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Boron trifluoride etherate

Boron trifluoride etherate structure

Boron trifluoride etherate 

structure
  • CAS No:

    109-63-7

  • Formula:

    C4H10BF3O

  • Chemical Name:

    Boron trifluoride etherate

  • Synonyms:

    Boron,trifluoro[1,1′-oxybis[ethane]]-,(T-4)-;Ethyl ether,compd. with boron fluoride (BF3) (1:1);Borane,trifluoro-,compd. with 1,1′-oxybis[ethane] (1:1);Ethyl ether,compd. with BF3 (1:1);Ethane,1,1′-oxybis-,compd. with trifluoroborane (1:1);Boron fluoride (BF3),compd. with ethyl ether (1:1);(T-4)-Trifluoro[1,1′-oxybis[ethane]]boron;Boron fluoride diethyl etherate;Boron fluoride etherate;Boron fluoride-ethyl etherate;Boron fluoride-ethyl ether complex;Boron trifluoride-ether complex;Boron trifluoride-ethyl ether;Boron trifluoride-ethyl etherate;Boron trifluoride-ethyl ether complex;Ethyl ether-boron trifluoride complex;Boron trifluoride etherate;Boron fluoride diethyl ether complex;Boron trifluoride-diethyl ether complex;Boron fluoride (BF3)-ethyl ether compound;Boron trifluoride ethyl etherate (1:1);Boron fluoride monoetherate;Boron trifluoride-diethyl ether complex (1:1);Boron trifluoride-ethyl ether (1:1);Trifluoroboron etherate;Boron fluoride-diethyl ether compound;Trifluoroborane-1,1′-oxybis[ethane] (1:1);Boron trifluoride-diethyl etherate;Diethyl ether trifluoroborane complex;Trifluoroborane diethyl etherate;Boron trifluoride-diethyl ether 1:1 complex;Diethyl ether compound with boron trifluoride;Boron trifluoride etherate (1:1);Boron trifluoride monoetherate;Boron trifluoride-diethyl ether (1:1);Diethyl ether-trifluoroborane (1:1);Trifluoroboron-diethyl ether (1:1);109704-88-3;110622-74-7;118648-53-6;125391-69-7;2167-26-2;14480-05-8;15688-21-8;89513-75-7;145459-43-4;147102-03-2;171915-81-4

  • Categories:

    Pharmaceutical Intermediates  >  Bulk Drug Intermediates

Boron trifluoride etherate Basic Attributes

141.93

142.078

3909607

203-689-8

29319090

Characteristics

9.2

brown liquid

1.3572 g/cm3 @ Temp: 20 °C

-60.4 °C

125.7 °C

118 °F

Solubility in water: reaction.Miscible with ether and alcohol.

2-8°C

4.2 mm Hg ( 20 °C)

4.9 (vs air)

Flammable; reacts with water or steam to form toxic, corrosive, combustible gas

5.1-18.2%(V)

Safety Information

8

UN 2604 8/PG 1

3

10-14-20/22-35-48/23-34-14/15-23-22

16-23-26-36/37/39-45-8-28A-43

T,C

Warehouse ventilated, low temperature and dry; waterproof; not long-lasting

Ethers can form peroxides and react with lithium tetrahydroaluminate easily to explode; oxidants

P210, P233, P240, P241, P242, P243, P260, P264, P273, P280, P301+P330+P331, P303+P361+P353, P304+P340, P305+P351+P338, P310, P321, P363, P370+P378, P403+P235, P405, P501

H226

|Danger|H226 (84.92%): Flammable liquid and vapor [Warning Flammable liquids]|P210, P233, P240, P241, P242, P243, P260, P261, P264, P270, P271, P280, P284, P301+P312, P301+P330+P331, P303+P361+P353, P304+P312, P304+P340, P305+P351+P338, P310, P312, P314, P320, P321, P330, P363, P370+P378, P403+P233, P403+P235, P405, and P501|Aggregated GHS information provided by 181 companies from 18 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.|H226: Flammable liquid and vapor [Warning Flammable liquids]|P210, P233, P240, P241, P242, P243, P260, P264, P280, P301+P330+P331, P303+P361+P353, P304+P340, P305+P351+P338, P310, P321, P363, P370+P378, P403+P235, P405, and P501

Drug Information

boron trifluoride diethyl etherate

Boron trifluoride etherate Use and Manufacturing

Methods of Manufacturing

In the absorption method, boric acid is reacted with fuming sulfuric acid and fluorite powder to generate boron trifluoride gas, which is then absorbed by ether and rectified under reduced pressure to obtain a boron trifluoride ether complex product. Its 3H2SO4+2H33BO3+3CaF2→2BF3+3CaSO4+6H2OBF3+(C2H5)2O→(C2H5)2O·BF3

Uses

Catalyst in acetylation, alkylation, polymerization, dehydration, and condensation reactions.

Computed Properties

Molecular Weight:141.93
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:2
Exact Mass:142.0776796
Monoisotopic Mass:142.0776796
Topological Polar Surface Area:9.2
Heavy Atom Count:9
Complexity:19.1
Covalently-Bonded Unit Count:2
Compound Is Canonicalized:Yes

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