aminoiminomethyl)-1-tetrazene-1-carboximidic acid 2-nitrosohydrazide
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CAS No:
109-27-3
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Formula:
C2H8N10O
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Chemical Name:
4-(Aminoiminomethyl)-1-tetrazene-1-carboximidic acid 2-nitrosohydrazide
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Synonyms:
1-Tetrazene-1-carboximidic acid,4-(aminoiminomethyl)-,2-nitrosohydrazide;1-Tetrazene,4-amidino-1-(nitrosaminoamidino)-;4-(Aminoiminomethyl)-1-tetrazene-1-carboximidic acid 2-nitrosohydrazide;4-Guanyl-1-(nitrosoamino guanyl)-1-tetrazene;Tetracene;Tetracene (explosive);4-Guanyl-1-(nitrosaminoguanyl)-1-tetrazene
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CAS No:
Description
Colorless or pale-yellow, fluffy solid. Apparent d 0.45 but yields a pellet of d 1.05 under pressure of 3000 psi. Practically insoluble in water, alcohol, ether, benzene, and carbon tetrachloride; slightly hygroscopic.
This compound is an explosive.
This compound is an explosive.
4-(Aminoiminomethyl)-1-tetrazene-1-carboximidic acid 2-nitrosohydrazide Basic Attributes
188.15
188.08800
203-659-4
0114
2928000090
Characteristics
175.99000
0.51500
This compound is an explosive.
1.6049 (rough estimate)
323.14°C (rough estimate)
190.2ºC
1.8900 (estimate)
No rapid reaction with air. No rapid reaction with water.
Azo, Diazo, Azido, Hydrazine, and Azide Compounds
Explosive
Safety Information
1.1A
114
R2;R33;R26/27/28;R51/53
S35;S36;S45;S62
E;T+;N
Excerpt from ERG Guide 112 [Explosives* - Division 1.1, 1.2, 1.3 or 1.5]: MAY EXPLODE AND THROW FRAGMENTS 1600 METERS (1 MILE) OR MORE IF FIRE REACHES CARGO. For information on "Compatibility Group" letters, refer to Glossary section. (ERG, 2016)
|Danger|H200 (100%): Unstable Explosive [Danger Explosives]|P201, P202, P281, P372, P373, P380, P401, and P501|Aggregated GHS information provided by 14 companies from 2 notifications to the ECHA C&L Inventory.|H200: Unstable Explosive [Danger Explosives]
Excerpt from ERG Guide 112 [Explosives* - Division 1.1, 1.2, 1.3 or 1.5]: CARGO FIRE: DO NOT fight fire when fire reaches cargo! Cargo may EXPLODE! Stop all traffic and clear the area for at least 1600 meters (1 mile) in all directions and let burn. Do not move cargo or vehicle if cargo has been exposed to heat. TIRE OR VEHICLE FIRE: Use plenty of water - FLOOD it! If water is not available, use CO2, dry chemical or dirt. If possible, and WITHOUT RISK, use unmanned hose holders or monitor nozzles from maximum distance to prevent fire from spreading to cargo area. Pay special attention to tire fires as re-ignition may occur. Stand by, at a safe distance, with extinguisher ready for possible re-ignition. (ERG, 2016)
Excerpt from ERG Guide 112 [Explosives* - Division 1.1, 1.2, 1.3 or 1.5]: Isolate spill or leak area immediately for at least 500 meters (1/3 mile) in all directions. LARGE SPILL: Consider initial evacuation for 800 meters (1/2 mile) in all directions. FIRE: If rail car or trailer is involved in a fire, ISOLATE for 1600 meters (1 mile) in all directions; also, initiate evacuation including emergency responders for 1600 meters (1 mile) in all directions. (ERG, 2016)
Excerpt from ERG Guide 112 [Explosives* - Division 1.1, 1.2, 1.3 or 1.5]: ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). All equipment used when handling the product must be grounded. Do not touch or walk through spilled material. DO NOT OPERATE RADIO TRANSMITTERS WITHIN 100 METERS (330 FEET) OF ELECTRIC DETONATORS. DO NOT CLEAN-UP OR DISPOSE OF, EXCEPT UNDER SUPERVISION OF A SPECIALIST. (ERG, 2016)
Excerpt from ERG Guide 112 [Explosives* - Division 1.1, 1.2, 1.3 or 1.5]: Wear positive pressure self-contained breathing apparatus (SCBA). Structural firefighters' protective clothing will only provide limited protection. (ERG, 2016)
Drug Information
Excerpt from ERG Guide 112 [Explosives* - Division 1.1, 1.2, 1.3 or 1.5]: Fire may produce irritating, corrosive and/or toxic gases. (ERG, 2016)
Excerpt from ERG Guide 112 [Explosives* - Division 1.1, 1.2, 1.3 or 1.5]: Ensure that medical personnel are aware of the material(s) involved and take precautions to protect themselves. Move victim to fresh air. Call 911 or emergency medical service. Give artificial respiration if victim is not breathing. Administer oxygen if breathing is difficult. Remove and isolate contaminated clothing and shoes. In case of contact with substance, immediately flush skin or eyes with running water for at least 20 minutes. (ERG, 2016)
4-(Aminoiminomethyl)-1-tetrazene-1-carboximidic acid 2-nitrosohydrazide Use and Manufacturing
Initiating explosive.
1-Tetrazene-1-carboximidic acid, 4-(aminoiminomethyl)-, 2-nitrosohydrazide: ACTIVE
Computed Properties
Molecular Weight:188.15
XLogP3:0.3
Hydrogen Bond Donor Count:5
Hydrogen Bond Acceptor Count:7
Rotatable Bond Count:4
Exact Mass:188.08825492
Monoisotopic Mass:188.08825492
Topological Polar Surface Area:181
Heavy Atom Count:13
Complexity:235
Undefined Bond Stereocenter Count:2
Covalently-Bonded Unit Count:1
Compound Is Canonicalized:Yes
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4-(Aminoiminomethyl)-1-tetrazene-1-carboximidic acid 2-nitrosohydrazide
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