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Home > Encyclopedia > Chlorophyll b

Chlorophyll b

pharmaceutical raw materials
Chlorophyll b structure

Chlorophyll b 

structure
  • CAS No:

    519-62-0

  • Formula:

    C55H70MgN4O6

  • Chemical Name:

    Chlorophyll b

  • Synonyms:

    Magnesium,[(2E,7R,11R)-3,7,11,15-tetramethyl-2-hexadecenyl (3S,4S,21R)-9-ethenyl-14-ethyl-13-formyl-21-(methoxycarbonyl)-4,8,18-trimethyl-20-oxo-3-phorbinepropanoato(2-)-κN23,κN24,κN25,κN26]-,(SP-4-2)-;Magnesium,[dihydrogen 21-carboxy-14-ethyl-13-formyl-4,8,18-trimethyl-20-oxo-9-vinyl-3-phorbinepropionato(2-)]-,21-methyl 3-phytyl ester,(E)-;Magnesium,[3,7,11,15-tetramethyl-2-hexadecenyl 9-ethenyl-14-ethyl-13-formyl-21-(methoxycarbonyl)-4,8,18-trimethyl-20-oxo-3-phorbinepropanoato(2-)-κN23,κN24,κN25,κN26]-,[SP-4-2-[3S-[3α(2E,7S*,11S*),4β,21β]]]-;3-Phorbinepropanoic acid,9-ethenyl-14-ethyl-13-formyl-21-(methoxycarbonyl)-4,8,18-trimethyl-20-oxo-,3,7,11,15-tetramethyl-2-hexadecenyl ester,magnesium complex,[3S-[3α(2E,7S*,11S*),4β,21β]]-;Phorbine,magnesium deriv.;(SP-4-2)-[(2E,7R,11R)-3,7,11,15-Tetramethyl-2-hexadecenyl (3S,4S,21R)-9-ethenyl-14-ethyl-13-formyl-21-(methoxycarbonyl)-4,8,18-trimethyl-20-oxo-3-phorbinepropanoato(2-)-κN23,κN24,κN25,κN26]magnesium;Chlorophyll b;β-Chlorophyll;Magnesium,[3,7,11,15-tetramethyl-2-hexadecenyl 9-ethenyl-14-ethyl-13-formyl-21-(methoxycarbonyl)-4,8,18-trimethyl-20-oxo-3-phorbinepropanoato(2-)-N23,N24,N25,N26]-,[SP-4-2-[3S-[3α(2E,7S*,11S*),4β,21β]]]-;Chlorophyll-β;16103-80-3;22088-17-1

  • Categories:

    Organic Chemistry  >  Aldehydes

Description

Chlorophyll b is Light, silvery, metallic element.

Chlorophyll b Basic Attributes

907.47

906.514587

208-272-4

29339900

Characteristics

121.32000

9.13350

183-185 °C(lit.)

1071.6ºC at 760mmHg

601.9ºC

2-8°C

D20 -267° (acetone-methanol)

Safety Information

NONH for all modes of transport

3

22-24/25

Drug Information

chlorophyll b

Chlorophyll b Use and Manufacturing

Methods of Manufacturing

Chlorophyll is mostly extracted from plants (such as spinach, etc.) or dried silkworm sand. For example, the following method can be used to extract chlorophyll from silkworm sand. Organic solvent extraction: take clean silkworm sand, adjust it into a slurry with more than 70% industrial ethanol, filter out the dark green solution, and dry it. Another operation is to mix 45 parts of petroleum ether, 15 parts of methanol, and 4 parts of benzene, mix with clean silkworm sand to adjust the slurry, filter, and wash the filtrate 4 times with water. Add a small amount of sodium sulfate to the organic extract to remove residual water, filter, and recover the solvent from the filtrate to obtain chlorophyll. Physical separation: 0.4mol/L dilute sucrose solution and 0.06mol/L dilute potassium phosphate solution (pH 6-7) are mixed 1:1 into a buffer medium. Add about 1L of buffer medium per 2kg of silkworm sand, mix evenly, filter out the green suspension with a multi-layer sand cloth, centrifuge in a low-temperature centrifuge for 5-10min, wash the precipitate with water, and centrifuge again to obtain a chlorophyll precipitate. Chlorophyll is treated with oxalic acid to obtain magnesium-free pheophytin, which is then converted back to chlorophyll by introducing magnesium. Removal of phytol and magnesium with strong acid leads to phytophylloate, and phytol can also be reintroduced. Hydrolysis removes phytol and methanol to obtain chlorophyllic acid. Chlorophyll is mostly extracted from plants (such as spinach, etc.) or dried silkworm sand. For example, the following method can be used to extract chlorophyll from silkworm sand. Organic solvent extraction: take clean silkworm sand, adjust it into a slurry with more than 70% industrial ethanol, filter out the dark green solution, and dry it. Another operation is to mix 45 parts of petroleum ether, 15 parts of methanol, and 4 parts of benzene, mix with clean silkworm sand to adjust the slurry, filter, and wash the filtrate 4 times with water. Add a small amount of sodium sulfate to the organic extract to remove residual water, filter, and recover the solvent from the filtrate to obtain chlorophyll. Physical separation: 0.4mol/L dilute sucrose solution and 0.06mol/L dilute potassium phosphate solution (pH 6-7) are mixed 1:1 into a buffer medium. Add about 1L of buffer medium per 2kg of silkworm sand, mix evenly, filter out the green suspension with a multi-layer sand cloth, centrifuge in a low-temperature centrifuge for 5-10min, wash the precipitate with water, and centrifuge again to obtain a chlorophyll precipitate. Chlorophyll is treated with oxalic acid to obtain magnesium-free pheophytin, which is then converted back to chlorophyll by introducing magnesium. Removal of phytol and magnesium with strong acid leads to phytophylloate, and phytol can also be reintroduced. Hydrolysis removes phytol and methanol to obtain chlorophyllic acid.

Uses

Extends the absorption spectrum of light-harvesting complexes LHC-I and LHC-II above 700 nm

Magnesium, [(2E,7R,11R)-3,7,11,15-tetramethyl-2-hexadecenyl (3S,4S,21R)-9-ethenyl-14-ethyl-13-formyl-21-(methoxycarbonyl)-4,8,18-trimethyl-20-oxo-3-phorbinepropanoato(2-)-.kappa.N23,.kappa.N24,.kappa.N25,.kappa.N26]-, (SP-4-2)-: ACTIVE

Computed Properties

Molecular Weight:907.5
Hydrogen Bond Acceptor Count:10
Rotatable Bond Count:23
Exact Mass:906.5145777
Monoisotopic Mass:906.5145777
Topological Polar Surface Area:114
Heavy Atom Count:66
Complexity:2180
Defined Atom Stereocenter Count:5
Defined Bond Stereocenter Count:1
Covalently-Bonded Unit Count:2
Compound Is Canonicalized:Yes

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